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Sustainable Synthesis of Calcium Propionate from Cockle Shell Biowaste for Food Additive Production
(2026-06-01)
Seangarun, Chaowared
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Boonchom, Banjong
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Seesanong, Somkiat
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Boonmee, Wimonmat
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Punthipayanon, Sirichet
Calcium propionate (Ca(CH<inf>3</inf>CH<inf>2</inf>COO)<inf>2</inf>) was successfully synthesized from cockle shell biowaste through a reaction with propionic acid at concentrations of 80%, 90%, and 99%, valorizing seafood processing biowaste as a renewable calcium source in support of circular economy principles. The synthesis was conducted at ambient temperature with a fixed CaCO<inf>3</inf>: propionic acid molar ratio of 1:2, enabling rapid reaction completion without external heating or complex purification steps. The prepared samples were characterized by FTIR, XRD, TGA, and SEM techniques, which confirmed the formation of calcium propionate monohydrate (Ca(CH<inf>3</inf>CH<inf>2</inf>COO)<inf>2</inf>·H<inf>2</inf>O), while XRF confirmed more than 97 wt% CaO across all samples with non-toxic impurities corresponding to compositional requirements for food additive calcium propionate (E282). The sample prepared using 80% propionic acid exhibited the highest yield (90.24%) and soluble percentage (98.23%). The proposed approach demonstrates an effective valorization of cockle shell waste into a food additive, calcium propionate, offering advantages in terms of sustainability, cost efficiency, and scalability, and highlighting its strong potential for industrial food additive production within a circular economy framework.
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Sustainable Production of Chitosan from Mussel Shells with Upcycling of Demineralization Effluent into Calcium Formate
(2026-05-01)
Seangarun, Chaowared
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Boonchom, Banjong
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Seesanong, Somkiat
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Boonmee, Wimonmat
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Punthipayanon, Sirichet
This study proposes a sustainable, integrated biorefinery approach to valorize mussel shell waste into high-value products, including chitin, chitosan, and calcium formate. Formic acid was employed as an effective demineralizing agent, enabling not only efficient mineral removal but also the direct conversion of the demineralization effluent into value-added calcium formate. The sequential extraction processes, demineralization, deproteinization, and decolorization, successfully yielded purified chitin (PCH), which was subsequently deacetylated to produce chitosan (CTS) with a degree of deacetylation of 85% and a molecular weight of 75 kDa. The physicochemical properties of all products were characterized using Fourier transform infrared spectroscopy (FTIR), X-ray diffraction (XRD), thermogravimetric analysis (TGA), and scanning electron microscopy (SEM). FTIR and XRD analyses confirmed the successful extraction of chitin and chitosan, demonstrating the feasibility of mussel shells as an alternative biopolymer source. In parallel, calcium formate (CCF) was obtained from the demineralization effluent with a yield of 94.19%, and its formation was verified by FTIR and XRD. Elemental analysis by XRF exhibited 98.3% CaO with minimal non-toxic impurities. The TGA/DTG profiles of CCF exhibited a well-defined two-step thermal decomposition, confirming its anhydrous form. Overall, this environmentally benign process enables the simultaneous production of multiple value-added products while significantly improving resource utilization and reducing waste generation. The proposed integrated biorefinery model offers a promising, economically viable pathway for marine biomass valorization, aligned with the Bio-Circular-Green (BCG) economy concept.
