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Highly active and stable Ni–W/SiO2 catalyst derived from W incorporated on Ni phyllosilicate for deoxygenation of triglycerides into green biofuel range hydrocarbons
(2025-10-01)
Praikaew, Wanichaya
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Prameswari, Jedy
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Ratchahat, Sakhon
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Chaiwat, Weerawut
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Sakdaronnarong, Chularat
Highly active and stable Ni–W/SiO<inf>2</inf> catalyst derived from W incorporated into Ni phyllosilicate (Ni-PS) was prepared by the ammonia evaporation (AE) method, and benchmarked with the catalyst prepared by the impregnation method (IM). Their catalytic activities were evaluated for deoxygenation of triglycerides into green biofuel-range hydrocarbons. The Ni-PS structure demonstrated a large surface area with strong interaction between Ni2+ and SiO<inf>2</inf>, resulting from the incorporation of Ni2+ into the silica framework, which led to highly dispersed Ni⁰ after H<inf>2</inf> reduction. Additionally, the H<inf>2</inf> adsorption and desorption capabilities, together with a substantial quantity of Lewis acid sites, were advantageous features of Ni-PS catalysts compared to Ni-IM and 5 W/Ni-IM catalysts. Ex situ and in situ structural characterizations revealed the generation of Ni⁰ and W⁰ states, along with remaining W4+ species after H<inf>2</inf> reduction. The 5 W/Ni-AE catalyst exhibited stable performance up to 60 h on stream, producing consistent yields of 30 % jet fuel and 40 % diesel, which was attributed to its high porosity, small Ni⁰ particle sizes, enhanced H<inf>2</inf> adsorption–desorption capacities, and abundant Lewis acid sites. Consequently, the heterogeneous 5 W/Ni-AE catalyst shows significant practical relevance for generating green biofuel from oil-derived feedstock in sustainable biorefineries.
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Overview of biorefinery
(2022-01-01)
Thongchul, Nuttha
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Charoensuppanimit, Pongtorn
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Anantpinijwatna, Amata
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Gani, Rafiqul
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Assabumrungrat, Suttichai
A strong reliance on fossil resources gives rise to a depletion of nonrenewable resources and negative or harmful environmental impacts. Circumvention of this energy-environment nexus has been proposed through the application of the concept of biorefinery. In this concept, biomass, an alternative renewable feedstock containing C-rich chemicals, is utilized as a replacement of the fossil-based feedstock to produce bioenergy and bio-based chemicals. Originally, biorefinery was perceived as a platform of biomass processing, which would produce primarily fuels and chemicals. To date, biorefinery harnesses a variety of sustainable and synergetic technologies that converts biomass into a wide range of profitable products such as food-and-feed for the future, biopharmaceuticals, and nutraceuticals. Due to variability of feedstock and newly emerged technologies, classifications of biorefinery are diverse and depend on the basis (e.g., source of a biomass, the generation of a feedstock, etc.) taken in consideration. A comprehensive view of biorefinery requires the consideration of processing of biomass from different origins via diversified technology platforms. Since the concept of biorefinery also concerns social aspects and location-specific technologies, various aspects of stakeholders including academia, industry, economy, and society need also to be considered. Collaboration among the various actors is facilitated if necessary key information is easily accessible. Therefore, an overview of biorefinery should cover key information related to biorefinery, such as nature of biomass, current situation, available technologies, process design methods, associated tools, and analyses of processing routes along with case studies. In this chapter, the indices representing the key information related to biorefinery are arranged alphabetically and tabulated to enhance a good understanding of the concept of biorefinery.
