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    Item type:Publication,
    Performance Analysis of Biomass Gasification with Biogas Co-Feeding for Hydrogen Production
    (2025-01-01)
    Saebea, Dang
    ;
    Patcharavorachot, Yaneeporn
    To improve the hydrogen yield in biomass gasification, the addition of biogas for co-feeding with biomass in gasification was proposed in this work. The gasification model developed in Aspen Plus software was validated with experimental data. The performance of biomass gasification with biogas co-feeding using steam as a gasifying agent was investigated. The effect of the steam-to-fuel ratio on the gasification of mixed biomass and biogas was studied. The results show that the simulation results of biomass gasification were consistent with experimental data. Biomass gasification with biogas co-feeding can raise the amount of hydrogen and carbon monoxide in gas products by 22.12% and 18.44%, respectively. Moreover, the increase in the steam-to-fuel ratio enhances hydrogen in syngas. However, the system efficiency decreases with increasing steam-to-fuel ratio.
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    Item type:Publication,
    Performance and environmental study of a biogas-fuelled solid oxide fuel cell with different reforming approaches
    (2018-03-01)
    Chatrattanawet, Narissara
    ;
    Saebea, Dang
    ;
    Authayanun, Suthida
    ;
    Arpornwichanop, Amornchai
    ;
    Patcharavorachot, Yaneeporn
    In this work, solid oxide fuel cells (SOFCs) using biogas as the fuel with two different reforming approaches, i.e., external and internal reforming, were studied to determine the optimal operation conditions for each approach. Thermodynamic analysis was performed using a flowsheet simulator. The equilibrium gas composition was calculated by minimizing the Gibbs free energy. An electrochemical model that includes three voltage losses (i.e., activation, ohmic, and concentration losses) was used to predict the performance of the SOFCs. The simulation results showed that the reformer in the external reforming SOFC should be operated at a temperature of 973 K, a pressure of 1 atm, and a steam-to-carbon molar ratio of 0.5. In performance analysis, the simulation results indicated that both approaches have the same optimal operating conditions, i.e. a temperature of 1173 K, a pressure of 3 atm, and a current density of 5000 A/m<sup>2</sup>. Under the same operating conditions, the internal reforming SOFC exhibited better electrical efficiency than that of the external reforming SOFC. Considering the CO<inf>2</inf> and CO emissions, the exhaust gas obtained from the anode side of the internal reforming SOFC contained 7.4% CO<inf>2</inf> and 37.9% CO, which are higher values than those for the external reforming SOFC (1.9% CO<inf>2</inf> and 32.5% CO).
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    Item type:Publication,
    Thermodynamic analysis of hydrogen production from the adsorption-enhanced steam reforming of biogas
    (2014-01-01)
    Saebea, Dang
    ;
    Authayanun, Suthida
    ;
    Patcharavorachot, Yaneeporn
    ;
    Arpornwichanop, Amornchai
    Biogas is considered a potential, renewable fuel to be used as a hydrogen source. At present, a steam reforming is widely used process in hydrogen production, but it needs to be operated at high temperature to achieve high hydrogen yield. Because biogas consists of mostly CO<inf>2</inf>, the hydrogen purification of a reformate gas obtained is another important issue, especially for fuel cell applications. In this study, an enhanced-adsorption steam reforming process in which steam reforming reaction and CO<inf>2</inf> adsorption are occurred in a single unit is investigated. A thermodynamic analysis is performed to study effects of important operating parameters on hydrogen yield and product distribution. It is found that a biogas processor should be operated at high temperatures and inlet steam-T o-methane ratio. The content of CO in the reformate gas increases with increased operating temperature. The steam reforming of biogas coupled with a CO<inf>2</inf> adsorption gives a higher hydrogen product with considerable low CO content, compared to the conventional steam reforming of biogas.