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Low-Cost and Rapid Production of Calcium Formate from Cockle Shell Waste for Sustainable Waste Recycling
(2026-04-01)
Seangarun, Chaowared
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Boonchom, Banjong
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Seesanong, Somkiat
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Boonmee, Wimonmat
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Punthipayanon, Sirichet
Calcium formate (Ca(HCOO)<inf>2</inf>) is an important industrial chemical widely used in construction, feed additives, and various chemical processes. In this work, calcium formate was synthesized from cockle shell waste and concentrated formic acid (50%, 60%, and 70% w/w) by a simple, rapid, low-cost, and environmentally friendly process, denoted as CF50, CF60, and CF70, respectively. The chemical and physical properties of as-synthesized calcium formate using cockle shells as a renewable calcium source were investigated by Fourier transform infrared (FT-IR), X-ray diffraction (XRD), X-ray fluorescence (XRF), Thermal gravimetric analysis (TGA), and scanning electron microscopy (SEM) techniques. The FTIR and XRD results revealed that the samples prepared using 50% and 60% formic acid produced well-crystallized α-calcium formate. In contrast, the reaction using 70% formic acid generated a strongly exothermic reaction, which hindered the complete conversion of calcium carbonate and resulted in the presence of residual CaCO<inf>3</inf> in the final product. Similarly, the SEM images of the CF50 and CF60 samples show the slick surface of orthorhombic crystals of calcium formate; on the other hand, the SEM image of CF70 shows some small particles of aragonite on the surface of the calcium formate crystals. The 60% formic acid provided the optimal synthesis condition, yielding pure calcium formate with the shortest synthesis time. Overall, the proposed approach provides a simple, rapid, and cost-effective route for producing calcium formate from shell waste. Furthermore, the utilization of cockle shell waste as a renewable calcium source contributes to waste valorization, reduces environmental impacts associated with shell disposal, and minimizes dependence on mined limestone resources, supporting sustainable resource utilization within a circular economy.
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Valorization of Mussel Shell Waste to Chitin, Chitosan, and Calcium Lactate for Bio-Green-Circular Management
(2026-04-01)
Seangarun, Chaowared
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Seesanong, Somkiat
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Boonchom, Banjong
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Boonmee, Wimonmat
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Punthipayanon, Sirichet
This study presents a green bio-upcycling strategy for converting mussel shell biowaste into three value-added products: chitin, chitosan, and calcium lactate. Mussel shells were treated chemically with lactic acid during demineralization, yielding a solid fraction rich in chitin and a liquid fraction containing calcium and lactate ions. The solid fraction was sequentially purified by deproteinization and decolorization, then deacetylated to obtain chitosan, while the liquid fraction was evaporated to obtain calcium lactate. Notably, 2.37 g of raw chitin, 2.15 g of purified chitin, and 275.87 g of calcium lactate were obtained from 100 g of mussel shells, demonstrating the efficiency of the process. FTIR spectra revealed characteristic absorption bands corresponding to α-chitin and chitosan functional groups, while XRD patterns indicated the crystalline α-chitin structure and the formation of calcium lactate pentahydrate. TGA demonstrated the high thermal stability of chitin and chitosan and confirmed the presence of crystallization water in calcium lactate. In conclusion, these results confirmed the successful preparation of α-chitin, chitosan, and calcium lactate pentahydrate, with improved purity compared to previous studies. This approach highlights the potential of the green bio-upcycling process of mussel shell waste as a renewable source for the eco-friendly production of biopolymers and calcium salts, supporting sustainable waste management and the development of the Bio-Circular-Green (BCG) economy.
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A Biomathematical Clustering Framework for Classifying Neuromechanical Performance Profiles in Amateur Boxers
(2026-01-01)
Punthipayanon, Sirichet
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Chottidao, Monchai
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Manilam, Surasak
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Thongtha, Kaboon
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Pochai, Nopparat
Boxing effectiveness is strongly influenced by neuromuscular power generation and the efficient transmission of force through the lower extremities; however, traditional evaluation methods tend to assess these variables in isolation across athletes. A biomathematical clustering strategy provides a structured approach to extracting coherent performance patterns from complex, multidimensional biomechanical datasets. The present investigation proposes a biomathematical clustering model to categorise amateur boxers and quantify between-cluster variation, thereby facilitating tailored training interventions. A cohort of 30 amateur competitors underwent a series of standardised biomechanical tests, including Muscle Power (MP), reaction time (RT), rear-leg ground reaction force (GRF) relative to body mass, and maximal cross-punch (MCP) force output. Before analysis, all variables were rescaled through min–max normalisation. Unsupervised classification was executed via K-means clustering. The quality of clustering was assessed using indices of compactness and separation, specifically the Dunn Index and Davies–Bouldin Index. In contrast, the appropriate cluster count was determined using within-cluster sum of squares (WCSS) interpreted via the elbow method. Statistical procedures, including post hoc testing and effect size computation, were applied to evaluate intergroup differences. Additionally, principal component analysis (PCA) was utilised to project the data into a reduced-dimensional space for clearer visual interpretation of cluster distinctiveness. All computational procedures were implemented in Python. The analysis supported a three-cluster configuration. Cluster 3 (40%) exhibited superior performance characteristics, including elevated MP (7,700 ± 3,500 W), reduced RT (0.18 ± 0.03 s), and greater rear-leg GRF (1.55 ± 0.18 BW) relative to Cluster 2 (p ≤ 0.002; d = 1.35–2.45). In contrast, Cluster 2 (46.7%) was characterised by diminished MP (4,000 ± 1,400 W) and prolonged RT (0.26 ± 0.07 s), whereas Cluster 1 (13.3%) showed moderate values across all measured variables. The biomathematical clustering framework successfully distinguishes discrete neuromechanical profiles among amateur boxers, thereby enabling cluster-specific training strategies and enhancing individual performance optimisation.
