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Author: search.filters.author.Attaphong, ChodchanokSubject: search.filters.subject.Biofuel

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    Phase behaviors and fuel properties of palm oil-based microemulsion biofuels using sugar-based surfactants
    (2017-07-12)
    Attaphong, Chodchanok
    ;
    Charoensaeng, Ampira
    ;
    Sorrasuchart, Nutthaporn
    ;
    Khaodhiar, Sutha
    ;
    Arpornpong, Noulkamol
    Due to environmental concerns and current fossil-fuel situations, palm oil has been considered as a potential vegetable oil for renewable biofuel applications in South East Asia. To solve durability problems in diesel engine caused by high viscosity of palm oil, microemulsification has led to more attention as a novel viscosity-reducing technique. Microemulsion biofuels are transparent, thermodynamically stable, and singlephase microemulsions, where the polar phase is solubilized in surfactant aggregates existing in the non-polar phase. Surfactants (surface active agents) play a key role in enhancement of the interaction between polar and non-polar phases. Since sugar-based surfactants have been derived from bio-based resources, they have been introduced to formulate microemulsion biofuels in this study. Three sugar-based surfactants, sorbitan monolaurate (SM20), sorbitan monooleate (SM80), and sorbitan trioleate (ST85) and three alcohols (butanol, hexanol, and octanol) were used as surfactants and co-surfactants, respectively. The objectives of this study are to formulate microemulsion biofuels using sugar-based surfactants, to study the effects of surfactants and co-surfactants on phase behaviors and kinematic viscosities, and to investigate the effect of surfactant/co-surfactant ratio on other fuel properties (i.e. energy content, cold flow properties, density, and ash content). The results show that the microemulsion system using SM80 and octanol at the molar ratio of 1 to 8 was considered as an optimized microemulsion biofuel formulation demonstrating comparable fuel properties to biodiesel. These results provide useful guidance for future design of environmentally friendly microemulsion biofuels.
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    Effect of additives on fuel properties and emission characteristics of micromulsion biofuels from palm oil
    (2017-07-12)
    Attaphong, Chodchanok
    ;
    Lumyong, Pichit
    ;
    Wichadee, Sasiwimon
    ;
    Khaodhiar, Sutha
    ;
    Sarikprueck, Piampoom
    Microemulsiflcation is one of the novel techniques to reduce viscosity of vegetable oils to avoid durability problems in diesel engines. Microemulsion biofuels are transparent, thermodynamically stable, and single-phase mixtures of vegetable oils and ethanol in the presence of surfactants and co-surfactants. Additives have also been included in microemulsion biofuel formulations to improve their stability and fuel properties; however, there is limited research on the effect of additives on emission characteristics of microemulsion biofuels. In this study, microemulsion biofuels were formulated from palm oil/diesel blend (1:1 v/v), ethanol, surfactant, and co-surfactants. Five additives, ethylene glycol butyl ether (EGBE), diethylene glycol ethyl ether (DEGEE), propylene glycol ethyl ether (PGEE), dipropylene glycol methyl ether (DPGME), and ethyl acetate (EA), were used to study the effect of additives on phase behaviors, fuel properties, and emission characteristics. The results showed that studied additives could improve some fuel properties of microemulsion biofuels with negligible effect on phase stability. Additionally, it was found that carbon monoxide (CO) emissions from microemulsion biofuels with DEGEE and EA, and nitrogen oxide (NOx) emissions from microemulsion biofuels with all additives were lower than those from diesel and biodiesel. Therefore, DEGEE and EA can be considered as promising additives for microemulsion biofuel formulations, which can improve fuel properties as well as can significantly reduce CO and NO<inf>x</inf> emissions below the levels of diesel and biodiesel. These encouraging results offer options of additives for biofuel applications.