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Thermodynamic models for determination of the solubility of 2,5-bis(2-furylmethylidene)cyclopentan-1-one in different solvents at temperatures ranging from 308.15 to 403.15K
(2014-04-15)
Prapasawat, Tatchanok
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Hronec, Milan
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Štolcová, Magdaléna
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Lothongkum, Anchaleeporn Waritswat
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Pancharoen, Ura
The solubility data of 2,5-bis(2-furylmethylidene)cyclopentan-1-one (F<inf>2</inf>C) in solid-liquid equilibrium in alternative solvents are vital for a preliminary study of industrial applications aimed at producing sustainable and renewable materials and fuels. The solubility behavior of F<inf>2</inf>C in different solvents, such as tetrahydrofuran, mixed water-tetrahydrofuran (1:1, v/v), methanol, and water at temperatures ranging from 308.15 to 403.15K was investigated. An isothermal method was employed to measure the solubility data of F<inf>2</inf>C. The experimental data showed that the solubility of F<inf>2</inf>C increased as the temperature increased and was strongly affected by the surface tension and polarity index. The solubility of F<inf>2</inf>C in the studied solvents increased in the following order: H<inf>2</inf>O<methanol<H<inf>2</inf>O-THF mixture<THF. The thermodynamic models, such as the polynomial empirical equation, the Van't Hoff, and the modified Apelblat models were investigated to describe the experimental data. It was found that the modified Apelblat model was the most suitable for predicting the solubility behavior of F<inf>2</inf>C with a temperature increment. The calculated thermodynamic parameters indicated that in each studied solvent the dissolution process of F<inf>2</inf>C is endothermic and spontaneous. © 2014 Elsevier B.V.
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Modelling and experimental validation of enantioseparation of racemic phenylalanine via a hollow fibre-supported liquid membrane
(2014-02-01)
Prapasawat, Tatchanok
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Lothongkum, Anchaleeporn Waritswat
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Pancharoen, Ura
This paper reports on the enantioseparation of racemic phenylalanine or D-phenylalanine and Lphenylalanine via a hollow fibre-supported liquid membrane (HFSLM) and the results are compared with the mathematical model. The enantioseparation results, of 80 % and 73 %, showed the highest extraction and stripping of l-phenylalanine from the feed phase and the enantiomeric excess (% ee) of 60 % from 6 mmol L-1 of initial rac-phenylalanine in the feed solution. The optimum parameters were feed solution at pH 5, 6 mmol L L-1 of O,O′-dibenzoyl-(2S,3S)-tartaric acid ((+)-DBTA) as the extractant in octanol as the liquid membrane, and deionised water as the stripping solution. Equal flow-rates of feed and stripping solutions of 100 mL minL-1 were adjusted in a batch operation mode for 50 min at ambient temperature. From the calculation, the equilibrium constants of extraction (K <inf>ex</inf>) and mass transfer coefficients in the feed phase (k <inf>f</inf>) and in the liquid membrane phase (k <inf>m</inf>) were found to be 1.81 L mmol-2, 3.50 × 10-2 cm s-1, and 1.40 × 10-2 cm s-1, respectively. Finally, the change in concentrations of d,l-phenylalanine over time in the feed and stripping solutions by mathematical model were estimated and compared with the experimental results. The values thus calculated were in agreement with the experimental data with the average deviation of approximately 3 %. © 2013 Institute of Chemistry, Slovak Academy of Sciences.