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A Simple and Rapid Synthesis of Spherical Silver Phosphate (Ag3PO4) and Its Antimicrobial Activity in Plant Tissue Culture
(2025-08-01)
Laohavisuti, Nongnuch
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Boonchom, Banjong
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Rungrojchaipon, Pesak
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Boonmee, Wimonmat
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Seesanong, Somkiat
A simple and rapid precipitation process was successfully employed to prepare silver phosphate (SP, Ag<inf>3</inf>PO<inf>4</inf>). Two different phosphate sources: diammonium hydrogen phosphate ((NH<inf>4</inf>)<inf>2</inf>HPO<inf>4</inf>) and dipotassium hydrogen phosphate (K<inf>2</inf>HPO<inf>4</inf>) were applied separately as the precursor, obtaining ((NH<inf>4</inf>)<inf>2</inf>HPO<inf>4</inf>)− and K<inf>2</inf>HPO<inf>4</inf>− derived SP powders, named SP-A or SP-P, respectively. Fourier transform infrared (FTIR) spectra pointed out the vibrational characteristics of P–O and O–P–O interactions, confirming the presence of the PO43– functional group for SP. X-ray diffraction (XRD) patterns revealed that the SP crystallized in a cubic crystal structure. Whereas the field emission scanning electron microscope (FESEM) exposed spherical SP particles. The potentially antibacterial activity of SP-A and SP-P against bacterial Bacillus stratosphericus, yeast Meyerozyma guilliermondii, and fungal Phanerodontia chrysosporium was subsequently investigated. All studied microorganisms were recovered and isolated from the aquatic plant during the tissue culture process. The preliminary result of the antimicrobial test revealed that SP-A has higher antimicrobial activity than SP-P. The superior antimicrobial efficiency of SP-A compared to SP-P may be attributed to its purity and crystallite size, which provide a higher surface area and more active sites. In addition, the presence of potassium-related impurities in SP-P could have negatively affected its antimicrobial performance. These findings suggest that SP holds potential as an antimicrobial agent for maintaining sterility in tissue cultures, particularly in aquatic plant systems. The growth of both B. stratosphericus and M. guilliermondii was suppressed effectively at 30 ppm SP-A, whereas 10 ppm of SP-A can suppress P. chrysosporium development. This present work also highlights the potential of SP at very low concentrations (10–30 ppm) for utilization as an effective antimicrobial agent in tissue culture, compared to a commercial antimicrobial agent, viz., acetic acid, at the same concentration.
