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    Item type:Publication,
    Characterization of biodiesels and tire derived particulate matters in morphology and nanostructure
    (2022-01-01)
    Oh, Ban seok
    ;
    Karin, Preechar
    ;
    Srilomsak, Mek
    ;
    Chonvasin, Kritin
    ;
    Po-ngen, Watcharin
    Particulate Matters (PM) are known to be dangerous to human health and the environment. Regulations have been set to limit PM levels from vehicles, including compression ignition engine vehicles. The effect of increasing biodiesel content in the fuels has been investigated with respect to the PM using scanning electron microscopy (SEM) and transmission electron microscopy (TEM). PM from tire emissions were compared against diesel PM using SEM, energy dispersive x-ray spectroscopy (EDS), TEM, particle size analysis, x-ray diffraction (XRD), and Raman spectroscopy (RS). The SEM and TEM show that increasing the biodiesel content decreased the size of the PM agglomerate particles, primary particles, and fringes. The EDS, RS, and XRD show that Tire PM are mostly carbon with silicon, calcium, zinc, and other various trace elements. They also allow comparisons with diesel PM for the carbon nanostructure. The particle size analysis shows that Tire PM are generally larger than engine derived PM. The TEM showed that the nanostructure of the carbonaceous Tire PM was the same fringe structure as the engine derived PM. The Tire PM was successfully characterized using similar methods as engine derived soot. There is strong relationship between the increasing of biodiesel content and reduction of agglomerate size, primary particle size and average fringe length.
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    Item type:Publication,
    Impact of engine oil's additives on particulate matter's micro-and nanostructure using electron microscopy image analysis
    (2019-01-01)
    Koko, Phyozin
    ;
    Karin, Preechar
    ;
    Rungsritanapaisan, Sippakorn
    ;
    Tongsri, Ruangdaj
    ;
    Hanamura, Katsunori
    According to increasingly stringent emission regulations on particle emissions from automotive vehicles, a diesel engine must be equipped with diesel particulate filter (DPF) to trap the particulate matters (PMs) which can be harmful to human health. Morphology and chemical composition of particulate matters were successfully studied using electron microscopy and electron dispersive x-ray spectroscopy (EDS) analysis. Microstructure of particulate matters derived from diesel blending lubricating oil were not significant different compared to diesel PM. Nanostructure of soot is a spherical shape composed of curve line crystallites and the particle sizes were in the range of 10 -60 nm while the metal oxide ash is composed of lattice fringes. Chemical composition analysis of EDS result showed that metallic additives from lubricating oil cannot be burned during combustion and might be transformed into metal oxide ash.
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    Item type:Publication,
    Characterization of Biodiesel Particle Emission in Trapping and Regeneration Processes on Cordierite Diesel Particulate Filter
    (2015-11-17)
    Siricholathum, Komkla
    ;
    Karin, Preechar
    ;
    Charoenphonphanich, Chinda
    ;
    Hanamura, Katsunori
    ;
    Chollacoop, Nuwong
    As well-known, the diesel engine has the highest thermal efficiency at the same load as compared with internal combustion engine but its disadvantage is particulate matter (PM) emitted to the atmosphere. The studies of this paper were divided into two parts. The first part studied the quantity of PM from the both diesel and biodiesel fuels at 80% load (2400 rpm) by the trapping process on diesel particulate filter (DPF) used in a partial flow dilution tunnel. The second part studied the regeneration process of PM under the flow rate of oxygen and nitrogen gas of 13.5 L/min with 10%, 15%, and 21% of oxygen gas. The result showed that amount of PM from biodiesel fuel was lower around two times than PM from diesel fuel. The duration in regeneration process of biodiesel's PM was shorter than diesel while increasing of oxygen percentage can reduce regeneration time.