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    Item type:Publication,
    Analysis of the Pomelo Peel Essential Oils at Different Storage Durations Using a Visible and Near-Infrared Spectroscopic on Intact Fruit
    (2024-08-01) ;
    Duangchang, Jittra
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    ; ;
    Shrestha, Bim Prasad
    Pomelo fruit pulp mainly is consumed fresh and with very little processing, and its peels are discarded as biological waste, which can cause the environmental problems. The peels contain several bioactive chemical compounds, especially essential oils (EOs). The content of a specific EO is important for the extraction process in industry and in research units such as breeding research. The explanation of the biosynthesis pathway for EO generation and change was included. The chemical bond vibration affected the prediction of EO constituents was comprehensively explained by regression coefficient plots and x-loading plots. Visible and near-infrared spectroscopy (VIS/NIRS) is a prominent rapid technique used for fruit quality assessment. This research work was focused on evaluating the use of VIS/NIRS to predict the composition of EOs found in the peel of the pomelo fruit (Citrus maxima (J. Burm.) Merr. cv Kao Nam Pueng) following storage. The composition of the peel oil was analyzed by gas chromatography–mass spectrometry (GC-MS) at storage durations of 0, 15, 30, 45, 60, 75, 90, 105 and 120 days (at 10 °C and 70% relative humidity). The relationship between the NIR spectral data and the major EO components found in the peel, including nootkatone, geranial, β-phellandrene and limonene, were established using the raw spectral data in conjunction with partial least squares (PLS) regression. Preprocessing of the raw spectra was performed using multiplicative scatter correction (MSC) or second derivative preprocessing. The PLS model of nootkatone with full MSC had the highest correlation coefficient between the predicted and reference values (r = 0.82), with a standard error of prediction (SEP) of 0.11% and bias of 0.01%, while the models of geranial, β-phellandrene and limonene provided too low r values of 0.75, 0.75 and 0.67, respectively. The nootkatone model is only appropriate for use in screening and some other approximate calibrations, though this is the first report of the use of NIR spectroscopy on intact fruit measurement for its peel EO constituents during cold storage.
      1
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    Primary assessment of macronutrients in durian (CV Monthong) leaves using near infrared spectroscopy with wavelength selection
    (2024-01-05) ;
    Jaisue, Natthapon
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    Worphet, Akarawhat
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    Tawinteung, Nukoon
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    Farmers would be able to regulate fertilization and produce quality durian if they knew the nutrient concentration in durian leaves. A long period of time for traditional nutritional content determination is needed. Therefore, near-infrared spectroscopy is a good method for nondestructive and quick nutrient content evaluation. The leaf sample matrices (fresh leaves, dried ground leaves, and dried ground leaf pellets) were scanned by Fourier transform near-infrared (FT-NIR) with a wavelength of 12,500–3,600 cm<sup>−1</sup>. Regression models were developed using partial least squares (PLS) with full wavelength, short wavelength, and selected wavelength by successive projections algorithm (SPA). In this study, the model for N and K concentration was acceptable and the prediction was considered good but for P content not had succeeded. As a result, the PLS-SPA model using fresh leaf samples for evaluating N content in durian leaves exhibited performance of r<sup>2</sup> = 0.852, SEP = 0.14%, RPD = 2.63 and bias = −0.020%. The PLS-SPA model using dried ground leaf samples for evaluating K content in durian leaves exhibited performance of r<sup>2</sup> = 0.820, SEP = 0.13%, RPD = 2.36 and bias = 0.006%. This research found that it is possible to apply NIR waves to predict N and K concentrations in durian leaves. It is not necessary to predict directly from the wavelengths associated with -N or -K bonds. Instead, NIR can measure them indirectly from the bonding of proteins, which are products formed by N and K. In addition, selecting the wavelength that is related to the value to be measured can produce results that are not significantly different from using full or short wavelengths. These models can assist farmers in rapidly predicting N and K content in durian leaves for immediate fertilizer adjustment.
