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Author: search.filters.author.Chandra-ambhorn, WalairatSubject: search.filters.subject.Oxidation

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    The roles of CO2 and water vapour on the high temperature corrosion of a type 430 stainless steel as an interconnect of bio-gas fuel intermediate temperature SOFCs
    (2025-12-01)
    Thublaor, Thammaporn
    ;
    Srihathai, Padungaut
    ;
    Tengprasert, Watcharapon
    ;
    Suparapinyopapkul, Grid
    ;
    Yan, Jiayi
    A Type 430 stainless steel was exposed to Ar-20 %CO<inf>2</inf> without and with water vapour at 800 °C up to 96 h. Increasing water vapour content from 5 % to 40 % helped reduce mass gain, enhance volatilisation, and improve scale adhesion with fewer pores at scale/steel interface. Mechanisms for Cr and Mn volatilisations including the direct reactions between Cr-containing oxide and CO<inf>2</inf> were suggested with the aid of the XPS results. Mathematical relations that express the role of water vapour on concentrations of defects responsible for scale growth were proposed to help explain the reduced oxidation rate.
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    Effects of temperature and water vapour on Cr-species volatilisation, oxidation and scale adhesion of a Type 409L stainless steel for application as interconnect of low temperature solid oxide fuel cells
    (2024-06-01)
    Homjabok, Wanna
    ;
    Tengprasert, Watcharapon
    ;
    Thublaor, Thammaporn
    ;
    Wiman, Panya
    ;
    Nilsonthi, Thanasak
    Though the classical transport theory does not mathematically express the Arrhenius-like relation between Cr-loss flux due to volatilisation and absolute temperature, such relation was experimentally observed for 409L stainless steel exposed at 600–750 °C. Volatilisation calculation in the present cases can be estimated giving such relation because of the nearly linear relation between mass transfer coefficient and temperature. Cr-loss fluxes in O<inf>2</inf> with 20 and 40 % H<inf>2</inf>O are close to or coincided with the fluxes calculated from MnCr<inf>2</inf>O<inf>4</inf> evaporation. Increasing water vapour could enhance volatilisation contributed from the raised CrO<inf>2</inf>(OH)<inf>2</inf> pressure, reduce oxidation rate, and worsen scale adhesion.
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    Oxidation and Scale Adhesion of a Type 430 Stainless Steel in Ar–CO2 Gas Mixtures at 800 °C
    (2023-04-01)
    Wiman, Panya
    ;
    Muengjai, Angkana
    ;
    Srihathai, Padungaut
    ;
    Thublaor, Thammaporn
    ;
    Siripongsakul, Thamrongsin
    Biogas is an alternative source of fuel potentially used to run solid oxide fuel cells (SOFCs). It mainly consists of CH<inf>4</inf> and CO<inf>2</inf> which can degrade the SOFC interconnect, which is typically made of stainless steel. To investigate the effect of each gas constituent, we focussed here on the effect of CO<inf>2</inf> on high-temperature oxidation behavior of and scale adhesion on the stainless steel interconnect, Type 430 stainless steel. The samples studied were oxidised in CO<inf>2</inf> at contents of 5–100% at 800 °C. The oxidation kinetics were found to be parabolic with the rate constant increasing when the CO<inf>2</inf> content increased. The scale adhesion was assessed using a tensile-test method. The scale formed in the atmosphere containing higher CO<inf>2</inf> content exhibited poorer scale adhesion, as indicated by a lower strain initiating the first spallation and a larger spallation percentage after the first spallation took place. The worsened scale adhesion relates to pores formed at the scale/steel interface. The adhesion energies were further quantified giving the values of about 40–100 J m<sup>–2</sup>. Oxidation mechanisms were suggested based on the dependence of the parabolic rate constant on the oxygen partial pressure and the inward diffusion of carbon-bearing species.
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    Oxidation and volatilisation behaviour of a type 430 stainless steel coated by Mn-Co oxide by slurry method with pre-oxidation for SOFC interconnect application
    (2021-07-15)
    Chandra-ambhorn, Somrerk
    ;
    Homjabok, Wanna
    ;
    Chandra-ambhorn, Walairat
    ;
    Thublaor, Thammaporn
    ;
    Siripongsakul, Thamrongsin
    An AISI 430 stainless steel was coated by Mn-Co spinel using a slurry method. Pre-oxidation before the coating helped reduce the oxidation rate of the coated steel at 800 °C in O<inf>2</inf>-5%H<inf>2</inf>O, relating to the formation of the continuous chromia layer which inhibited the outward diffusion of iron to the coating layer. It also helped reduce the mass flux of Cr loss due to the volatilisation. The combined molecular and Knudsen diffusion of the volatile species through the coating layer was suggested to explain the reduced volatilisation rate of the coated sample with pre-oxidation.