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Extraction of Chitin, Chitosan, and Calcium Acetate from Mussel Shells for Sustainable Waste Management
(2025-08-01)
Seangarun, Chaowared
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Seesanong, Somkiat
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Boonchom, Banjong
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Laohavisuti, Nongnuch
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Rungrojchaipon, Pesak
In this paper, mussel shells were used to produce chitin, chitosan, and calcium acetate using chemical processes, searching for an alternative environmentally friendly biopolymer and calcium source. Mussel shells were treated with acetic acid as a demineralizing agent, resulting in separate solid fractions and calcium solution. The solid was further purified to produce chitin by deproteinization and decolorization processes, and then the deacetylation process was used to obtain chitosan. The calcium solution was evaporated to produce calcium acetate powder. The yields of extracted chitin, chitosan, and calcium acetate from 100 g of mussel shells were 2.98, 2.70, and 165.23 g, respectively. The prepared chitin, chitosan, and calcium acetate were analyzed by Fourier transform infrared (FTIR) spectrophotometry, X-ray diffraction (XRD), thermogravimetric analysis (TGA), and scanning electron microscope (SEM) to confirm the chemical and physical properties. The analysis results of chitin and chitosan revealed the similarity to chitosan derived from crustaceans and insects in terms of functional group, structure and morphologies. The prepared calcium acetate shows FTIR and XRD data corresponding to calcium acetate monohydrate (Ca(CH<inf>3</inf>COO)<inf>2</inf>·H<inf>2</inf>O) similar to synthesized calcium acetate in previous research. In addition, the mineral contents of calcium acetate identified by X-ray fluorescence (XRF) analysis exhibit 97.8% CaO with non-toxic impurities. This work demonstrated the potential of the production process of chitin, chitosan, and calcium acetate for the development of a sustainable industrial process with competitive functional performance against the commercial chitin and chitosan production process using crustacean shells and supported the implementation of a circular economy.
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Health Behavior and Emotional Responses of Thai National Team Athletes during the COVID-19 Pandemic: A Comparative Study of Individual and Team Sports
(2025-08-01)
Pluemsamran, Theeratheeta
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Pariyavuth, Pariya
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Pochai, Nopparat
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Panurushthanon, Phichayavee
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Punthipayanon, Sirichet
Objectives: COVID-19 significantly impacted athletes’ health behavior and emotional well-being. Disruptions to training routines, competition schedules, and social structures raised concerns about psychological resilience, especially for elite athletes. In this study, we (1) adapted and validated the Emotional State Questionnaire (EST-Q-2) for Thai athletes, (2) examined the emotional responses and associated health behavior patterns of Thai national team athletes during the COVID-19 pandemic, and (3) compared emotional states between individual and team sport athletes. Methods: We surveyed 280 Thai national team athletes (146 male, 134 female) preparing for the 19th Asian Games. Participants completed the culturally adapted EST-Q-2, measuring 5 dimensions: depression, general anxiety, panic disorder, fatigue, and insomnia. We compared emotional responses by sport type. Results: The most prominent symptoms reported were fatigue and insomnia (M = 3.26), general anxiety (M = 2.84), depression (M = 2.35), and panic disorder (M = 2.17). We found no statistically significant differences between individual and team sport athletes across emotional dimensions. The adapted EST-Q-2 demonstrated strong reliability (Cronbach’s α = 0.80). Conclusion: The COVID-19 pandemic adversely affected the emotional states and health behavior of Thai national athletes, with high levels of fatigue and sleep disturbances. The lack of significant differences between sport types indicates a universal psychological impact, underscoring the need for targeted mental health interventions regardless of sport category.
