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Corrigendum to “Process design and muti-objective optimization of solid waste/biomass co-gasification considering tar formation” [Journal of the Taiwan Institute of Chemical Engineers 164 (2024) 105688](S1876107024003468)(10.1016/j.jtice.2024.105688)
(2025-03-01)
Aentung, Tanawat
;
Wu, Wei
;
Patcharavorachot, Yaneeporn
The authors regret to correct the title of the article as ‘Process design and multi-objective optimization of solid waste/biomass co-gasification considering tar formation’. The authors would like to apologise for any inconvenience caused.
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Economic and environmental analyses for achieving net-zero CO2 emissions of a green diesel production process
(2024-12-01)
Pongboriboon, Nattapat
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Mariyappan, Vinitha
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Wu, Wei
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Chandra-Ambhorn, Walairat
Background: In this study, palm oil hydrotreating for producing green diesel has been thoroughly explored, emphasizing high yields, reduced environmental impact, and lower energy consumption, particularly with solar collectors. Methods: This study addresses these gaps by evaluating impacts on multiple fronts, including carbon revenue, GHG emissions, and overall environmental effects. The Life Cycle Assessment (LCA) technique, utilizing the CML method developed by Centrum voor Milieukunde Leiden (the Center for Environmental Science at Leiden University, The Netherlands) in SimaPro®, is employed to assess the environmental impact of green diesel production processes. The CML method evaluates environmental impacts through three phases: characterization, which quantifies environmental loads; midpoint, which assesses intermediate impact stages such as global warming potential; and damage, which evaluates potential harm to human health, ecosystems, and resource availability. The scope of work includes simulating the production process and incorporating a CO<inf>2</inf> capture unit with Aspen Plus®. Additionally, kinetic parameters for the palm oil hydrotreating reaction were validated, and energy consumption was optimized using the Aspen Energy Analyzer. Significant findings: The net-zero emissions of the green diesel (GD) production from crude palm oil (CPO) is achieved by using an integration of an evacuated tube solar collector (ETSC), heat exchanger network, and a post-separation CO<inf>2</inf> capture process. Through the life cycle assessment (LCA), the terrestrial ecotoxicity potential (TEIP) is identified as a significant environmental factor due to chemical pesticides used in the oil palm cultivation. The carbon neutrality is validated by producing 1 kg of GD from CPO down to 0.0617 kg total CO<inf>2</inf> emissions since the net CO<inf>2</inf> sequestration for palm oil from oil palm plantation is taken into account. Referring to the Guthrie method, the economic indicators including the net present value (NPV) and the payback period are estimated at around 0.9 M$ in the 15th year and 9 years, respectively, if the CPO purchase price and the GD selling price are assumed to be $0.47/kg CPO and $1.98/kg GD, respectively, and the increased annual carbon credit is taken into account.
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Process design and muti-objective optimization of solid waste/biomass co-gasification considering tar formation
(2024-11-01)
Aentung, Tanawat
;
Wu, Wei
;
Patcharavorachot, Yaneeporn
Background: The co-gasification of solid waste and biomass to produce syngas is an environmentally friendly technology. Unfortunately, the tar formation in the solid waste/biomass co-gasification process would degrade the product gas quality and the overall process efficiency. Methods: In this study, the kinetics of the solid waste/biomass co-gasification is shown by the Aspen Plus simulation. Through the model validation and sensitivity analysis, it is validated that tar yield, syngas composition, and syngas yield are sensitive to gasifier temperature, steam-to-feed ratio (S/F), and blending weight ratio (B/W). It shows that the increase of the product gas yield (GY) increases CO<inf>2</inf> concentration in the product gas, but the tar yield is reduced. To address the sustainable solid waste/biomass co-gasifier, the multi-objective optimization (MOO) algorithm is implemented to maximize GY and minimize CO<inf>2</inf> concentration. For solving the MOO problem, the standard genetic algorithm (GA) coupled with response surface methodology (RSM) is performed to find the Pareto frontier plot, and the technique for order of preference by similarity to the ideal solution (TOPSIS) is used to determine optimal operating conditions. Significant Findings: Under the Pareto frontier plot and TOPSIS, a GY of 2.672 Nm³/kg, CO<inf>2</inf> concentration of 8.045 vol.%, and tar yield of 17.0617 g/Nm³ can be achieved under the optimal conditions of T = 1099.95 °C, S/F ratio = 0.79, and B/W ratio = 10.02. In addition, the CO<inf>2</inf> absorption using CaO is added to purify CO<inf>2</inf> up to 99.999 % of purity.
