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Mechanical, Thermal and Morphological Properties of Poly(Lactic Acid) and Poly(Butylene Adipate-co-Terephthalate) Blends with Organoclay
(2022-01-01)
Wacharawichanant, Sirirat
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Wongpan, Krittaphorn
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Aksornnam, Khunpat
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Phankokkruad, Manop
This work studied the effect of nanoclay surface modified with 25-30 wt% of methyl dihydroxyethyl hydrogenated tallow ammonium (Clay-DHA) on morphological, mechanical and thermal properties of poly(lactic acid) (PLA) and poly(butylene adipate-co-terephthalate) (PBAT) blends. The PLA/PBAT (75/25 w/w) blends without and with Clay-DHA were melt mixed by an internal mixer and molded by compression method. The morphological analysis observed the phase separation of PLA/PBAT blends due to minor PBAT phase dispersed as spherical shape in PLA phase, indicating a poor interfacial adhesion between PLA and PBAT phases. The incorporation of Clay-DHA could improve the compatibility of polymer blends. The tensile testing found that the addition of Clay-DHA 1 and 3 phr increased Young’s modulus of PLA/PBAT blends. The addition of Clay-DHA decreased the strain at break of PLA/PBAT blends. The thermal degradation of PLA/PBAT blends and composites showed the similar thermal degradation process step. The addition of Clay-DHA was no effect on thermal stability and thermal properties of PLA/PBAT blends.
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Influence of cellulose fiber content on morphology and properties of poly(Lactic acid)/propylene-ethylene copolymer/cellulose composites
(2021-01-01)
Wacharawichanant, Sirirat
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Opasakornwong, Patteera
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Poohoi, Ratchadakorn
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Phankokkruad, Manop
This work studied the effects of medium-length fibrous cellulose (MFC) on the morphology, mechanical and thermal properties of poly(lactic acid) (PLA)/propylene-ethylene copolymer (PEC) (90/10) blends. The morphological analysis of PLA/MFC composites observed MFC fibers inserted in the PLA matrix and MFC appeared agglomeration when added high MFC loading. The phase morphology showed the two-phase separation of PLA/PEC blends. The presence of PEC reduced the agglomeration of MFC fibers in polymer matrix. The tensile stress and strain curves found that the ultimate stress of PLA was the highest value and the addition of MFC increased Young’s modulus of PLA/MFC and PLA/PEC/MFC composites. The PEC presence improved the strain at breaking point of PLA/PEC blends. The thermal properties found that the incorporation of MFC did not improve the thermal stability of PLA/MFC and PLA/PEC/MFC composites due to the PLA had degradation temperature higher than MFC.
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Improvement of poly(Lactic acid) properties by ethylene-octene copolymer and organoclay
(2020-01-01)
Wacharawichanant, Sirirat
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Hanjai, Paweena
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Khongaio, Sanya
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Phankokkruad, Manop
The work studied the morphological, mechanical and thermal properties of poly(lactic acid) (PLA)/ethylene-octene copolymer (EOC) blends before and after adding the montmorillonite clay surface modified with 25-30% of octadecylamine (clay-ODA). The PLA/EOC blends and composites were prepared by melt mixing in an internal mixer. The EOC contents were 5, 10, 20, 30 wt% and clay-ODA contents were 1 and 3 phr. The morphology analysis showed that the addition of clay-ODA could improve the miscibility of PLA and EOC phases due to the domain size of dispersed EOC phase decreased with increasing clay-ODA content. X-ray diffraction revealed the formation of intercalated/exfoliated structure in PLA/clay-ODA and PLA blend composites. The mechanical properties showed that the impact strength of PLA/EOC blends dramatically increased with increasing EOC content up to 10 wt%. The strain at break of PLA blends increased with increasing EOC content. Moreover, the incorporation of clay-ODA increased significantly Young’s modulus of PLA and PLA/EOC blends with increasing clay-ODA content. The thermal stability of PLA/EOC blends improved with the addition of a small amount of clay-ODA.
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Morphology and mechanical properties of poly(Lactic acid) with propylene-ethylene copolymer and α-cellulose
(2019-01-01)
Wacharawichanant, Sirirat
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Opasakornwong, Patteera
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Poohoi, Ratchadakorn
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Phankokkruad, Manop
This work studied the improvement of poly(lactic acid) (PLA) properties by adding propylene-ethylene copolymer (PEC) and α-cellulose (AC). The PLA blends and composites were melt mixed by an internal mixer and molded by compression method. The morphological analysis observed the phase separation of PLA/PEC blends due to minor PEC phase dispersed as spherical shape in PLA phase, indicating a poor interfacial adhesion between PLA and PEC phases. The incorporation of AC did not improve the compatibility of polymer blends. Young’s modulus and tensile strength of PLA blends reduced with increasing amount of PEC because the elastics of ethylene molecules in PEC structure. Young’s modulus of PLA/PEC/AC composites increased with increasing AC contents. The stress at break of the PLA/PEC blends was improved with the presence of AC. The strain at break of PLA/PEC blends increased with increasing PEC contents, and the presence of AC showed the decrease of strain at break of PLA/PEC blends.
