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Author: search.filters.author.Arpornwichanop, AmornchaiSubject: search.filters.subject.Modeling

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    Item type:Publication,
    Flowsheet-based model and exergy analysis of solid oxide electrolysis cells for clean hydrogen production
    (2018-01-01)
    Im-orb, Karittha
    ;
    Visitdumrongkul, Nuttawut
    ;
    Saebea, Dang
    ;
    Patcharavorachot, Yaneeporn
    ;
    Arpornwichanop, Amornchai
    A solid oxide electrolysis cell (SOEC) is an electrochemical technology used for hydrogen production via a steam electrolysis reaction. Because the existing SOEC models are complicated, the aim of this study is to develop a user-friendly SOEC model in a flowsheet simulator (Aspen Plus). The developed model is used to perform a parametric analysis to investigate the effects of key process parameters, i.e., operating temperature, current density, steam concentration, sweep gas type and number of cells, on the SOEC performance. The simulation results show that the voltage and the overall overpotential decrease as the cell temperature increases, whereas the opposite trends are observed when the current density increases. From the energy and exergy analyses, the total energy demand slightly increases with cell temperature, whereas the electrical energy demand decreases. Based on an operating temperature of 1273 K when the SOEC uses oxygen as the sweep gas, the highest energy and exergetic efficiencies of 78.45% and 92.20% are achieved at a current density of 2500 A m<sup>−2</sup> and at a steam concentration of 90% in a 500-cell stack.
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    Performance comparison of solid oxide steam electrolysis cells with/without the addition of methane
    (2016-07-15)
    Patcharavorachot, Yaneeporn
    ;
    Thongdee, Sirapa
    ;
    Saebea, Dang
    ;
    Authayanun, Suthida
    ;
    Arpornwichanop, Amornchai
    Hydrogen is considered a clean energy carrier for the future. At present, the production of hydrogen via a solid oxide electrolysis cell is of interest because water is the only reactant used; however, hydrogen production through electrolysis technology is still costly due to high electrical energy consumption. To reduce this energy demand, an addition of methane to the anode side of the solid oxide electrolysis cell, where it behaves like the anode side of the solid oxide fuel cell and generates heat and electricity to accomplish the electrolysis process, is one interesting method. In this study, modeling of the solid oxide fuel-assisted electrolysis cell is performed based on an electrochemical model to analyze the performance of the electrolyzer with/without the addition of methane in terms of the power input and the energy efficiency. In addition, the effect on the electrolyzer cell by key operating parameters, such as current density, steam fraction, steam-to-carbon ratio, temperature, pressure, steam utilization and fuel utilization, is presented. The simulation analysis shows that the performance of the solid oxide fuel-assisted electrolysis cell is higher than that of conventional solid oxide electrolysis cell, as it requires a lower power input. Furthermore, it is possible to run the solid oxide fuel-assisted electrolysis cell without an external electrical energy input.