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Influence of Organic Solvent on the Physicochemical Characteristics of Calcium Citrate Prepared from Mussel Shell Waste
(2025-06-01)
Punthipayanon, Sirichet
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Chanwetprasat, Pantita
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Seesanong, Somkiat
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Boonchom, Banjong
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Rungrojchaipon, Pesak
A green and mild chemical reaction of calcium citrate (CC) was successfully prepared from reactions between mussel shell waste and citric acid in the presence of acetone (AC), ethanol (Et), and isopropyl alcohol (IPA). All the synthesized CCs contained the same functional groups such as citrate (C<inf>6</inf>H<inf>5</inf>O<inf>7</inf>3−), water (H<inf>2</inf>O), and calcium–oxygen (Ca–O). However, the differences in the spectra pointed out the differences in the crystal environment and structure of CCs. CC-AC and CC-IPA mainly crystallized in the monoclinic [Ca<inf>3</inf>(C<inf>6</inf>H<inf>5</inf>O<inf>7</inf>)<inf>2</inf>(H<inf>2</inf>O)<inf>2</inf>]·2H<inf>2</inf>O crystal system, whereas CC-Et mainly crystallized in the triclinic Ca<inf>3</inf>(C<inf>6</inf>H<inf>5</inf>O<inf>7</inf>)<inf>2</inf>∙(H<inf>2</inf>O)<inf>4</inf> structure. The molecular alignments of triclinic CC-Et were different from monoclinic CC-AC and CC-IPA, resulting in differences in thermal behaviors. Two dehydration steps were observed for the monoclinic CC-AC and CC-IPA, whereas the triclinic CC-Et showed a single dehydration process. The TG mass losses further demonstrated that anhydrous Ca<inf>3</inf>(C<inf>6</inf>H<inf>5</inf>O<inf>7</inf>)<inf>2</inf> phase, in addition to the Ca<inf>3</inf>(C<inf>6</inf>H<inf>5</inf>O<inf>7</inf>)<inf>2</inf>∙4H<inf>2</inf>O, was also observed for CC-AC and CC-IPA, whereas CC-Et contained a single Ca<inf>3</inf>(C<inf>6</inf>H<inf>5</inf>O<inf>7</inf>)<inf>2</inf>∙(H<inf>2</inf>O)<inf>4</inf> phase. The morphologies of CC-AC and CC-IPA also differed from that of CC-Et. The differences in some properties of the synthesized CCs could be attributed to the change in the supersaturation state of the reaction solution. Due to the superior polarity, ethanol is more compatible with citric acid. The presence of ethanol could suppress the supersaturation rate of the reaction solution, causing the modulation of the precipitation mechanisms and reducing the particle growth rate of CC-Et, thereby explaining the difference in vibrational, structural, thermal, and morphological characteristics of CC-Et, compared to CC-AC and CC-IPA.
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Cockle-shell biowaste as a low-cost renewable source for synthesis of calcium acetate monohydrate as a precursor of quasi-amorphous calcium pyrophosphate hydrate
(2025-01-01)
Thompho, Somphob
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Laohavisuti, Nongnuch
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Seangarun, Chaowared
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Boonchom, Banjong
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Rungrojchaipon, Pesak
Calcium-rich seashell wastes can be used as renewable materials to prepare value-added compounds. This work proposed an eco-environmental preparation of calcium pyrophosphate by using cockle-shell biowaste as a low-cost renewable calcium source for the first time. Cockle shell was first ground, obtaining calcium carbonate (CaCO<inf>3</inf>) powders, which were then used as the renewable material to synthesize calcium acetate monohydrate (Ca(CH<inf>3</inf>COO)<inf>2</inf>·H<inf>2</inf>O) via acetic acid reaction. After that, cockle-derived calcium acetate monohydrate was subsequently prepared as a solution to synthesize calcium pyrophosphate (Ca<inf>2</inf>P<inf>2</inf>O<inf>7</inf>·xH<inf>2</inf>O) via a simple precipitation process with tetrasodium pyrophosphate decahydrate (Na<inf>4</inf>P<inf>2</inf>O<inf>7</inf>·10H<inf>2</inf>O). The physicochemical characteristics of the synthesized calcium acetate precursor and its calcium pyrophosphate product were investigated by X-ray fluorescence, X-ray diffraction, Fourier transform infrared spectroscopy, thermogravimetry, and scanning electron microscopy. The characterization results demonstrate that cockle shell powder (CaCO<inf>3</inf>) is a potentially renewable source for the preparation of triclinic calcium acetate with the chemical formula of Ca(CH<inf>3</inf>COO)<inf>2</inf>·H<inf>2</inf>O, which was further used as the precursor to form value-added amorphous calcium pyrophosphate with the chemical formula of Ca<inf>2</inf>P<inf>2</inf>O<inf>7</inf>·4H<inf>2</inf>O. This approach not only demonstrates the feasibility of using biogenic Ca-sources for material synthesis but also offers an environmentally friendly process with potential long-term benefits in reducing environmental issues, promoting sustainable chemical production, and increasing value to the underused biowaste.

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