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Morphology, mechanical and thermal properties of poly(Lactic acid)/propylene-ethylene copolymer/cellulose composites
(2019-01-01)
Wacharawichanant, Sirirat
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Opasakornwong, Patteera
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Poohoi, Ratchadakorn
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Phankokkruad, Manop
This work studied the effects of various types of cellulose fibers on the morphology, mechanical and thermal properties of poly(lactic acid) (PLA)/propylene-ethylene copolymer (PEC) (90/10 w/w) blends. The PLA/PEC blends before and after adding cellulose fibers were prepared by melt blending method in the internal mixer and molded by compression method. The morphological analysis observed that the presence of cellulose in PLA did not change the phase morphology of PLA, and PLA/cellulose composite surfaces were observed the cellulose fibers inserted in PLA matrix and fiber pull-out. The phase morphology of PLA/PEC blends was changed from brittle fracture to ductile fracture behavior and showed the phase separation between PLA and PEC phases. The presence of celluloses did not improve the compatibility between PLA and PEC phases. The tensile stress and strain curves found that the tensile stress of PLA was the highest value. The addition of all celluloses increased Young's modulus of PLA. The PEC presence increased the tensile strain of PLA over two times when compared with neat PLA and PLA was toughened by PEC. The incorporation of cellulose fibers in PLA/PEC blends could improve Young's modulus, tensile strength, and stress at break of the blends. The thermal stability showed that the degradation temperatures of all types of cellulose were less than the degradation temperatures of PLA. Thus, the incorporation of cellulose in PLA could not enhance the thermal stability of PLA composites and PLA/PEC composites. The degradation temperature of PEC was the highest value, but it could not improve the thermal stability of PLA. The incorporation of cellulose fibers had no effect on the melting temperature of the PLA blend and composites.
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Improvement of poly(Lactic acid) properties by using acrylonitrile-butadiene rubber and polyethylene-g-maleic anhydride
(2019-01-01)
Wacharawichanant, Sirirat
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Wisuttrakarn, Chawisa
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Chomphunoi, Kasana
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Phankokkruad, Manop
This research prepared poly(lactic acid) (PLA) and PLA/acrylonitrile-butadiene rubber (NBR) blends before and after adding polyethylene-g-maleic anhydride with 3 wt% of maleic anhydride (PE-g-MA3) 3 phr. The effects of NBR and PE-g-MA3 on morphological, mechanical and thermal properties of PLA and PLA blends were discussed. The morphological analysis observed the two-phase morphology of PLA/NBR blends, and it was observed the cavities generated due to NBR phase detachment during sample fracture, and droplets of NBR phase at higher NBR content. The PE-g-MA3 addition could improve adhesion between PLA and NBR phases due to the decrease of cavities in PLA matrix and droplet size of NBR. The mechanical properties showed the impact strength and strain at break of PLA/NBR blends dramatically increased when the amount of NBR increasing. The addition of PE-g-MA3 significantly improved the impact strength of PLA/NBR blends. The thermal properties showed the NBR addition had effect slightly on the melting temperature of PLA/NBR blends. The filling of NBR and PE-g-MA3 greatly decreased the percent crystallinity of PLA more than two times. The thermal degradation of pure PLA and NBR proceeds by one step, while the thermal degradation process of PLA/NBR and PLA/PE-g-MA3 proceeds by two steps. Which the first step showed a large mass loss of PLA degradation and the second step showed a small mass loss of PE-g-MA and NBR degradation.
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Mechanical properties and phase morphology of poly(lactic acid)/acrylonitrile-butadiene rubber/organoclay nanocomposites prepared by melt blending
(2018-01-01)
Wacharawichanant, Sirirat
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Chomphunoi, Kasana
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Wisuttrakarn, Chawisa
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Phankokkruad, Manop
This work investigated the mechanical properties and phase morphology of poly(lactic acid) (PLA)/acrylonitrile-butadiene rubber (NBR) blends and nanocomposites, which prepared by melt blending in an internal mixer. The contents of NBR were 5, 10, 15 and 20 wt% and the content of organoclay was 3 phr. The impact test showed that the impact strength of PLA/NBR blends increased with an increase of NBR content and the impact strength of the blends was more than eight times by adding NBR 10 wt% when compared with neat PLA. The tensile test showed that Young's modulus and tensile strength of PLA/NBR blends and nanocomposites decreased after adding NBR and organoclay. While the strain at break of the NBR blends increased with increasing NBR content. This result is attributed to the rubber phase in NBR in a cause the increment of elongation and elasticity in PLA/NBR blends. The morphology of PLA/NBR blends observed the fractured surface was rougher than that of pure PLA. This observation indicates that the addition of NBR in PLA can change the brittle fracture of PLA to ductile fracture, which has an effect to the strain at break or elongation of PLA. However, the morphology of the PLA/NBR blends were also observed the phase separation of the dispersed NBR phase and PLA matrix phase, and appeared the voids in a polymer matrix. The addition of organoclay had an effect slightly on the morphology of the blends. From X-ray diffraction, results found that PLA/organoclay and PLA/NBR/organoclay nanocomposites showed the intercalated structure, which PLA chains were inserted into the interlayer of clay due to the increase of d-spacing.

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