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Characterization and properties of biodegradable thermoplastic grafted starch films by different contents of methacrylic acid
(2019-02-15)
Weerapoprasit, Chayapa
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Prachayawarakorn, Jutarat
Due to poor mechanical and thermal properties of native starch (NS) film; in the present work; NS was modified by graft copolymerization. Thermoplastic starch (TPS) grafted by methacrylic acid (MAA) with different percentage of grafting, i.e., 0%, 18.3%, 36.3%, 52.1% and 89.7% were prepared and tested. The result demonstrated that the intensity of IR peak of acrylic group increased with the increasing percentage of grafting. The higher graft copolymerization with MAA also significantly reduced degree of crystallinity. The strain at maximum load of TPS film grafted by MAA increased with the increasing percentage of grafting. However, water uptake of TPS film grafted by MAA reduced with high percentage of grafting (52.1% and 89.7%). In addition, different TPS films grafted by MAA were also examined for morphology, water vapor permeability, thermal property and biodegradable property by soil buried test.
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Effect of neem wood sawdust content on properties of biodegradable thermoplastic acetylated cassava starch/neem wood sawdust composites
(2017-03-01)
Prachayawarakorn, Jutarat
;
Hanchana, Areeya
Due to several important limitations for applications of thermoplastic starch (TPS), thermoplastic acetylated cassava starch (TPACS) polymer was reinforced by different contents of neem wood sawdust (SD). Thermoplastic cassava starch (TPCS)/SD composites were also prepared and reinforced by different SD contents and compared with the TPACS/SD composites. Morphological, thermal, and biodegradable properties of different composites were also examined. The results showed that IR absorption bands of OH stretching and OH bending vibrations shifted to lower wavenumbers, indicating new hydrogen bond formation for all composites. Stress at maximum load and Young's modulus were significantly improved when the SD content increased for all the TPACS/SD and TPCS/SD composites; strain at maximum load was higher for the TPACS/SD composites. A decrease in water uptake was detected when the SD reinforcement was incorporated into either the TPACS or TPCS matrix.
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Effect of pectin particles and cotton fibers on properties of thermoplastic cassava starch composites
(2016-03-01)
Prachayawarakorn, Jutarat
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Pattanasin, Worawan
Due to poor mechanical properties and high water uptake of thermoplastic starch (TPS), this research focused on property improvement of thermoplastic cassava starch (TPCS) using natural compatible polymers, i.e. pectin particles and cotton fibers. Different TPCS composites, reinforced by the pectin particles and/or the cotton fibers, were compounded and shaped using an internal mixer and a compression molding machine, respectively. It was found from infrared (IR) spectra that the peak position of O-H stretching of the TPCS polymer clearly shifted to lower wavenumber by the addition of the pectin particles and/or the cotton fibers. Moreover, the significant increase of stress at maximum load and Young’s modulus of the TPCS/pectin particle and the TPCS/cotton fiber composites was observed. The drop of water uptake was also found when the cotton fibers were incorporated into the TPCS matrix with/without pectin particles. In addition, X-Ray Diffraction, Scanning Electron Microscopy and Thermogravimetric Analysis were used to characterize different TPCS composites.
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Effect of pectin contents on properties of biodegradable thermoplastic mung bean starch/low-density polyethylene blends using injection molding technique
(2016-01-01)
Prachayawarakorn, Jutarat
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Hommanee, Luxana
Mechanical properties and water uptake of thermoplastic starch (TPS)/low-density polyethylene (LDPE) blend are still the main problems for applications of biodegradable polymers; therefore, properties of the TPS/LDPE blends were, then, modified using pectin, a natural gelling agent. In this study, biodegradable polymer blends; prepared from thermoplastic mung bean starch (TPMBS) and LDPE, were processed using an injection molding technique. Different contents of pectin, i.e. 0%, 2%, 4%, 6%, 8% and 10% were added into the TPMBS/ LDPE blend. It was found from Fourier Transform Infrared spectroscopy (FT-IR) spectra that O-H stretching peak shifted to lower wavenumber by the addition of pectin, even with the presence of LDPE. Better phase compatibility between the TPMBS and LDPE phases, observed from Scanning Electron Microscopy (SEM) technique, was also detected by the addition of pectin. In addition, tensile properties of the TPMBS/LDPE blends were also significantly improved by the modification of pectin. Melt flow index, water absorption, thermal degradation temperature and biodegradability of different TPMBS/LDPE blends modified by pectin were also investigated.
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Effect of starch types on properties of biodegradable polymer based on thermoplastic starch process by injection molding technique
(2015-01-01)
Tanetrungroj, Yossathorn
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Prachayawarakorn, Jutarat
In this study effects of different starch types on the properties of biodegradable polymer based on thermoplastic starch (TPS) were investigated. Different types of starch containing different contents of amylose and amylopectin were used, i.e. cassava starch, mungbean starch, and arrowroot starch. The TPS polymers were compounded and shaped using an internal mixer and an injection molding machine, respectively. It was found that the amount of amylose and amylopectin contents on native starch influence the properties of the TPS polymer. A high amylose starch of TPMS led to higher strength, hardness, degree of crystallization than the high amylopectin starch of TPCS. In addition, function group analysis by Fourier transforms infrared spectrophotometer, water absorption, and biodegradation by soil burial test were also examined.
