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Monitoring of organochlorine pesticide residues in school milk and associated health risk assessment in Thailand
(2026-06-01)
Cha-aim, Chatartorn
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Manamoongmongkol, Kanjana
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Nisapai, Wiparat
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Phumjan, Lamphung
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Oomnog, Niroth
School milk products are recognized as an important and affordable food source for Thai people, particularly students. However, milk was classified as an agricultural product in which organochlorine pesticide (OCP) residues can be detected due to its fat content. This study investigated the levels of organochlorine pesticides in school milk products, including raw milk, pasteurized milk, and UHT milk, using the QuEChERS method. The fat content of these three types of milk was 3.50%, 3.03%, and 3.33%, respectively. A correlation coefficient (R2) of 0.9953–0.9998 confirmed the validity of the QuEChERS method. The limit of detection (LOD) for each pesticide ranged from 0.003 to 0.0615 mg/kg, and the limit of quantification (LOQ) ranged from 0.010 to 0.2050 mg/kg, with recovery rates of 80.95–110.00%. The analysis for 13 organochlorine pesticide residues, including Aldrin, Cis-Chlordane, Trans-Chlordane, Dieldrin, p,p'-DDD, p,p'-DDE, p,p'-DDT, Endrin, Heptachlor, Heptachlor epoxide, alpha-HCH, beta-HCH, and gamma-HCH using a GC–MS, revealed that no residues were detected above the LOQ (0.01 mg/kg) in any samples, indicating compliance with food safety standards. A scenario-based risk assessment using estimated daily intake (EDI) and hazard quotient (HQ) suggested that, although current exposure is negligible, potential risks may arise under worst-case conditions, particularly for aldrin, dieldrin, and heptachlor in high-consumption groups. Overall, school milk products in Thailand are considered safe; however, continuous monitoring and risk assessment remain essential to ensure long-term food safety.
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Organochlorine pesticide residues persist throughout the sugar production process
(2024-01-01)
Janjamroon, Wilailak
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Sriprom, Pongsert
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Kaewlaoyoong, Acharee
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Cheruiyot, Nicholas Kiprotich
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Permana, Lasuardi
Thailand, one of the world's largest sugarcane producers, has historically used organochlorine pesticides (OCPs) extensively in its plantations. Therefore, OCP residues are anticipated in plantation soil. However, the persistence of these compounds during sugar production is ambiguous. Thus, this study investigated the OCP residues in sugarcane at the different processing stages. Five product samples, i.e., sugarcane juice, bagasse, raw sugar, granulated white sugar, and molasses were obtained from different regions in Thailand. High concentrations of p,p′-dichlorodiphenyltrichloroethane (p,p′-DDT), γ-hexachlorocyclohexane (γ-HCH or lindane), and cyclodiene derivatives such as aldrin, dieldrin, heptachlor and its epoxide were found in the samples. This is surprising because the OCP use in sugarcane plantations has been long banned in Thailand. Bagasse and raw sugar had the highest total OCP concentrations of 1.0393 ± 0.7555 mg/kg and 0.9658 ± 0.8209 mg/kg, followed by white sugar (0.1616 ± 0.1311 mg/kg), molasses (0.0813 ± 0.1195 mg/kg), and sugarcane juice (0.0173 ± 0.0112 mg/kg). This study offers comprehensive information on the fate of OCPs during the entire sugarcane processing stage, from the cane to the final granulated sugar. The findings also suggest persistent OCP presence in plantation soil, possibly due to illegal use.
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Innovative mycoremediation technique for treating unsterilized PCDD/F-contaminated field soil and the exploration of chlorinated metabolites
(2021-11-15)
Kaewlaoyoong, Acharee
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Chen, Jenq Renn
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Cheng, Chih Yu
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Lin, Chitsan
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Cheruiyot, Nicholas Kiprotich
Mycoremediation of unsterilized PCDD/F-contaminated field soil was successfully demonstrated by solid-state fermentation coupled with Pleurotus pulmonarius utilizing a patented incubation approach. The experiments were carried out in four setups with two as controls. The contaminated soil was homogenously mixed with solid inocula, 1:0.5 dry w/w, resulting in an initial concentration of 4432 ± 623 ng WHO-TEQ kg−1. After a 30-day incubation under controlled conditions, the overall removal (approx. 60%) was non-specific. The removal was attributed to degradation by extracellular ligninolytic enzymes and uptake into the fruiting tissue (~110 ng WHO-TEQ kg−1 of mushroom). Furthermore, less recalcitrant chlorinated metabolites were found, implying ether bond cleavage and dechlorination happened during the mycoremediation. These metabolites resulted from the complex interaction between P. pulmonarius and the indigenous microbes from the unsterilized soil. This study provides a new step toward scaling up this mycoremediation technique to treat unsterilized PCDD/F-contaminated field soil.
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White rot fungus Pleurotus pulmonarius enhanced bioremediation of highly PCDD/F-contaminated field soil via solid state fermentation
(2020-10-10)
Kaewlaoyoong, Acharee
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Cheng, Chih Yu
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Lin, Chitsan
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Chen, Jenq Renn
;
Huang, Wen Yen
This study was performed to evaluate the use of white rot fungus, Pleurotus pulmonarius, to treat polychlorinated dibenzo-p-dioxins and furans (PCDD/Fs) in contaminated soil using solid state fermentation (SSF). The soil was collected from a long-closed pentachlorophenol plant in southern Taiwan. The non-sterilized soil with a total PCDD/F concentration of 14,000 ± 2400 ng I-TEQ kg−1 was mixed directly with the solid fungal inocula at dry w/w ratio of 1:1.4 (ratio-adjusted test) and incubated at 26 ± 2 °C in a controlled environment. The highest PCDD/F decomposition was observed during the mycelium colonization. Pearson correlation coefficient (r) studied during this period (35 days) indicated that laccase had no significant correlation (r = −0.53), while manganese peroxidase had a strong positive correlation (r = 0.88) with PCDD/F decomposition efficiency. After 72 days, the more toxic congeners, tetra- and penta-CDD/Fs were removed to non-detectable levels. Meanwhile, the removal efficiencies of hexa-, hepta-, and octa-CDD/Fs were >80%, >97%, and >90%, respectively. The simultaneous degradation of low and high chlorinated DD/Fs suggested that overall removal was nonspecific. The overall PCDD/F removal was 96%, and the residual concentration (276 ng I-TEQ kg−1) was below the regulatory control limit (1000 ng I-TEQ kg−1). In conclusion, this study shows that P. pulmonarius via SSF can successfully remediate the PCDD/F-contaminated field soil. Furthermore, this SSF technique overcame the well-known intractability of PCDD/F biodegradation in non-sterilized soil, making it promising for actual field application.

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