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    Item type:Publication,
    Paste-Injection of Low-Density Barium Hexaferrite Magnets with Soft Magnetic Iron Phase
    (2022-10-01)
    Thongsamrit, Wannisa
    ;
    Jantaratana, Pongsakorn
    ;
    Charoensuk, Thanida
    ;
    Sirisathitkul, Chitnarong
    Permanent magnets of varying shapes and sizes are increasingly produced. For hexaferrite magnets, it is challenging to incorporate polymers and a soft magnetic phase in the form of paste before injection molding or extrusion free-forming. In this study, hard magnetic barium hexaferrite/soft magnetic iron composites with a density of 2.28–2.34 g/cm<sup>3</sup> are obtained after paste-injection molding and subsequent sintering at 1150 °C for 5 h. Variations of the binder (143.5–287.0 mg poly(vinyl alcohol), PVA) and the plasticizer (75–150 mg poly(ethylene glycol), PEG-400) in the ceramic–polymer paste give rise to comparable remanent magnetization (33.10–33.63 emu/g) and coercivity (3854–3857 Oe). Unlike all-ferrite systems, the presence of a soft magnetic metal phase is not detrimental to the coercivity. However, the remanent and saturation magnetizations are not substantially increased. The addition of 1% and 5% of iron oxide in the ceramic–polymer paste gives rise to hard/soft composites with lower densities of 2.11 and 2.14 g/cm<sup>3</sup>. The coercivity is increased to 3942–3945 Oe; however, the maximum energy product is reduced.
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    Item type:Publication,
    Enhanced Coercivity of Low-Density Barium Hexaferrite Magnets from Paste-Injection Molding
    (2022-04-01)
    Thongsamrit, Wannisa
    ;
    Jantaratana, Pongsakorn
    ;
    Charoensuk, Thanida
    ;
    Sirisathitkul, Chitnarong
    Ceramic–polymer paste-injection molding is demonstrated as a facile fabrication route for barium hexaferrite magnets. Interestingly, these low-density (1.90–2.35 g/cm<sup>3</sup> ) magnets exhibit substantial coercivity of 3868–4002 Oe. When ceramic paste without polymeric additives is used, reduced coercivity and slightly increased magnetizations are obtained from a magnet with the density of 2.55 g/cm<sup>3</sup> . Their magnetizations are also higher than those obtained from compactions of sol–gel-derived powders. For compact magnets (3.46–3.77 g/cm<sup>3</sup> ), the DI water addition results in a slightly higher magnetization but lower coercivity than dry-pressed magnets. Compactions into disk and bar magnets give rise to comparable magnetic properties. The morphological characterizations reveal smaller barium hexaferrite particles leading to larger coercivity, and the density and shape of magnets have a less pronounced effect.