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Author: search.filters.author.Chandra-ambhorn, WalairatSubject: search.filters.subject.Volatilisation

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    The roles of CO2 and water vapour on the high temperature corrosion of a type 430 stainless steel as an interconnect of bio-gas fuel intermediate temperature SOFCs
    (2025-12-01)
    Thublaor, Thammaporn
    ;
    Srihathai, Padungaut
    ;
    Tengprasert, Watcharapon
    ;
    Suparapinyopapkul, Grid
    ;
    Yan, Jiayi
    A Type 430 stainless steel was exposed to Ar-20 %CO<inf>2</inf> without and with water vapour at 800 °C up to 96 h. Increasing water vapour content from 5 % to 40 % helped reduce mass gain, enhance volatilisation, and improve scale adhesion with fewer pores at scale/steel interface. Mechanisms for Cr and Mn volatilisations including the direct reactions between Cr-containing oxide and CO<inf>2</inf> were suggested with the aid of the XPS results. Mathematical relations that express the role of water vapour on concentrations of defects responsible for scale growth were proposed to help explain the reduced oxidation rate.
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    Effects of temperature and water vapour on Cr-species volatilisation, oxidation and scale adhesion of a Type 409L stainless steel for application as interconnect of low temperature solid oxide fuel cells
    (2024-06-01)
    Homjabok, Wanna
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    Tengprasert, Watcharapon
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    Thublaor, Thammaporn
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    Wiman, Panya
    ;
    Nilsonthi, Thanasak
    Though the classical transport theory does not mathematically express the Arrhenius-like relation between Cr-loss flux due to volatilisation and absolute temperature, such relation was experimentally observed for 409L stainless steel exposed at 600–750 °C. Volatilisation calculation in the present cases can be estimated giving such relation because of the nearly linear relation between mass transfer coefficient and temperature. Cr-loss fluxes in O<inf>2</inf> with 20 and 40 % H<inf>2</inf>O are close to or coincided with the fluxes calculated from MnCr<inf>2</inf>O<inf>4</inf> evaporation. Increasing water vapour could enhance volatilisation contributed from the raised CrO<inf>2</inf>(OH)<inf>2</inf> pressure, reduce oxidation rate, and worsen scale adhesion.
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    Corrosion behaviour of AISI 430 stainless steel in O2-40%H2O at 800 °C
    (2022-07-15)
    Wiman, Panya
    ;
    Thublaor, Thammaporn
    ;
    Rojhirunsakool, Tanaporn
    ;
    Bidabadi, Mohammad Hassan Shirani
    ;
    Yang, Zhi Gang
    Less mass gain and poorer scale adhesion assessed by the tensile test of the AISI 430 stainless steel exposed to O<inf>2</inf>-40%H<inf>2</inf>O at 800 °C were observed in comparison with the exposure to O<inf>2</inf>. The reduced mass gain was partly due to Cr-species volatilisation while the worse scale adhesion related to pores formed at scale/steel interface. The Brouwer diagrams were proposed to help discuss the water vapour effect on altering defect concentrations that could affect the oxidation rate and scale adhesion of the studied steel.
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    Oxidation and volatilisation behaviour of a type 430 stainless steel coated by Mn-Co oxide by slurry method with pre-oxidation for SOFC interconnect application
    (2021-07-15)
    Chandra-ambhorn, Somrerk
    ;
    Homjabok, Wanna
    ;
    Chandra-ambhorn, Walairat
    ;
    Thublaor, Thammaporn
    ;
    Siripongsakul, Thamrongsin
    An AISI 430 stainless steel was coated by Mn-Co spinel using a slurry method. Pre-oxidation before the coating helped reduce the oxidation rate of the coated steel at 800 °C in O<inf>2</inf>-5%H<inf>2</inf>O, relating to the formation of the continuous chromia layer which inhibited the outward diffusion of iron to the coating layer. It also helped reduce the mass flux of Cr loss due to the volatilisation. The combined molecular and Knudsen diffusion of the volatile species through the coating layer was suggested to explain the reduced volatilisation rate of the coated sample with pre-oxidation.