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Subject: search.filters.subject.Bi(Zn 0.5Ti0.5)O3

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    Phase transition and dielectric properties of lead free (K 0.5Na0.5)NbO3- Bi(Zn0.5Ti 0.5)O3 piezoelectric ceramics
    (2009-12-01)
    Sutapun, Manoon
    ;
    Vittayakorn, Naratip
    Lead-free piezoelectric ceramics of (1-x)(K0.5Na0.5) NbO3 - x(Bi(Zn0.5Ti0.5)O3; x = 0.00-0.30 were prepared via the two-stage mixed oxide fabrication technique. The crystal structure and ferroelectric phase transitions were studied by means of x-ray diffraction and thermal measurements. XRD results showed that a single-phase perovskite structurewas formed in the ceramics with x ≤ 0.25. For the ceramics with x = 0.30, a small amount of secondary phase Bi2Ti2O7 with a cubic structure was formed. The ceramics with a perovskite structure showed an orthorhombic phase at 0.00 ≤ x ≤ 0.010 and became rhombohedral at 0.010 < x ≤ 0.015 before transforming to a cubic phase at 0.015 < x ≤ 0.25. In addition, DSC results showed that the phase transition temperature of orthorhombic-tetragonal (TO-T) and tetragonal-cubic (TC) decreased when a small amount of BZT was added. The trend of enthalpy for orthorhombic → tetragonal phase transition and tetragonal → cubic phase were found to reduce with progressive increases in small amounts of BZT content. This behavior could originate from the more complex occupation of the A and B sites in an ABO3 perovskite structure. Copyright © Taylor & Francis Group, LLC.
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    Preparation and properties of lead free bismuth sodium titanate-bismuth zinc titanate ceramics
    (2009-12-01)
    Muanghlua, Rangson
    ;
    Niemcharoen, Surasak
    ;
    Vittayakorn, Wanwilai C.
    ;
    Tungsitvisetkul, Nattapong
    ;
    Chinwaro, Pimjan
    Lead-free piezoelectric ceramics based on (1-x)Bi1/2Na1/2TiO3 - x Bi(Zn1/2 Ti1/2)O3 (x = 0.0, 0.02, 0.04, 0.06, 0.08, 0.10, 0.20, 0.30, 0.40, and 0.5) were obtained via solid-state processing techniques. The influence of BZT addition on BNT characteristics, sintering, microstructure and properties was investigated. A single perovskite phase with rhombohedral symmetry was obtained for Bi(Zn1/2Ti1/2)O3 substitutions of up to 10 mole%. A small amount of BZT was effective for improving both sintering behavior and dielectric properties of BNT ceramics. Optimized dielectric properties were obtained for samples with a maximum density of ρ = 98.3% for the composition, x = 0.1. Copyright © Taylor & Francis Group, LLC.