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Effect of carrageenan on properties of biodegradable thermoplastic cassava starch/low-density polyethylene composites reinforced by cotton fibers
(2014-01-01)
Prachayawarakorn, Jutarat
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Pomdage, Wanida
Applications of biodegradable thermoplastic starch (TPS) have been restricted due to its poor mechanical properties, limited processability and high water uptake. In order to improve properties and processability, thermoplastic cassava starch (TPCS) was compounded with low-density polyethylene (LDPE). The TPCS/LDPE blend was, then, modified by a natural gelling agent, i.e. carrageenan and natural fibers, i.e. cotton fibers. All composites were compounded and processed using an internal mixer and an injection molding machine, respectively. It was found that stress at maximum load and Young's modulus of the TPCS/LDPE composites significantly increased by the addition of the carrageenan and/or the cotton fibers. The highest mechanical properties were obtained from the TPCS/LDPE composites modified by both the carrageenan and the cotton fibers. Percentage water absorption of all of the TPCS/LDPE composites was found to be similar. All modified composites were also degraded easier than the non-modified one. Furthermore, all the composites were analyzed using Fourier-transform infrared spectroscopy (FTIR), X-ray diffraction (XRD) and Scanning electron microscopy (SEM). © 2014 Elsevier Ltd.
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Effect of Agar and Cotton Fiber on Properties of Thermoplastic Waxy Rice Starch Composites
(2012-03-01)
Prachayawarakorn, J.
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Limsiriwong, N.
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Kongjindamunee, R.
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Surakit, S.
Biodegradable polymer from thermoplastic waxy rice starch (TPWRS) was prepared by internal mixer and compression molding. Since tensile properties and water uptake of the TPWRS was still the main disadvantages, the TPWRS sample was, therefore, modified by agar and/or cotton fibers. The effect of different ratios of agar:cotton fibers on properties of the TPWRS matrix were also studied. It was found that new hydrogen bonds could be found for the TPWRS matrix with the addition of different ratios of agar: cotton fibers by the detection of IR peak shift. Tensile properties of the TPWRS sample were significantly improved by the addition of agar or cotton fibers and the highest tensile properties were obtained from the TPWRS composite modified with 4:6 agar:cotton fibers. In addition, thermal degradation temperature and thermal stability of the starch were improved by the incorporation of agar and/or cotton fibers. Moreover, color measurement, morphology, water uptake and biodegradability from soil burial test were also examined. © 2011 Springer Science+Business Media, LLC.
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Effect of Cotton Fiber Contents and Lengths on Properties of Thermoplastic Starch Composites Prepared from Rice and Waxy Rice Starches
(2011-03-01)
Prachayawarakorn, Jutarat
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Ruttanabus, Pornnipa
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Boonsom, Pimvilai
Biodegradable polymer was prepared as thermoplastic starch (TPS) using rice and waxy rice starches. In order to increase mechanical properties and reduce water absorption of the TPS, cotton fiber was incorporated as the fiber reinforcement into the TPS matrix. The effect of cotton fiber contents and lengths on properties of the TPS was examined. Internal mixer and compression molding machine were used to mix and shape the samples. It was found that the thermoplastic rice starch (TPRS) showed higher stress at maximum load and Young's modulus but lower strain at maximum load than the thermoplastic waxy rice starch (TPWRS). In addition, stress at maximum load and Young's modulus of both TPRS and TPWRS increased significantly with the addition of the cotton fiber. Cotton fiber contents and lengths also affected mechanical properties of the TPRS and TPWRS composites. Moreover, water absorption of the TPRS and TPWRS composites decreased by the use of the cotton fibers. FT-IR and XRD techniques were used to study a change in functional group and crystallinity of the thermoplastic starch composites. Morphological, thermal and biodegradable properties of different thermoplastic starch composites were also investigated. © 2010 Springer Science+Business Media, LLC.
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Property improvement of thermoplastic mung bean starch using cotton fiber and low-density polyethylene
(2010-08-01)
Prachayawarakorn, Jutarat
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Hommanee, Luxsana
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Phosee, Darin
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Chairapaksatien, Parichat
Due to high water uptake and low mechanical properties of biodegradable thermoplastic starch, thermoplastic starch prepared from mung bean starch (TPMBS) was modified by the incorporation of cotton fiber and low-density polyethylene (LDPE). The effect of different ratios of cotton fiber/LDPE, i.e., 10:0, 7:3, 5:5, 3:7, and 0:10, on water uptake, mechanical, thermal, and biodegradable properties of TPMBS was examined. Different TPMBS samples were prepared using internal mixer for compounding and compression molding machine for shaping samples. It was found that the TPMBS incorporated with 10:0, 7:3, and 3:7 cotton fiber/LDPE showed an increase in the stress at maximum load and Young's modulus. Moreover, the water absorption of all of the modified TPMBS samples tended to decrease as compared to the pure TPMBS. Morphological, thermal, and biodegradable properties of different TPMBS samples were also investigated. © 2010 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
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Properties of thermoplastic rice starch composites reinforced by cotton fiber or low-density polyethylene
(2010-06-11)
Prachayawarakorn, J.
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Sangnitidej, P.
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Boonpasith, P.
Biodegradable polymer was prepared from thermoplastic rice starch (TPRS) plasticized by glycerol. In order to improve poor tensile properties and high water absorption of the TPRS, cotton fiber or low-density polyethylene (LDPE) were added into the TPRS matrix. The effect of maleic anhydride-grafted-polyethylene (MAPE) and vinyltrimethoxy silane (VTMS) compatibilizers on properties of the TPRS/LDPE specimens were also studied. The TPRS/cotton fiber, TPRS/LDPE, TPRS/LDPE/MAPE and TPRS/LDPE/VTMS samples were analyzed for tensile and morphological properties. The results showed that the incorporation of either cotton fiber or LDPE into the TPRS matrix caused the considerable improvement of tensile strength and Young's modulus. Moreover, water absorption of the TPRS samples was clearly reduced by the inclusion of cotton fiber or LDPE. In addition, phase morphology, thermal stability and biodegradability were carried out for different TPRS samples. Crown Copyright © 2010.

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