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Item type:Publication, Improvement of biohydrogen production from biomass using supercritical water gasification and CaO adsorption(2024-04-01) ;Panichkittikul, Nitsara ;Mariyappan, Vinitha ;Wu, WeiPatcharavorachot, YaneepornProducing biohydrogen is a promising alternative to fossil fuels, sourced from renewable energy like wind, solar, and biomass, known for its eco-friendliness and minimal greenhouse gas emissions. This study focuses on the process design and simulation of producing biohydrogen from biomass (bagasse) gasification. New integration of the water gas shift reactor and CaO adsorption process is connected to biomass gasification with the steam/supercritical water agents for improving the hydrogen production process. Simulations show that steam gasification integrated with CaO adsorption (SG-CaO) is optimized at specific conditions, resulting in high-purity hydrogen at 99.95 %. Similarly, the supercritical water gasification integrated with CaO adsorption (SCWG-CaO) requires specific conditions, achieving exceptionally pure hydrogen at 99.99 %. In terms of energy analysis, SCWG-CaO outperforms SG-CaO, with higher hydrogen yield (14.16 % vs. 14.12 %) and greater energy efficiency (42.32 % vs. 40.26 %). It shows that the SCWG-CaO is a suitable and efficient approach for biohydrogen production, considering factors such as hydrogen purity, yield, and energy efficiency. - Some of the metrics are blocked by yourconsent settings
Item type:Publication, Comparative exergoeconomic analysis of indirect and direct bio-dimethyl ether syntheses based on air-steam biomass gasification with CO2 utilization(2020-10-15) ;Nakyai, Teeranun ;Patcharavorachot, Yaneeporn ;Arpornwichanop, AmornchaiSaebea, DangDimethyl ether (DME) is a potential energy source because it is a clean fuel and a crucial intermediate in various chemical productions. The main purposes of this work were to assess and compare the indirect and direct bio-DME syntheses from air-steam biomass gasification with CO<inf>2</inf> utilization using energetic, exergetic, and exergoeconomic analyses. The effects of hydrogen to carbon monoxide (H<inf>2</inf>/CO) and carbon dioxide to carbon monoxide (CO<inf>2</inf>/CO) ratios on DME yield of the indirect and direct processes were firstly investigated. When considering the combined processes, the results were found that the DME yield of the system with direct DME synthesis is higher than that of the indirect system. Moreover, the energy consumption and exergy destruction of biomass gasification and DME synthesis processes in the indirect system are considerably higher when compared to the direct system. For exergoeconomic analysis, the DME unit cost of the direct system (1.66 $/kg DME) also has lower than that of the system with indirect DME synthesis (2.26 $/kg DME). In addition, the CO<inf>2</inf> emission of both systems was also considered. The CO<inf>2</inf> emission intensity of the system with direct DME synthesis shows 32.35% lower than the system with indirect DME synthesis. - Some of the metrics are blocked by yourconsent settings
Item type:Publication, Syngas production from sugarcane leftover gasification integrated with absorption process for green liquid production(2019-10-20) ;Chatrattanawet, Narissara ;Authayanun, Suthida ;Saebea, DangPatcharavorachot, YaneepornThe aim of research is to present favorable operating conditions for the clean syngas production from sugarcane leftover through the gasification process by using AspenPlus™ software. In order to obtain the suitable syngas for liquid fuel production, this process should be integrated with gas cleaning. The simulation was performed by comparing three gasifying agents, i.e., steam, air, and steam-air. To find favorable operating conditions that provide the highest syngas molar flow rate, the effect of operating conditions in gasifier was also examined. In addition, the possibility of syngas production operated under a thermal self-sufficient condition was studied. The gasification results showed that the syngas production significantly increases with the increase of temperature. The proper gasifying temperature for three processes is at 750 °C. When the maximum syngas molar flow rate was considered, it was found that the use of steam (at S/B of 0.6) and steam-air (at S/B of 0.8 and A/B of 0.04) in gasification can achieve this criterion. Both processes can provide syngas molar flow rate as ∼149 kmol/h. However, it was found that thermal self-sufficient operation is possible when air and steam-air are used as gasifying agent. The result indicated that syngas molar flow rate obtained from air gasification (at A/B of 1.309) is more than that from steam-air gasification (at S/B of 0.1 and A/B of 1.375). In order to obtain the cleaner production of syngas, the absorption process with capturing CO<inf>2</inf> and H<inf>2</inf>S was studied via using monoethanolamine (MEA) as solvent. The optimal column pressure is 40 bars and the number of trays equals to 10. To obtain the H<inf>2</inf>S content below 0.1 mg/m<sup>3</sup>, the MEA molar flow rates are 325, 450, and 465 kmol/h for steam, air, and steam-air gasification processes, respectively.
