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Optimization of chemical precipitation for valuable metal recovery from spent lithium nickel manganese cobalt oxide batteries
(2026-05-01)
Morawan, Nattaya
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Kruthun, Orathai
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Katers, John F.
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Attaphong, Chodchanok
This study investigated the optimized conditions for chemical precipitation to recover nickel manganese cobalt hydroxide (NiCoMn-OH) and lithium carbonate (Li<inf>2</inf>CO<inf>3</inf>) from spent lithium nickel manganese cobalt oxide (sLi-NMC) batteries. The research focused on establishing optimized conditions to maximize recovery efficiency and product purity. The process involved dismantling and incinerating the batteries to produce black powder, followed by acid leaching using H<inf>2</inf>SO<inf>4</inf> and H<inf>2</inf>O<inf>2</inf>, and a two-step precipitation to recover NiCoMn-OH and Li<inf>2</inf>CO<inf>3</inf>. Results indicated that the optimized incineration conditions for efficient black powder production were 600 °C for 30 min. During the leaching process, the optimized extraction of lithium, nickel, cobalt, and manganese was achieved using 1 M H<inf>2</inf>SO<inf>4</inf> with 2% H<inf>2</inf>O<inf>2</inf> at a liquid-to-solid ratio of 30:1 mL/g. In the first precipitation stage, the optimized conditions for co-precipitating the solid NiCoMn-OH using saturated NaOH were identified as pH 10, 25 °C, and a contact time of 90 min. The results showed that nickel, manganese, and cobalt were precipitated at 92.04%, 90.35%, and 86.78%, respectively (a purity of 98.67%). Finally, lithium was successfully recovered as Li<inf>2</inf>CO<inf>3</inf> using saturated Na<inf>2</inf>CO<inf>3</inf>, at pH 12, 100 °C, and a contact time of 120 min up to 96.51% (a purity of 98.98%). Ultimately, the optimized conditions obtained from this study can provide valuable data for waste management and serve as a comparative baseline for environmental impact assessment of conventional metal recovery, enabling direct comparisons with optimized alternative methods in future research.
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Formulation of microemulsion-based biofuels via the HLD framework
(2025-01-01)
Attaphong, Chodchanok
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Charoensaeng, Ampira
The attention given to reverse micelle microemulsion for biofuel production has increased over the years. For Winsor Type II microemulsion systems using vegetable oil/diesel blends as an oil phase and an alkanol (i.e., ethanol) as a polar phase, surfactants with or without cosurfactants play a crucial role in the formulations. In this work, the microemulsion biofuel formulations were reviewed and discussed with regard to the formulation compositions (i.e., polar phase, oil phase, surfactant, and cosurfactant). The optimized systems in the literature were selected to calculate the HLD values. The HLD concept was investigated to predict the formulations, especially the total surfactant and cosurfactant concentration, for specific microemulsion biofuels. From the published experimental data set, correlations relating to the characteristics of the surfactant, cosurfactant, polar phase, and oil were examined. The results indicate that the HLD concept can be a useful tool to predict and provide the appropriate range of the surfactant/cosurfactant amount at the laboratory scale, which can then be developed and extended to the industrial scale in biofuel production.
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Assessment and classification of different ashes from waste incinerators in Thailand
(2024-12-01)
Muthuraja, Raji
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Pombhejara, Chatpong Na
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Ganesan, Sunantha
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Attaphong, Chodchanok
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Morawan, Nattaya
Rapid urbanisation and a growing population have led to a huge production of solid waste worldwide. To mitigate solid wastes, Thailand adapts incineration. As a consequence, a variety of fly ashes being produced in large quantities. Fly ash management is therefore a risk for the future. A comparison of the chemical and physical properties of five sources of ashes from the waste incinerators in three regions in Thailand, namely MFA1, MFA2, IFA, and fly ash that used in a ready-mixed concrete plant, CFA1 and CFA2 was conducted. Additionally, bottom ashes, MBA1, MBA2 and IBA were also characterized similarly. The analysis showed that coal fly ash from ready mixed concrete plant of CFA1 and CFA2 were classified under class F and C, respectively. The heavy metal analysis showed that fly ash from MFA1 and IFA has high amount of Zn (7,523 mg/kg and 28,315 mg/kg), followed by MFA1 has high amount of cadmium (127 mg/kg) and MFA1 and IFA showed high concentration of lead (1,955 mg/kg and 1,425 mg/kg). The present study show that fly ash often contains heavy metals, dioxins, and other hazardous substances, highlighting the need for detailed analysis to determine proper handling and disposal methods. Advanced classification systems, which may include parameters such as leaching behavior, particle size distribution, and contaminant concentrations, are essential for categorizing fly ash into appropriate management pathways, such as landfilling, resource recovery, or reuse in construction materials.