      2
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    Item type:Publication,
    Classification of the Crosslink Density Level of Para Rubber Thick Film of Medical Glove by Using Near-Infrared Spectral Data
    (2024-01-01) ;
    Howimanporn, Suppakit
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    Sitorus, Agustami
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    ;
    Posom, Jetsada
    Classification of the crosslink density level of para rubber medical gloves by using near-infrared spectral data combined with machine learning is the first time reported in this paper. The spectra of medical glove samples with different crosslink densities acquired by an ultra-compact portable MicroNIR spectrometer were correlated with their crosslink density levels, which were referencely evaluated by the toluene swell index (TSI). The machine learning protocols used to classify the 3 groups of TSI were specified as less than 80% TSI, 80–88% TSI, and more than 88% TSI. The 80–88% TSI group was the group in which the compounded latex was suitable for medical glove production, which made the glove specification comply with the requirements of customers as indicated by the tensile test. The results show that when comparing the algorithms used for modeling, the linear discriminant analysis (LDA) developed by 2nd derivative spectra with 15 k-best selected wavelengths fairly accurately predicted the class but was most reliable among other algorithms, i.e., artificial neural networks (ANN), support vector machines (SVM), and k-nearest neighbors (kNN), due to higher prediction accuracy, precision, recall, and F1-score of the same value of 0.76 and no overfitting or underfitting prediction. This developed model can be implemented in the glove factory for screening purposes in the production line. However, deep learning modeling should be explored with a larger sample number required for better model performance.
      1
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    Cognitive spectroscopy for the classification of rice varieties: A comparison of machine learning and deep learning approaches in analysing long-wave near-infrared hyperspectral images of brown and milled samples
    (2022-06-01) ;
    Ma, Te
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    Inagaki, Tetsuya
    ;
    ;
    Tsuchikawa, Satoru
    Rapid and non-destructive detection of genuine Thai Jasmine rice (Khao Dawk Mali 105 (KDML105)) from Pathum Thani1 (PTT1) and Phitsanulok2 (PSL2) under either milled or brown conditions is required to disrupt fraudulent. This study aimed to resolve this real issue using long-wave near infrared hyperspectral imaging (NIR-HSI) coupled with machine learning and deep learning approaches. The best classification accuracy for the milled rice was achieved using the spectral imaging-based analysis on the NIR-HSI data with selected wavelength, approximately 95% for the test set either by convolutional neural network or support vector machine (SVM), whereas for the brown rice, the SVM model based on the averaged NIR spectra could achieve the best classification accuracy of 95.4%. It suggests the chemical component difference and its spatial distribution in the milled rice could contribute higher classification accuracy. Additionally, the surface bran effects of brown rice could be reduced by using averaged spectral data coupled with the SVM method.
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    Item type:Publication,
    High accuracy rapid prediction and feasibility of on-site nondestructive estimation of Para rubber quality by spectroscopic methods
    (2013-04-01)
    Inagaki, Tetsuya
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    Liu, Chang
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    Thanapase, Warunee
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    Tsuchikawa, Satoru
    The aim of this study was to investigate convenient spectroscopic evaluation method of Para rubber quality. Ultra violet-near infrared (UV-NIR 370-1085 nm) spectra of latex were measured in transmittance mode. Calibrations for total solid content (TSC) and dry rubber content (DRC) were developed using spectral data set with aid of partial least square regression analysis using 57 samples. UV-NIR spectra of latex provided good regression models between measured and predicted values of TSC and DRC with determination coefficient for cross-validation of 0. 96 and 0. 97, respectively. The ranks were 2 and 1, respectively. This study suggests high accuracy in-line quality control of latex using UV-NIR spectroscopy. The long wavelength NIR spectra of bark were scanned to check the feasibility of on-site evaluation of latex quality by measuring the NIR spectra of standing tree. From the observation of near infrared spectra, it was shown that there was more latex signal in outer part of wood bark than in inner part of wood bark. This result suggests that the focal point should be on the outer part of bark to get the signal of latex when we measure the spectra of standing tree. © 2012 The Japan Wood Research Society.
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