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Co-Gasification of Plastic Waste Blended with Biomass: Process Modeling and Multi-Objective Optimization
(2024-09-01)
Aentung, Tanawat
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Patcharavorachot, Yaneeporn
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Wu, Wei
Mixed plastic/biomass co-gasification stands out as a promising and environmentally friendly technology, since it reduces wide solid wastes and produces green hydrogen. High-quality syngas can be obtained by virtue of the process design and optimization of a downdraft fixed-bed co-gasifier. The design is based on the actual reaction zones within a real gasifier to ensure accurate results. The methodology shows that (i) the co-gasifier modeling is validated using the adiabatic RGibbs model in Aspen Plus, (ii) the performance of the co-gasifier is evaluated using cold-gas efficiency (CGE) and carbon conversion efficiency (CCE) as indicators, and (iii) the multi-objective optimization (MOO) is employed to optimize these indicators simultaneously, utilizing a standard genetic algorithm (GA) combined with response surface methodology (RSM) to identify the Pareto frontier. The optimal conditions, resulting in a CGE of 91.78% and a CCE of 83.77% at a gasifier temperature of 967.89 °C, a steam-to-feed ratio of 1.40, and a plastic-to-biomass ratio of 74.23%, were identified using the technique for order of preference by similarity to ideal solution (TOPSIS). The inclusion of plastics enhances gasifier performance and syngas quality, leading to significant improvements in CGE and CCE values.
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Improvement of biohydrogen production from biomass using supercritical water gasification and CaO adsorption
(2024-04-01)
Panichkittikul, Nitsara
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Mariyappan, Vinitha
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Wu, Wei
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Patcharavorachot, Yaneeporn
Producing biohydrogen is a promising alternative to fossil fuels, sourced from renewable energy like wind, solar, and biomass, known for its eco-friendliness and minimal greenhouse gas emissions. This study focuses on the process design and simulation of producing biohydrogen from biomass (bagasse) gasification. New integration of the water gas shift reactor and CaO adsorption process is connected to biomass gasification with the steam/supercritical water agents for improving the hydrogen production process. Simulations show that steam gasification integrated with CaO adsorption (SG-CaO) is optimized at specific conditions, resulting in high-purity hydrogen at 99.95 %. Similarly, the supercritical water gasification integrated with CaO adsorption (SCWG-CaO) requires specific conditions, achieving exceptionally pure hydrogen at 99.99 %. In terms of energy analysis, SCWG-CaO outperforms SG-CaO, with higher hydrogen yield (14.16 % vs. 14.12 %) and greater energy efficiency (42.32 % vs. 40.26 %). It shows that the SCWG-CaO is a suitable and efficient approach for biohydrogen production, considering factors such as hydrogen purity, yield, and energy efficiency.
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Simple Empirical Relation for an Evacuated-Tube Solar Collector Performance Prediction from Solar Intensity
(2023-09-01)
Pongboriboon, Nattapat
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Wu, Wei
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Chandra-ambhorn, Walairat
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Wongpromrat, Patthranit
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Bumrungthaichaichan, Eakarach
In this paper, the effect of solar intensity on the heat pipe tip temperature in a heat pipe type—evacuated-tube solar collector (HP-ETSC) was investigated. A simple relation was proposed, relating the solar intensity to the heat pipe tip temperature generated from the experimental data. This simple empirical relation was applied in a set of heat transfer equations derived to predict the heating medium temperature at the manifold outlet of the evacuated-tube solar collector. The calculated results corresponding to two types of heating medium, i.e., palm oil and water, were compared with experimental results from the literature. The results show that the average error was 6.41% for the case of palm oil and 4.66% for the case of water. Based on the case of water as a heating medium fluid, it was found that the flow rate of the heating medium fluid affected the accuracy of prediction, as the percentage error increased with the heating medium flow rate. The maximum percentage error increased from only 1.83% for a water inlet flowing at a Reynolds number of about 2.4 × 103 to 15.23% for a water flow rate at a Reynolds number of about 2.6 × 104. The correction factor was added into the correlation to predict the heat transfer coefficients of heating medium fluids. With this correction factor, the maximum error could be reduced from 11.78% to 7.29% for the palm oil case and from 15.23% to 5.57% for the water case. The average errors corresponding to palm oil and water cases could be reduced to 0.74% and 1.26%, respectively.