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Environmental Impact Assessment of Lead-Acid and Lithium-ion Battery Waste Management in Thailand
(2024-01-01)
Morawan, Nattaya
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Mungkhala, Issariya
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Attaphong, Chodchanok
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Katers, John
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Sarikprueck, Piampoom
This study used material flow analysis and life cycle impact assessment to evaluate the management of lead-acid and lithium-ion batteries in Thailand in 2022. Four scenarios were designed, employing two methods: landfilling and material recovery. Landfilling lead-acid and lithium-ion batteries showed significant negative environmental impacts. Lead recovery for lead-acid batteries waste also had negative impacts due to slag generation. However, metal recovery of lithium-ion battery waste, which recovered lithium carbonate and cobalt carbonate, demonstrated positive environmental outcomes. When comparing the two methods, landfilling was preferable for lead-acid batteries, whereas metal recovery was better for lithium-ion batteries. These findings provide essential information for battery management guidelines in Thailand and indicate that future research should explore additional methods and their economic aspect.
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Phase stability, fuel properties, and diesel engine performance of palm-oil-based microemulsion biofuels
(2023-05-01)
Attaphong, Chodchanok
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Morawan, Nattaya
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Sarikprueck, Piampoom
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Charoensaeng, Ampira
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Khaodhiar, Sutha
Microemulsification and blending are two viscosity-modifying techniques of vegetable oils for direct use with diesel engine. In this study, alcohol blends are mixtures of ethanol, diesel, and palm-oil biodiesel while microemulsion biofuels are thermodynamically stable, clear, and single-phase mixtures of diesel, palm oil, and ethanol stabilized by surfactants and cosurfactants. Although there are many studies on biofuels lately, there is limited research on using biodiesel as a surfactant in microemulsion formulations and applied on engine performance at different engine loads. Therefore, the objectives are to investigate phase stability and fuel properties of formulated biofuels (various blends and microemulsions), to determine the engine performance at different engine loads (no load, and from 0.5 to 2.0 kW), and to estimate laboratory-scale cost of the selected biofuels compared to diesel and biodiesel. The results showed that phase stability and fuel properties of selected microemulsion biofuels are comparable to diesel and biodiesel. These microemulsion biofuels can be applied to the diesel engine at different loads while diesel-ethanol blends and palm-oil-biodiesel-ethanol blends cannot be. It was found that the energy efficiencies of the system using microemulsion biofuels were slightly lower than the average energy efficiency of diesel engine. From this study, it can be summarized that microemulsion biofuels can be formulated using palm-oil biodiesel (palm-oil methyl ester) as a bio-based surfactant and they can be considered as environmentally-friendly alternatives to diesel and biodiesel. However, cost considerations showed that the raw materials should be locally available to reduce additional costs of microemulsion biofuels.
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Cold Water Detergency of Triacylglycerol Semisolid Soils: The Effect of Salinity, Alcohol Type, and Surfactant Systems
(2019-09-01)
Phaodee, Parichat
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Attaphong, Chodchanok
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Sabatini, David A.
Cold water detergency of triacylglycerol semisolid soils is much more challenging than liquid vegetable oils due to poorer interaction between surfactants and semisolid soil. This research seeks to improve the removal efficiency of semisolid soils below their melting points using surfactant-based formulations containing different alcohol additives. To this end, cold water detergency of solid coconut oil and solid palm kernel oil was investigated in various surfactant/alcohol systems, including single anionic extended surfactants, single nonionic alcohol ethoxylate surfactants, and a mixture of anionic surfactants. A series of alcohols (2-butanol, 1-hexanol, 1-heptanol, 1-octanol, 1-nonanol, and 1-decanol) were added to the surfactant formulations to investigate cold water detergency improvement. While cold water detergency using surfactants alone was poor, it was considerably improved when optimum salinity (S*) and 1-heptanol, 1-octanol, or 1-nonanol were introduced to the studied surfactant formulations. The maximum detergency of solid coconut oil exceeded 90% removal in the 0.1 w/v% C<inf>14-15</inf>-8PO-SO<inf>4</inf>Na/0.2 w/v% 1-octanol/4 w/v% NaCl system (a final optimized surfactant system) at a washing temperature of 10°C versus 22.9 ± 2.2% in the surfactant alone (not at optimum salinity and no additive). Further analysis showed that improved cold water detergency using surfactant/intermediate-chain alcohols/NaCl could be correlated with high wettability (low contact angle) as well as favorable surfactant system-soil interaction as observed by lower interfacial tension values. In contrast, the improved cold water detergency was observed to be independent of dispersion stability. This work thus demonstrates that surfactant system design, including additives, can improve cold water detergency of semisolid soils and should be further explored in future research.
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Magnetization of NdFeB Permanent Magnet Considering Demagnetization Effect
(2018-11-27)
Sarikprueck, Piampoom
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Lumyong, Pichit
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Niroiana, Chamakorn Na
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Attaphong, Chodchanok
Electrical machine efficiency improvement has been paid more attention over the past years. Using Permanent Magnets (PMs) in various modern electrical machines is one of the most favorable approaches to increase machine efficiency. However, PMs still have a significant disadvantage that is the demagnetization issue. Therefore, these demagnetized PMs need to magnetize for regaining their initial capability considering the demagnetization level. Therefore, first of all, this paper proposes the demagnetization behavior of NdFeB PMs due to thermal effect. Then, these PMs are magnetized using a proposed simple magnetizing technique considering various demagnetization conditions. Finally, the results indicate that the most complete demagnetized PMs are able to significantly recover to their initial capability.