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Uphill transport and mathematical model of Pb(II) from dilute synthetic lead-containing solutions across hollow fiber supported liquid membrane
(2012-05-15)
Suren, Sira
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Wongsawa, Thidarat
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Pancharoen, Ura
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Prapasawat, Tatchanok
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Lothongkum, Anchaleeporn Waritswat
This work presents an experimental investigation and mathematical model of Pb(II) separation and stripping from relatively low-level lead-containing synthetic solutions through a hollow fiber supported liquid membrane (HFSLM) by using di-2-ethylhexyl phosphoric acid (D2EHPA) in toluene as an extractant or carrier. The separation was studied on several variables: concentration of D2EHPA, types of stripping solutions (distilled water, HNO <inf>3</inf>, H <inf>2</inf>SO <inf>4</inf> and HCl), concentration of the selected stripping solution, flow patterns of feed and stripping solutions, types of lead-containing solutions (Pb(NO <inf>3</inf>) <inf>2</inf> and PbCl <inf>2</inf>), and flow rates of feed and stripping solutions. The results remarkably showed that HFSLM could successfully reduce a very low concentration of Pb(II) in feed solution to less than the regulatory discharge limit of 0.2mg/L issued by the Ministry of Industry and the Ministry of Natural Resource Environment, Thailand. The highest extraction and stripping results were achieved by using 0.03M D2EHPA, 0.9M HCl at equal flow rates of feed and stripping solutions of 100mL/min using a single-pass of feed solution and circulating of stripping solution. High percentages of extraction and stripping were observed from both Pb(NO <inf>3</inf>) <inf>2</inf> and PbCl <inf>2</inf> solutions. The kinetics of Pb(NO <inf>3</inf>) <inf>2</inf> and PbCl <inf>2</inf> separation were corresponded to second-order reaction with the rate constants of 1.49 and 1.51L/mgmin, respectively. The prediction of Pb(II) concentrations in the outlet Pb(NO <inf>3</inf>) <inf>2</inf> and PbCl <inf>2</inf> feed solutions obtaining from mathematical model were in good agreement with the experimental results at the average percent deviations of 4% for Pb(NO <inf>3</inf>) <inf>2</inf> solution and 8% for PbCl <inf>2</inf> solution. © 2012 Elsevier B.V.
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Synergistic separation of yttrium ions in lanthanide series from rare earths mixture via hollow fiber supported liquid membrane
(2009-03-01)
Ramakul, Prakorn
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Supajaroon, Tossaporn
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Prapasawat, Tatchanok
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Pancharoen, Ura
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Lothongkum, Anchaleeporn W.
Separation of yttrium ions from the mixture of rare earths in lanthanide series has been examined by a microporous hydrophobic hollow fiber supported liquid membrane. Cyanex 272 and TBP in kerosene are used separately as an extractant. Nitric acid solution is used as a stripping solution. Increasing the concentration of Cyanex 272 increases the percentages of extraction and stripping of yttrium from rare earths but slightly percentages are obtained by TBP. Interestingly, when TBP is added with Cyanex 272, the percentages of extraction and stripping increases. This is due to the synergistic effect of the extractants. Moreover, yttrium can be selectively extracted and stripped more than other lanthanide ions because the equilibrium constant decreases with an increase in atomic number or decreases with the ionic radius of the lanthanides. In other words, yttrium is separated selectively due to the smallest ionic radius while other lanthanides are separated with a decrease in ionic radius or an increase in atomic number. © 2009 The Korean Society of Industrial and Engineering Chemistry.
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Separation of As(III) and As(V) by hollow fiber supported liquid membrane based on the mass transfer theory
(2008-01-01)
Prapasawat, Tatchanok
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Ramakul, Prakorn
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Satayaprasert, Chairit
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Pancharoen, Ura
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Lothongkum, Anchaleeporn W.
Separation of As(III) and As(V) ions from sulphate media by hollow fiber supported liquid membrane has been examined. Cyanex 923 was diluted in toluene and used as an extractant. Water was used as a stripping solution. The extractability of As(V) was higher than As(III). When the concentration of sulphuric acid in feed solution and Cyanex 923 in liquid membrane increased, more arsenic ions were extracted into liquid membrane and recovered into the stripping solution. The mathematical model was focused on the extraction side of the liquid membrane system. The mass transfer coefficients of the aqueous phase (k <inf>i</inf> ) and organic phase (k <inf>m</inf> ) are 7.15×10 -3 and 3.45×10-2 cm/s for As(III), and 1.07×10-2 and 1.79×10-2 cm/s for As(V). Therefore, the rate-controlling step for As(III) and As(V) in liquid membrane process is the mass transfer in the aqueous film between the feed solution and liquid membrane. The calculated mass transfer coefficients agree with the experimental results. © 2008 Springer.

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