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Novel CO2-negative design of palm oil-based polygeneration systems
(2023-02-01)
Wu, Wei
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Supankanok, Rasa
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Chandra-Ambhorn, Walairat
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Taipabu, Muhammad Ikhsan
A palm oil-based polygeneration system (POPS), which is a combination of a fixed bed hydrotreating reactor (FBHTR), a three-phase separator, and a series of cryogenic separators, is co-production process of green diesel and liquefied petroleum gas (LPG) named Design 1. The FBHTR model is validated by experiment data and its optimal operating parameters are determined by solving the response surface methodology-based optimization algorithm. Two CO<inf>2</inf>-negative designs for the POPS named Designs 2 and 3 adopt approaches of (i) the evacuated tube solar collector (ETSC) for reducing 35% flue gas from the furnace, (ii) the amine-based CO<inf>2</inf> capture process coupling with pre- or post-separation system for producing the high-purity CO<inf>2</inf> product, and (iii) the heat integration design for reducing the energy duties of hot/cold utilities. Design 2 is validated to achieve the maximum negative net CO<inf>2</inf> emissions. Design 3 not only ensures the negative net CO<inf>2</inf> emissions, but also it produces three high-purity products (98.3% green diesel, 100% LPG, and 99.9% CO<inf>2</inf>) simultaneously.
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Process design and economic evaluation of biomass-based negative emission technologies
(2023-01-01)
Wu, Wei
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Supankanok, Rasa
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Chandra-Ambhorn, Walairat
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Pongboriboon, Nattapat
A palm oil-based polygeneration system (POPS) is simulated to produce the main product of high-purity green diesel as well as the liquefied petroleum gas (LPG) as a by-product. The CO<inf>2</inf>-negative design includes approaches of (i) a series of cryogenic separators for the recovery of approximately 65.5% of hydrogen feedstock, (ii) the evacuated tube solar collector (ETSC) for reducing 35% flue gas from the furnace, (iii) the amine-based CO<inf>2</inf> capture process for pursuing the high-purity CO<inf>2</inf> product. The economic analysis of POPS shows that the process becomes economically attractive if the diesel price and crude palm oil should be around 1.98 and 0.47 $kg-1, respectively.
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Effects of antioxidant and ceramic coating on performance enhancement and emission reduction of a diesel engine fueled by Annona oil biodiesel
(2021-08-01)
Viswanathan, Karthickeyan
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Wu, Wei
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Taipabu, Muhammad Ikhsan
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Chandra-Ambhorn, Walairat
Background: A broad investigation on alternative source of energy has been going on to find a solution to multi-faceted fossil fuel concerns namely exhaustion of fuels, energy demand, harmful emissions and environmental impact. Biodiesel is an environment-friendly and renewable alternative for diesel. In the present work, Annona seed oil has been assessed as a potential feedstock for biodiesel production. Methods: A100 was characterized by FTIR and GC-MS. Propyl Gallate (PG) was characterized by morphological study using FESEM. The elemental analysis of PG was measured using EDAX analysis. YPSZ coating was found suitable to make out the potential of A100 in diesel engine. PCCU was designed to reduce the emissions by the liquid reductant in the catalyst system. The process optimization was performed by RSM and factorial experimental design. Findings: With the YPSZ coated engine, improved characteristics of combustion and performance were noticed with A100+PG. A significant diminution on CO, HC and smoke emissions were perceived with A100+PG+CE. In addition, the work was expanded with the application PCCU for the lessening of NOx. A gradual decrement in NOx was observed with A100+PG+CE. Subsequently, A100+PG+CE with PCCU was deliberated as more prominent than other fuel samples in view of its engine characteristics.
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Modification of a solar thermal collector to promote heat transfer inside an evacuated tube solar thermal absorbe
(2021-05-01)
Supankanok, Rasa
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Sriwong, Sukanpirom
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Ponpo, Phisan
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Wu, Wei
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Chandra-Ambhorn, Walairat
Evacuated-tube solar collector (ETSC) is developed to achieve high heating medium temperature. Heat transfer fluid contained inside a copper heat pipe directly affects the heating medium temperature. A 10 mol% of ethylene-glycol in water is the heat transfer fluid in this system. The purpose of this study is to modify inner structure of the evacuated tube for promoting heat transfer through aluminum fin to the copper heat pipe by inserting stainless-steel scrubbers in the evacuated tube to increase heat conduction surface area. The experiment is set up to measure the temperature of heat transfer fluid at a heat pipe tip which is a heat exchange area between heat transfer fluid and heating medium. The vapor/ liquid equilibrium (VLE) theory is applied to investigate phase change behavior of the heat transfer fluid. Mathematical model validated with 6 experimental results is set up to investigate the performance of ETSC system and evaluate the feasibility of applying the modified ETSC in small-scale industries. The results indicate that the average temperature of heat transfer fluid in a modified tube increased to 160.32 °C which is higher than a standard tube by approximately 22 °C leading to the increase in its efficiency by 34.96%.

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