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    Item type:Publication,
    High-Performance Droplet-Based Triboelectric Nanogenerators: A Comparison of Device Configuration and Operating Parameters
    (2025-05-06)
    Chaithaweep, Kanokwan
    ;
    Pharino, Utchawadee
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    Pongampai, Satana
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    Hajra, Sugato
    ;
    Kim, Hoe Joon
    Droplet-based electricity generators (DEGs) harness liquid-solid electrification to convert water droplets impacts into electrical energy. This study systematically examines how droplet height, droplet volume, flow rate, and substrate tilt angle influence DEG performance using polytetrafluoroethylene (PTFE) as a triboelectric layer and deionized water. Three electrode designs (double, top, bottom) are evaluated, revealing that the double-electrode configuration delivers the highest output. This enhanced performance arises from synergistic droplet motion, electrical double-layer formation, and charge discharge, as validated by an equivalent circuit model. By varying droplet heights from 1–20 cm, volumes of 7.7–50 µL, flow rates of 50–300 drops/min, and tilt angles of 0–90°, an optimized setup yields −70 V and 22 mA, translating to a power density of 0.28 µW cm<sup>−2</sup>. High-speed imaging correlates these outputs with droplet impact dynamics and the resulting charge transfer. Additionally, the optimized DEG can power small electronic devices, charge capacitors, and monitor artificial acid rain in real-time, displaying distinct electrical signals compared to typical rainwater. These findings underscore the potential of DEGs as renewable energy harvesters and smart environmental sensors, paving the way for advanced on-demand power generation in diverse settings.
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    Item type:Publication,
    Theoretical investigation of rhodamine6g derivative as fluorescence metal ion sensor
    (2014-07-24)
    Puingam, R.
    ;
    Chindaduang, A.
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    Tumcharern, G.
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    Sae-Tang Phromyothin, D.
    ;
    Pratontep, S.
    The structural, energetic and optical properties of a Rhodamine6G derivative as the fluoroionphore for metal ion detection, particularly mercury, have been investigated using the time-dependent density functional theory (TD-DFT), compared to experiments. The TD-DFT calculations with the B3LYP method were conducted in the absence and the presence of metal ions. The results indicate that the absorption peaks of the pristine molecules are located at 236 and 282 nm, whereas the selective Hg<sup>2+</sup> binding peaks emerge at 263, 371 and 551 nm. A distinctive new band emerges around 550 nm, in accordance with the experiments, attributed to the metal-to-ionophore electron transfer. © 2014 Taylor & Francis Group, LLC.