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    Item type:Publication,
    Calcium Copper Titanate Particles Based Energy Harvesting and Removal of Pharmaceutical Pollutants
    (2025-05-13)
    Kaja, Kushal Ruthvik
    ;
    Behera, Swayam Aryam
    ;
    Das, Bhagyashree
    ;
    Hajra, Sugato
    ;
    Panda, Swati
    In this work, calcium copper titanate oxide (CaCu<inf>3</inf>Ti<inf>4</inf>O<inf>12</inf>, abbreviated as CCTO) was processed employing a solid-state reaction. The properties of CCTO were thoroughly characterized using various characterization tools. The CCTO particles layer and polytetrafluoroethylene (PTFE) acted as triboelectric layers, forming a contact and separation-based triboelectric nanogenerator (TENG). TENG, based on CCTO/PTFE, delivered an output of 74 V and 6 μA. TENG was utilized to harvest energy through various human activities, effectively charging capacitors, and was further attached to a pillow to monitor sleep. The study also evaluated the photocatalytic performance of CCTO for the degradation of doxycycline, achieving 87% efficiency within 45 minutes under visible light. The reaction pathway was thoroughly investigated, and catalyst reusability was examined. CCTO demonstrates potential as a dual-function material, serving both as a photocatalyst for environmental cleanup and as a triboelectric material for energy harvesting.
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    Item type:Publication,
    Antimony Sulfoiodide-Based Energy Harvesting and Self-Powered Temperature Detection
    (2024-03-01)
    Song, Heewon
    ;
    Hajra, Sugato
    ;
    Panda, Swati
    ;
    Hwang, Subhin
    ;
    Kim, Nayoon
    The ferroelectric-semiconductor behavior of antimony sulfoiodide (SbSI) has opened up the material as a base for energy-harvesting devices. Specifically, SbSI has drawn much attention for pyroelectric energy harvesting and thermal sensing with outstanding electrothermal properties. This work investigates the thermistor properties of an SbSI material and presents the development of an SbSI nanorod/Kapton-based triboelectric nanogenerator (TENG) for effective energy harvesting and temperature sensing. The TENG based on SbSI/ Kapton operating in vertical contact separation mode delivers a peak-to-peak voltage of 90 V and a current of 1510 nA, respectively. Introducing SbSI nanorods for TENG opens the possibility of extending the conventional triboelectric series. The electrical and dielectric properties of the SbSI nanorods are investigated. SbSI exhibits a highly linear temperature coefficient of resistance (TCR) of −0.026 °C<sup>−1</sup>, making it an excellent candidate material for a thermistor. In addition, the material exhibits an excellent thermal sensitivity (β<inf>20/80</inf> = 1612.1 K). For demonstration, the SbSI thermistor is connected with TENG, and the outputs at various temperatures are analyzed for self-powered temperature sensing. This capability allows for efficient temperature monitoring without relying on external power sources, advancing remote, and autonomous sensing applications.
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    Item type:Publication,
    High-Performance Hybridized Composited-Based Piezoelectric and Triboelectric Nanogenerators Based on BaTiO3/PDMS Composite Film Modified with Ti0.8O2 Nanosheets and Silver Nanopowders Cofillers
    (2019-05-28)
    Sriphan, Saichon
    ;
    Charoonsuk, Thitirat
    ;
    Maluangnont, Tosapol
    ;
    Vittayakorn, Naratip
    In order to commercialize the rapidly developing technology of energy harvesters, the following devices need to be developed further for enhancing output performance, flexibility, scalability, facile fabrication, and cheaper price. The composite-based triboelectric nanogenerator (CTENG), which contains the above properties, is a promising technology that has attracted special interest for a decade. Focus has been placed on the hybrid concept between the composite-based piezoelectric nanogenerator (CPENG) and CTENG in order to enhance CTENG efficiency. This study presented a high-performance hybridized CPENG and CTENG device, which operated from the composite film of Ti<inf>0.8</inf>O<inf>2</inf> nanosheets (Ti NSs)/silver nanoparticles (Ag NPs) co-doped BaTiO<inf>3</inf> nanopowders (BT NPOs) inside the polydimethylsiloxane (PDMS) host. The 0.3 vol % of Ti NSs and 1.5 vol % of Ag NPs exhibited the optimum harvesting performance in all compositions, with an output voltage and current density reaching approximately 150 V and 0.32 μA/cm<sup>2</sup>, respectively. Their harvesting performance was approximately 60 and 32 times higher than that of the CPENG constructed from pure PDMS. In addition, practical demonstration of the proposed device was investigated. The hybridized CPENG and CTENG device could operate in a long-term cyclic operation, charge the capacitor for storing energy, and also drive LEDs to brighten. This work suggested facile device fabrication and made a guideline to develop high-performance nanogenerators, which is crucial for device development and practical usage in the future.