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Item type:Publication, Nitrogen-doped graphene nanosheet-double-walled carbon nanotube hybrid nanostructures for high-performance supercapacitors(2021-09-01) ;Muangrat, Worawut ;Obata, Michiko ;Htay, Myo Than ;Fujishige, MasatsuguDulyaseree, PaweenaA hybrid nitrogen-doped graphene nanosheet-grafted double-walled carbon nanotube (NG-DWCNT) was synthesized by chemical vapor deposition (CVD). Double-walled carbon nanotube (DWCNT) was synthesized by floating catalytic CVD using ferrocene and thiophene dissolved in ethanol. NG was directly grafted onto the DWCNT bundles by thermal CVD using mixed ethanol-urea solution. The NG possess sharp-edged petal-like structure on one-dimensional DWCNT bundle. The NG-DWCNT showed the nitrogen content of approximately 1.93 at%. The NG-DWCNT hybrid nanostructures exhibited a higher specific capacitance of 563 F g<sup>−1</sup> than that of the DWCNT and un-doped G-DWCNT. The improvement of capacitance value is attributed to the synergic effect of the nitrogen doping together with the sharp-edged petal-like structure of the NG. The facile technique by CVD method provides a promising approach for simple and low-cost technique to synthesize the NG-DWCNT hybrid nanostructures. A hybrid carbon nanostructure of NG-DWCNT has a potential application in electrochemical conversion and energy storage devices. - Some of the metrics are blocked by yourconsent settings
Item type:Publication, Field emission properties of a DWCNT bundle and a single MWCNT(2018-02-01) ;Fujishige, Masatsugu ;Wongwiriyapan, Winadda ;Muramatsu, Hiroyuki ;Takeuchi, KenjiArai, SusumuThe field emission properties of a bundle of double-walled carbon nanotubes (DWCNTs) and a single multiwalled carbon nanotube (MWCNT) were investigated. A DWCNT bundle or a single MWCNT was attached to the head of sharpened tip of tungsten by electrophoresis; the tungsten tip was dipped into a drop of a carbon nanotube/1,2-dichloroethane suspension on a stainless plate, and a high-frequency AC voltage (20 V peak to peak with a frequency of 15 MHz) was applied between the tungsten tip and the stainless steel plate. The turn-on fields of the DWCNT and MWCNT tips for 1 nA/cm<sup>2</sup> were 0.05 and 0.48 V/μm, respectively. From the Fowler-Nordheim plots, the field enhancement factor (β) of the tips was estimated to be 109,600 (DWCNT) and 6780 (MWCNT). The present DWCNT emitter is characterized by a very small turn-on field and large β. The field emission performance is discussed in terms of the sizes of the bundle of DWCNTs and a single MWCNT.
