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Author: search.filters.author.Boonkanon, ChanitaSubject: search.filters.subject.Calcined oyster shell wastes

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    Magnetic calcium silicate hydrate–oyster shell waste nanocomposite for phosphate removal and recovery: RSM-based optimization, mechanism, and real water application
    (2025-09-01)
    Boonkanon, Chanita
    ;
    Wongniramaikul, Worawit
    ;
    Phawachalotorn, Chanadda
    ;
    Limwongsakorn, Somsak
    ;
    Choodum, Aree
    Magnetic nanocomposites offer an effective strategy for phosphate removal from wastewater, preventing eutrophication and enabling phosphate recovery for reuse as fertilizer—supporting a zero-waste approach. In this study, a novel hybrid nanocomposite composed of magnetized calcined oyster shell waste and calcium silicate hydrate (M-COS-CSH) was synthesized through a simple process completed within 5.2 h. Response Surface Methodology was employed for optimization: a Central Composite Design determined the optimal FeCl₃ and COS ratios, while a Box–Behnken Design optimized adsorption conditions including adsorbent dose (20–100 mg), initial phosphate concentration (10–90 mg L<sup>−1</sup>), contact time (15–75 min), and pH (3−11). Under optimal conditions (60 mg adsorbent, 10 mg L<sup>−1</sup> phosphate, 45 min, pH 6.28), M-COS-CSH achieved a predicted maximum removal efficiency of 97.30 %. An experimental removal efficiency of 98.06 % ± 0.19 % was obtained under the same conditions without pH adjustment (pH 6.84), offering a cost advantage. The adsorption process closely followed the Langmuir isotherm model (R<sup>2</sup> = 0.9963), with a maximum adsorption capacity of 161.29 mg g<sup>−1</sup>, and was best described by the pseudo-second-order kinetic model (R<sup>2</sup> = 1.0000). Characterization suggested a mechanism involving surface microprecipitation and inner-sphere complexation. Thermodynamic analysis confirmed the process to be endothermic and spontaneous (ΔG°: −9.97 to −10.84 kJ mol<sup>−1</sup>; ΔH°: 3.00 kJ mol<sup>−1</sup>; ΔS°: 43.52 J mol<sup>−1</sup> K<sup>−1</sup>). M-COS-CSH achieved phosphate removal ranging from 70.81 % ± 2.47 % to 94.24 % ± 0.39 % in real water samples. Even in the presence of competing anions at fivefold phosphate concentration, removal efficiency remained high (93.58 % ± 0.32 %), confirming the material's strong selectivity and suitability in complex matrices.