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Author: search.filters.author.Siripongsakul, ThamrongsinSubject: search.filters.subject.Stainless steel

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    Oxidation and Scale Adhesion of a Type 430 Stainless Steel in Ar–CO2 Gas Mixtures at 800 °C
    (2023-04-01)
    Wiman, Panya
    ;
    Muengjai, Angkana
    ;
    Srihathai, Padungaut
    ;
    Thublaor, Thammaporn
    ;
    Siripongsakul, Thamrongsin
    Biogas is an alternative source of fuel potentially used to run solid oxide fuel cells (SOFCs). It mainly consists of CH<inf>4</inf> and CO<inf>2</inf> which can degrade the SOFC interconnect, which is typically made of stainless steel. To investigate the effect of each gas constituent, we focussed here on the effect of CO<inf>2</inf> on high-temperature oxidation behavior of and scale adhesion on the stainless steel interconnect, Type 430 stainless steel. The samples studied were oxidised in CO<inf>2</inf> at contents of 5–100% at 800 °C. The oxidation kinetics were found to be parabolic with the rate constant increasing when the CO<inf>2</inf> content increased. The scale adhesion was assessed using a tensile-test method. The scale formed in the atmosphere containing higher CO<inf>2</inf> content exhibited poorer scale adhesion, as indicated by a lower strain initiating the first spallation and a larger spallation percentage after the first spallation took place. The worsened scale adhesion relates to pores formed at the scale/steel interface. The adhesion energies were further quantified giving the values of about 40–100 J m<sup>–2</sup>. Oxidation mechanisms were suggested based on the dependence of the parabolic rate constant on the oxygen partial pressure and the inward diffusion of carbon-bearing species.
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    Corrosion behaviour of AISI 430 stainless steel in O2-40%H2O at 800 °C
    (2022-07-15)
    Wiman, Panya
    ;
    Thublaor, Thammaporn
    ;
    Rojhirunsakool, Tanaporn
    ;
    Bidabadi, Mohammad Hassan Shirani
    ;
    Yang, Zhi Gang
    Less mass gain and poorer scale adhesion assessed by the tensile test of the AISI 430 stainless steel exposed to O<inf>2</inf>-40%H<inf>2</inf>O at 800 °C were observed in comparison with the exposure to O<inf>2</inf>. The reduced mass gain was partly due to Cr-species volatilisation while the worse scale adhesion related to pores formed at scale/steel interface. The Brouwer diagrams were proposed to help discuss the water vapour effect on altering defect concentrations that could affect the oxidation rate and scale adhesion of the studied steel.
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    Oxidation and volatilisation behaviour of a type 430 stainless steel coated by Mn-Co oxide by slurry method with pre-oxidation for SOFC interconnect application
    (2021-07-15)
    Chandra-ambhorn, Somrerk
    ;
    Homjabok, Wanna
    ;
    Chandra-ambhorn, Walairat
    ;
    Thublaor, Thammaporn
    ;
    Siripongsakul, Thamrongsin
    An AISI 430 stainless steel was coated by Mn-Co spinel using a slurry method. Pre-oxidation before the coating helped reduce the oxidation rate of the coated steel at 800 °C in O<inf>2</inf>-5%H<inf>2</inf>O, relating to the formation of the continuous chromia layer which inhibited the outward diffusion of iron to the coating layer. It also helped reduce the mass flux of Cr loss due to the volatilisation. The combined molecular and Knudsen diffusion of the volatile species through the coating layer was suggested to explain the reduced volatilisation rate of the coated sample with pre-oxidation.