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Phase behaviors and fuel properties of palm oil-based microemulsion biofuels using sugar-based surfactants
(2017-07-12)
Attaphong, Chodchanok
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Charoensaeng, Ampira
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Sorrasuchart, Nutthaporn
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Khaodhiar, Sutha
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Arpornpong, Noulkamol
Due to environmental concerns and current fossil-fuel situations, palm oil has been considered as a potential vegetable oil for renewable biofuel applications in South East Asia. To solve durability problems in diesel engine caused by high viscosity of palm oil, microemulsification has led to more attention as a novel viscosity-reducing technique. Microemulsion biofuels are transparent, thermodynamically stable, and singlephase microemulsions, where the polar phase is solubilized in surfactant aggregates existing in the non-polar phase. Surfactants (surface active agents) play a key role in enhancement of the interaction between polar and non-polar phases. Since sugar-based surfactants have been derived from bio-based resources, they have been introduced to formulate microemulsion biofuels in this study. Three sugar-based surfactants, sorbitan monolaurate (SM20), sorbitan monooleate (SM80), and sorbitan trioleate (ST85) and three alcohols (butanol, hexanol, and octanol) were used as surfactants and co-surfactants, respectively. The objectives of this study are to formulate microemulsion biofuels using sugar-based surfactants, to study the effects of surfactants and co-surfactants on phase behaviors and kinematic viscosities, and to investigate the effect of surfactant/co-surfactant ratio on other fuel properties (i.e. energy content, cold flow properties, density, and ash content). The results show that the microemulsion system using SM80 and octanol at the molar ratio of 1 to 8 was considered as an optimized microemulsion biofuel formulation demonstrating comparable fuel properties to biodiesel. These results provide useful guidance for future design of environmentally friendly microemulsion biofuels.
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Analyzing technique for electrical energy monitoring system in Thailand hospital
(2017-07-12)
Sarikprueck, Piampoom
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Attaphong, Chodchanok
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Lumyong, Pichit
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Ngamwatthanasilpa, Bandit
An electrical energy monitoring system helps improve the security and reliability of a hospital operating system which can also indirectly enhance energy efficiency itself. However, a large hospital has a complex electrical system which leads to the big data issue from the installed monitoring system in this size-scaled hospital. Therefore, this paper proposes K-mean clustering technique, which is one of the effective data mining techniques, to analyze the big data from the electrical energy monitoring system in hospital. The case study is a large hospital with 200 in-patient beds in Thailand. Without loss of generality, electrical load profile is used for analyzing instead of using the electrical energy. Finally, the proposed data clustering technique is able to characterize electrical load profiles effectively for each hospital floor. This technique also identify the abnormality of these characterized electrical load profiles in various scenarios which hospital system operators can use them to consider the security, reliability, and energy efficiency of their operating systems.
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Effect of additives on fuel properties and emission characteristics of micromulsion biofuels from palm oil
(2017-07-12)
Attaphong, Chodchanok
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Lumyong, Pichit
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Wichadee, Sasiwimon
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Khaodhiar, Sutha
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Sarikprueck, Piampoom
Microemulsiflcation is one of the novel techniques to reduce viscosity of vegetable oils to avoid durability problems in diesel engines. Microemulsion biofuels are transparent, thermodynamically stable, and single-phase mixtures of vegetable oils and ethanol in the presence of surfactants and co-surfactants. Additives have also been included in microemulsion biofuel formulations to improve their stability and fuel properties; however, there is limited research on the effect of additives on emission characteristics of microemulsion biofuels. In this study, microemulsion biofuels were formulated from palm oil/diesel blend (1:1 v/v), ethanol, surfactant, and co-surfactants. Five additives, ethylene glycol butyl ether (EGBE), diethylene glycol ethyl ether (DEGEE), propylene glycol ethyl ether (PGEE), dipropylene glycol methyl ether (DPGME), and ethyl acetate (EA), were used to study the effect of additives on phase behaviors, fuel properties, and emission characteristics. The results showed that studied additives could improve some fuel properties of microemulsion biofuels with negligible effect on phase stability. Additionally, it was found that carbon monoxide (CO) emissions from microemulsion biofuels with DEGEE and EA, and nitrogen oxide (NOx) emissions from microemulsion biofuels with all additives were lower than those from diesel and biodiesel. Therefore, DEGEE and EA can be considered as promising additives for microemulsion biofuel formulations, which can improve fuel properties as well as can significantly reduce CO and NO<inf>x</inf> emissions below the levels of diesel and biodiesel. These encouraging results offer options of additives for biofuel applications.

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