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    Item type:Publication,
    Liquid fuel production from waste tires and water hyacinth: A comparative study of Co-pyrolysis and Co-gasification with Fischer-Tropsch integration
    (2025-06-01)
    Aentung, Tanawat
    ;
    Thongchawee, Anutida
    ;
    Patcharavorachot, Yaneeporn
    This study investigates the sustainable conversion of waste tires (WT) and water hyacinth (WH) into liquid fuel using two thermochemical approaches: co-pyrolysis (direct method) and co-gasification integrated with Fischer-Tropsch (FT) process (indirect method). Aspen Plus software was employed to determine optimal operating conditions for maximizing fuel yield. The direct method achieved 6649.22 gallons of fuel per day at 400 °C with a WT/WH ratio of 75/25. In comparison, the indirect method, operating at 800 °C with a WT/WH ratio of 50/50, produced 115.92 kmol/h of syngas, which was subsequently converted into 8817.15 gallons of liquid fuel per day via the FT process. An economic analysis revealed that the indirect method offered higher fuel yields and better cost-effectiveness, with a capital investment approximately 5 million U.S. dollars lower than the direct method. These findings highlight the potential of integrating waste-derived feedstocks for efficient and sustainable liquid fuel production.
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    Process design and muti-objective optimization of solid waste/biomass co-gasification considering tar formation
    (2024-11-01)
    Aentung, Tanawat
    ;
    Wu, Wei
    ;
    Patcharavorachot, Yaneeporn
    Background: The co-gasification of solid waste and biomass to produce syngas is an environmentally friendly technology. Unfortunately, the tar formation in the solid waste/biomass co-gasification process would degrade the product gas quality and the overall process efficiency. Methods: In this study, the kinetics of the solid waste/biomass co-gasification is shown by the Aspen Plus simulation. Through the model validation and sensitivity analysis, it is validated that tar yield, syngas composition, and syngas yield are sensitive to gasifier temperature, steam-to-feed ratio (S/F), and blending weight ratio (B/W). It shows that the increase of the product gas yield (GY) increases CO<inf>2</inf> concentration in the product gas, but the tar yield is reduced. To address the sustainable solid waste/biomass co-gasifier, the multi-objective optimization (MOO) algorithm is implemented to maximize GY and minimize CO<inf>2</inf> concentration. For solving the MOO problem, the standard genetic algorithm (GA) coupled with response surface methodology (RSM) is performed to find the Pareto frontier plot, and the technique for order of preference by similarity to the ideal solution (TOPSIS) is used to determine optimal operating conditions. Significant Findings: Under the Pareto frontier plot and TOPSIS, a GY of 2.672 Nm³/kg, CO<inf>2</inf> concentration of 8.045 vol.%, and tar yield of 17.0617 g/Nm³ can be achieved under the optimal conditions of T = 1099.95 °C, S/F ratio = 0.79, and B/W ratio = 10.02. In addition, the CO<inf>2</inf> absorption using CaO is added to purify CO<inf>2</inf> up to 99.999 % of purity.
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    Item type:Publication,
    Comparative analysis of biomass and coal based co-gasification processes with and without CO2 capture for HT-PEMFCs
    (2019-01-22)
    Mongkolsiri, Pichamon
    ;
    Jitkeaw, Salinee
    ;
    Patcharavorachot, Yaneeporn
    ;
    Arpornwichanop, Amornchai
    ;
    Assabumrungrat, Suttichai
    With the seasonal availability and low energy density of biomass and the high environmental impact of coal, the co-gasification of biomass and coal is an alternative approach facilitating a trade-off between renewable and non-renewable resources. The aim of this study was to investigate hydrogen production from the co-gasification of biomass and coal integrated by means of the sorption-enhanced water gas shift reactor (G-SEWGS) for a high temperature proton exchange membrane fuel cell (HT-PEMFC). The effects of the gasifier temperature, the steam to fuel ratio (S/F ratio), and the equivalence ratio (ER) on the hydrogen production performance and environmental impact of the G-SEWGS were theoretically analysed and compared with the conventional gasifier integrated with the water gas shift reactor (G-WGS) and the sorption-enhanced gasifier integrated with the water gas shift reactor (SEG-WGS). As compared to the conventional water gas shift reactor, the addition of a CaO sorbent in the modified water gas shift reactor not only reduces the amount of the CO<inf>2</inf> emission but also leads to an increase in the hydrogen concentration and hydrogen content. The G-SEWGS provides better performance in terms of its fuel processor efficiency and CO<inf>2</inf> emission than the G-WGS and the SEG-WGS. Also, the problem of sulphur compound in the hydrogen-rich gas can be reduced by using of the sorption-enhanced water gas shift reactor (SEWGS). The best system exergy efficiency, which was around 22% for the power generation, was determined from the HT-PEMFC integrated with the G-SEWGS. The main exergy destruction of around 70% of the total loss was caused by hydrogen production processes.