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Author: search.filters.author.Authayanun, SuthidaSubject: search.filters.subject.Hydrogen production

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    Performance comparison of solid oxide steam electrolysis cells with/without the addition of methane
    (2016-07-15)
    Patcharavorachot, Yaneeporn
    ;
    Thongdee, Sirapa
    ;
    Saebea, Dang
    ;
    Authayanun, Suthida
    ;
    Arpornwichanop, Amornchai
    Hydrogen is considered a clean energy carrier for the future. At present, the production of hydrogen via a solid oxide electrolysis cell is of interest because water is the only reactant used; however, hydrogen production through electrolysis technology is still costly due to high electrical energy consumption. To reduce this energy demand, an addition of methane to the anode side of the solid oxide electrolysis cell, where it behaves like the anode side of the solid oxide fuel cell and generates heat and electricity to accomplish the electrolysis process, is one interesting method. In this study, modeling of the solid oxide fuel-assisted electrolysis cell is performed based on an electrochemical model to analyze the performance of the electrolyzer with/without the addition of methane in terms of the power input and the energy efficiency. In addition, the effect on the electrolyzer cell by key operating parameters, such as current density, steam fraction, steam-to-carbon ratio, temperature, pressure, steam utilization and fuel utilization, is presented. The simulation analysis shows that the performance of the solid oxide fuel-assisted electrolysis cell is higher than that of conventional solid oxide electrolysis cell, as it requires a lower power input. Furthermore, it is possible to run the solid oxide fuel-assisted electrolysis cell without an external electrical energy input.
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    Thermodynamic analysis of hydrogen production from the adsorption-enhanced steam reforming of biogas
    (2014-01-01)
    Saebea, Dang
    ;
    Authayanun, Suthida
    ;
    Patcharavorachot, Yaneeporn
    ;
    Arpornwichanop, Amornchai
    Biogas is considered a potential, renewable fuel to be used as a hydrogen source. At present, a steam reforming is widely used process in hydrogen production, but it needs to be operated at high temperature to achieve high hydrogen yield. Because biogas consists of mostly CO<inf>2</inf>, the hydrogen purification of a reformate gas obtained is another important issue, especially for fuel cell applications. In this study, an enhanced-adsorption steam reforming process in which steam reforming reaction and CO<inf>2</inf> adsorption are occurred in a single unit is investigated. A thermodynamic analysis is performed to study effects of important operating parameters on hydrogen yield and product distribution. It is found that a biogas processor should be operated at high temperatures and inlet steam-T o-methane ratio. The content of CO in the reformate gas increases with increased operating temperature. The steam reforming of biogas coupled with a CO<inf>2</inf> adsorption gives a higher hydrogen product with considerable low CO content, compared to the conventional steam reforming of biogas.
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    Use of different renewable fuels in a steam reformer integrated into a solid oxide fuel cell: Theoretical analysis and performance comparison
    (2013-01-01)
    Saebea, Dang
    ;
    Authayanun, Suthida
    ;
    Patcharavorachot, Yaneeporn
    ;
    Paengjuntuek, Woranee
    ;
    Arpornwichanop, Amornchai
    Hydrogen production from renewable energy resources has received significant attention with advances in fuel cell technology. The fuel type and operational reforming conditions directly affect fuel cell electricity generation. This study analyzes the theoretical performance of a solid oxide fuel cell (SOFC) integrated with a steam reforming process using three different renewable fuels: ethanol, glycerol and biogas. The effects of key steam reformer operating parameters on the hydrogen production for SOFCs are investigated. The performances of SOFC systems run on different fuels are compared in terms of electrical and thermal efficiencies. It is found that the biogas-fueled SOFC system requires the most energy, whereas the ethanol-fueled SOFC system achieves the highest electrical and thermal efficiencies. © 2012 Elsevier Ltd.