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Item type:Publication, Effects of temperature and water vapour on Cr-species volatilisation, oxidation and scale adhesion of a Type 409L stainless steel for application as interconnect of low temperature solid oxide fuel cells(2024-06-01) ;Homjabok, Wanna ;Tengprasert, Watcharapon ;Thublaor, Thammaporn ;Wiman, PanyaNilsonthi, ThanasakThough the classical transport theory does not mathematically express the Arrhenius-like relation between Cr-loss flux due to volatilisation and absolute temperature, such relation was experimentally observed for 409L stainless steel exposed at 600–750 °C. Volatilisation calculation in the present cases can be estimated giving such relation because of the nearly linear relation between mass transfer coefficient and temperature. Cr-loss fluxes in O<inf>2</inf> with 20 and 40 % H<inf>2</inf>O are close to or coincided with the fluxes calculated from MnCr<inf>2</inf>O<inf>4</inf> evaporation. Increasing water vapour could enhance volatilisation contributed from the raised CrO<inf>2</inf>(OH)<inf>2</inf> pressure, reduce oxidation rate, and worsen scale adhesion. - Some of the metrics are blocked by yourconsent settings
Item type:Publication, Oxidation and volatilisation behaviour of a type 430 stainless steel coated by Mn-Co oxide by slurry method with pre-oxidation for SOFC interconnect application(2021-07-15) ;Chandra-ambhorn, Somrerk ;Homjabok, Wanna ;Chandra-ambhorn, Walairat ;Thublaor, ThammapornSiripongsakul, ThamrongsinAn AISI 430 stainless steel was coated by Mn-Co spinel using a slurry method. Pre-oxidation before the coating helped reduce the oxidation rate of the coated steel at 800 °C in O<inf>2</inf>-5%H<inf>2</inf>O, relating to the formation of the continuous chromia layer which inhibited the outward diffusion of iron to the coating layer. It also helped reduce the mass flux of Cr loss due to the volatilisation. The combined molecular and Knudsen diffusion of the volatile species through the coating layer was suggested to explain the reduced volatilisation rate of the coated sample with pre-oxidation.