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Complete design case study for pulp and paper industry
(2022-01-01)
Anantpinijwatna, Amata
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Charoensuppanimit, Pongtorn
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Mongkhonsiri, Ghochapon
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Gani, Rafiqul
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Assabumrungrat, Suttichai
Pulp and paper industry is a traditional biorefinery system that produces low margin paper products at low innovation development. It needs business transformation to enhance profitability along with efficient material and energy consumption through process development of high-value bioproducts. In response to climate change concerns and declining petroleum resources, the concept of biorefinery has developed using biochemical and thermochemical technologies. To develop biorefinery together with the conventional pulp and paper industry, integrated biorefinery in the existing pulp mill has been designed as a long-term sustainable solution. A systematic framework is needed to synthesize and design promising integrated systems from numerous alternatives. A three-level methodology, involving Level-1 Base Case Design, Level-2 Optimization and Analysis, and Level-3 Innovation, is proposed as an effective approach to determine optimal technologies suitable for the transformation of the traditional system through superstructure optimization, process analysis, and process improvement in terms of economic and environmental issues. To achieve a sustainable development of the integrated biorefinery system, innovative alternatives are discovered to satisfy improvement targets. Computer-aided tools are employed to support systematic data collection, mathematical model formulation, and complicated problem solving. Case studies of synthesis, design and innovation tasks illustrating the application of the framework to obtain promising integrated pulp mill-biorefinery alternatives are presented.
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Novel biorefinery-Integrated-Kraft-pulping network for sustainable development
(2021-06-01)
Mongkhonsiri, Ghochapon
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Anantpinijwatna, Amata
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Charoensuppanimit, Pongtorn
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Arpornwichanop, Amornchai
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Gani, Rafiqul
Integration of the biorefinery concept to the existing Kraft-pulping process is undertaken to achieve a more sustainable development. This paper aims at developing a novel biorefinery-integrated-Kraft-pulping network with improved profitability, energy self-sufficiency and minimum CO<inf>2</inf> emission by employing technologies consisting of biofuel and biochemical productions, biomass gasification together with CO<inf>2</inf> capture and utilization. Three scenarios, including (I) the production of gasification-based dimethyl ether (DME); (II) the co-production of DME and succinic acid; and (III) the co-production of DME and succinic acid coupled with the CO<inf>2</inf> utilization, have been investigated. Among all scenarios, Scenario II exhibits the best economic performances as highlighted by the 74% increase of profit compared to the conventional process. Scenario III achieves the highest energy efficiency at 39% and an improved environmental performance due to the 65% reduction of CO<inf>2</inf> emission compared to the conventional process with only 0.7% profit reduction. Comparing to the biorefinery-integrated-Soda-pulping networks proposed by the previous work, the biorefinery-integrated-Kraft-pulping networks show higher performance on both economic and environmental improvements. Thereby confirming that the integration of the biorefinery network can improve the sustainability and enhance the economic benefit of the Kraft-pulping process beyond the conventional process.
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Process development of sustainable biorefinery system integrated into the existing pulping process
(2020-05-10)
Mongkhonsiri, Ghochapon
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Charoensuppanimit, Pongtorn
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Anantpinijwatna, Amata
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Gani, Rafiqul
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Assabumrungrat, Suttichai
The change of paper consumption trend may jeopardize the future of pulp and paper industry. This work aims to design and develop the integrated network of biochemical and biofuel productions into existing pulp mills for sustainable purposes. The systematic methodology aided by computation tools is undertaken using the three-stage approach including process synthesis, design and innovation. Previously, the optimal technologies of the biorefinery-integrated pulping processes were successfully determined in the synthesis stage providing the highest cost-effective incorporation; 48 million USD/year of profit was estimated according to the integration of succinic acid and dimethyl ether productions into the soda pulping process. Herein, the process designs of the integrated processes were performed followed by evaluations of the process performances and identifications of the hot spots and targets for establishments of the innovations. In this work, the biomass gasification option is designed and implemented to enhance the material and energy utilizations in the previously determined biorefinery-integrated pulping processes. Electricity and biofuel are produced and sold, which contributes positively to the economic and environmental impacts of these processes. The hot spots and targets are subsequently identified prior to the innovation stage. According to this stage, the cleaner alternatives that implements the CO<inf>2</inf> utilization via methanol synthesis and solar cell installations are selected in order to minimize the CO<inf>2</inf> emission. A net CO<inf>2</inf> reduction of 42% is achieved when the cleaner alternatives are applied. Accordingly, these biorefinery-integrated innovations are not only conducive to the enhanced sustainability of existing pulp mills but also adaptive in response to the change of paper consumption trend.

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