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Sustainable Production of Chitosan from Mussel Shells with Upcycling of Demineralization Effluent into Calcium Formate
(2026-05-01)
Seangarun, Chaowared
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Boonchom, Banjong
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Seesanong, Somkiat
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Boonmee, Wimonmat
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Punthipayanon, Sirichet
This study proposes a sustainable, integrated biorefinery approach to valorize mussel shell waste into high-value products, including chitin, chitosan, and calcium formate. Formic acid was employed as an effective demineralizing agent, enabling not only efficient mineral removal but also the direct conversion of the demineralization effluent into value-added calcium formate. The sequential extraction processes, demineralization, deproteinization, and decolorization, successfully yielded purified chitin (PCH), which was subsequently deacetylated to produce chitosan (CTS) with a degree of deacetylation of 85% and a molecular weight of 75 kDa. The physicochemical properties of all products were characterized using Fourier transform infrared spectroscopy (FTIR), X-ray diffraction (XRD), thermogravimetric analysis (TGA), and scanning electron microscopy (SEM). FTIR and XRD analyses confirmed the successful extraction of chitin and chitosan, demonstrating the feasibility of mussel shells as an alternative biopolymer source. In parallel, calcium formate (CCF) was obtained from the demineralization effluent with a yield of 94.19%, and its formation was verified by FTIR and XRD. Elemental analysis by XRF exhibited 98.3% CaO with minimal non-toxic impurities. The TGA/DTG profiles of CCF exhibited a well-defined two-step thermal decomposition, confirming its anhydrous form. Overall, this environmentally benign process enables the simultaneous production of multiple value-added products while significantly improving resource utilization and reducing waste generation. The proposed integrated biorefinery model offers a promising, economically viable pathway for marine biomass valorization, aligned with the Bio-Circular-Green (BCG) economy concept.
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Valorization of Mussel Shell Waste to Chitin, Chitosan, and Calcium Lactate for Bio-Green-Circular Management
(2026-04-01)
Seangarun, Chaowared
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Seesanong, Somkiat
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Boonchom, Banjong
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Boonmee, Wimonmat
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Punthipayanon, Sirichet
This study presents a green bio-upcycling strategy for converting mussel shell biowaste into three value-added products: chitin, chitosan, and calcium lactate. Mussel shells were treated chemically with lactic acid during demineralization, yielding a solid fraction rich in chitin and a liquid fraction containing calcium and lactate ions. The solid fraction was sequentially purified by deproteinization and decolorization, then deacetylated to obtain chitosan, while the liquid fraction was evaporated to obtain calcium lactate. Notably, 2.37 g of raw chitin, 2.15 g of purified chitin, and 275.87 g of calcium lactate were obtained from 100 g of mussel shells, demonstrating the efficiency of the process. FTIR spectra revealed characteristic absorption bands corresponding to α-chitin and chitosan functional groups, while XRD patterns indicated the crystalline α-chitin structure and the formation of calcium lactate pentahydrate. TGA demonstrated the high thermal stability of chitin and chitosan and confirmed the presence of crystallization water in calcium lactate. In conclusion, these results confirmed the successful preparation of α-chitin, chitosan, and calcium lactate pentahydrate, with improved purity compared to previous studies. This approach highlights the potential of the green bio-upcycling process of mussel shell waste as a renewable source for the eco-friendly production of biopolymers and calcium salts, supporting sustainable waste management and the development of the Bio-Circular-Green (BCG) economy.
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Extraction of Chitin, Chitosan, and Calcium Acetate from Mussel Shells for Sustainable Waste Management
(2025-08-01)
Seangarun, Chaowared
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Seesanong, Somkiat
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Boonchom, Banjong
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Laohavisuti, Nongnuch
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Rungrojchaipon, Pesak
In this paper, mussel shells were used to produce chitin, chitosan, and calcium acetate using chemical processes, searching for an alternative environmentally friendly biopolymer and calcium source. Mussel shells were treated with acetic acid as a demineralizing agent, resulting in separate solid fractions and calcium solution. The solid was further purified to produce chitin by deproteinization and decolorization processes, and then the deacetylation process was used to obtain chitosan. The calcium solution was evaporated to produce calcium acetate powder. The yields of extracted chitin, chitosan, and calcium acetate from 100 g of mussel shells were 2.98, 2.70, and 165.23 g, respectively. The prepared chitin, chitosan, and calcium acetate were analyzed by Fourier transform infrared (FTIR) spectrophotometry, X-ray diffraction (XRD), thermogravimetric analysis (TGA), and scanning electron microscope (SEM) to confirm the chemical and physical properties. The analysis results of chitin and chitosan revealed the similarity to chitosan derived from crustaceans and insects in terms of functional group, structure and morphologies. The prepared calcium acetate shows FTIR and XRD data corresponding to calcium acetate monohydrate (Ca(CH<inf>3</inf>COO)<inf>2</inf>·H<inf>2</inf>O) similar to synthesized calcium acetate in previous research. In addition, the mineral contents of calcium acetate identified by X-ray fluorescence (XRF) analysis exhibit 97.8% CaO with non-toxic impurities. This work demonstrated the potential of the production process of chitin, chitosan, and calcium acetate for the development of a sustainable industrial process with competitive functional performance against the commercial chitin and chitosan production process using crustacean shells and supported the implementation of a circular economy.
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Chitin and chitosan from shellfish waste and their applications in agriculture and biotechnology industries
(2025-01-01)
Rai, Sampurna
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Pokhrel, Prashant
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Udash, Pranaya
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Chemjong, Menjo
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Bhattarai, Namita
A shellfish processing plant generates only 30–40% of edible meat, while 70–60% of portions are considered inedible or by-products. This large amount of byproduct or shellfish processing waste contains 20–40% chitin, that can be extracted using chemical or greener alternative extraction technologies. Chitin and its derivative (chitosan) are natural polysaccharides with nontoxicity, biocompatible, and biodegradable properties. Due to their versatile physicochemical, mechanical, and various bioactivities, these compounds find applications in various industries, including: biomedical, dental, cosmetics, food, textiles, agriculture, and biotechnology. In the agricultural sector, these compounds have been reported to promote: plant growth, plant defense system, slow release of nutrients in fertilizer, plant nutrition, and remediate soil conditions, etc. Whereas, biotechnology applications indicated: enhanced enzyme stability and efficacy, water purification and remediation, application in fuel cells and supercapacitors for energy conversion, acting as a catalyst in chemical synthesis, etc. This review provides a comprehensive discussion on the utilization of these biopolymers in agriculture (fertilizer, seed coating, soil treatment, and bioremediation) and biotechnology (enzyme immobilization, energy conversion, wastewater treatment, and chemical synthesis). Additionally, various extraction techniques including conventional and non-thermal techniques have been reported. Lastly, concluding remarks and future direction have been provided.

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