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Evaluating limit of detection and quantification for higher heating value and ultimate analysis of fast-growing trees and agricultural residues biomass using NIRS
(2023-10-09)
Shrestha, Bijendra
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Shrestha, Zenisha
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Posom, Jetsada
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Sirisomboon, Panmanas
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Shrestha, Bim Prasad
Accurate non-destructive assessment of biomass energy properties is essential for optimizing its use as an alternative fuel. In this study, 200 biomass samples were used to determine higher heating value (HHV) and 120 biomass samples for analyzing ultimate analysis parameters using near-infrared spectroscopy within the full wavenumber range of 12489.48 – 3594.87 cm-1. The samples were grounded, and five different types of partial least squares regression (PLSR) models were developed using traditional preprocessing, multi-preprocessing (MP) with 5 range, MP with 3 range, genetic algorithm, and successive projection algorithm. Limit of detection (LOD) and quantification (LOQ) were calculated using the best-performing model among five different PLSR models for HHV in kJ/kg, as well as the weight percentage (wt.%) of carbon (C), oxygen (O), hydrogen (H), and nitrogen (N). The LOD and LOQ for HHV were calculated as 622.42 kJ/kg and 1886.13 kJ/kg, respectively. Additionally, LOD and LOQ for ultimate analysis parameters, including C, O, H, and N were calculated as: 3.24 weight percentage (wt.%) and 9.81 wt.% for C, 2.04 wt.% and 6.18 wt.% for O, 0.35 wt.% and 1.05 wt.% for H, and 0.22 wt.% and 0.68 wt.% for N. The LOD and LOQ values for HHV, C, O, and H were lower than the minimum reference values used for model development, demonstrating the models’ high sensitivity and potential to reliably detect and precisely quantify these parameters. However, the LOD and LOQ values exceeded the minimum reference value used during model development for the N, indicating that the selected models have certain limitations in assessing the N content in biomass. The sample range should be expanded for wt.% of N to enhance the model’s performance, surpassing the LOD and LOQ values. This will improve the overall sensitivity of the model for reliable detection and quantification of N content in biomass samples.
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Improving the non-destructive maturity classification model for durian fruit using near-infrared spectroscopy
(2023-03-01)
Ditcharoen, Sirirak
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Sirisomboon, Panmanas
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Saengprachatanarug, Khwantri
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Phuphaphud, Arthit
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Rittiron, Ronnarit
The maturity state of durian fruit is a key indicator of quality before trading. This research aims to improve the near-infrared (NIR) model for classifying the maturity stage of durian fruit using a completely non-destructive measurement. Both NIR spectrometers were investigated: the short wavelength NIR (SWNIR) ranging from 450 to 1000 nm and long wavelength NIR (LWNIR) ranging from 860 to 1750 nm. The samples collected for experimentation consisted of four stages: immaturity, prematurity, maturity, and ripe. Each fruit was scanned at the rind position on the main fertile lobe (header, middle, and tail) and stem. The classification models were developed using three supervised machine learning algorithms: linear discriminant analysis (LDA), support vector machine (SVM), and K-Nearest neighbours (KNN). The analysis results revealed that the use of durian rind spectra only obtained between 83.15% and 88.04% accuracy for the LWNIR spectrometer, while the SWNIR spectrometer provided 64.73 to 93.77% accuracy. The performance of model increases when developing with combination between rind and stem spectra. The LDA model developed using a combination of rind and stem spectra provided the greatest efficiency, exhibiting 97.28% and 100% accuracy for LWNIR and SWNIR spectrometers, respectively. The LDA model is therefore recommended for obtaining spectra from smoothing moving average (MA) + baseline of rind position and when used in combination with the MA + standard normal variance (SNV) of stem spectra. The NIR spectroscopy indicated high potential for non-destructive estimation of the durian maturity stage. This process could be used for quality control in the durian export industry to solve the problem of unripe durian being mixed with ripe fruit.
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Classification of N, P, and K concentrations in durian (Durio zibethinus murray cv. mon thong) leaves using near-infrared spectroscopy
(2022-08-24)
Phanomsophon, Thitima
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Jaisue, Natthapon
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Tawinteung, Nukoon
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Khurnpoon, Lampan
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Sirisomboon, Panmanas
A good durian fruit should be supported by sufficient nutrient concentrations. If farmers can quickly determine the nutrient concentration in leaves, they can control fertilisation. Near-infrared (NIR) spectroscopy is a rapid non-destructive test for estimating nutrient concentration. Measuring nutrient concentrations requires chemical analysis and is a time-consuming process. The aim of this paper is a preliminary test for classifying the N, P, and K concentration levels to determine the possibility of creating models in the future to help farmers obtain information on durian tree nutrient requirements quickly. The models reported in this paper were created by PLS-DA, which had higher accuracy than SVM and the SIMCA method. Fresh durian leaf samples were used, and the spectra provided greater accuracy than the dried ground leaf sample spectra. The classification models had an accuracy of 88.89, 81.25, and 86.36% for predicting N, P, and K, respectively.
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Application of near-infrared spectroscopy in detection of steroids adulteration in traditional thai medicines
(2022-01-01)
Sirisomboon, Panmanas
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Phetpan, Kittisak
This study aimed to focus on applying near-infrared (NIR) spectroscopy to identify the adulteration of traditional Thai medicine products (TTM) with steroids. One hundred and ten samples were prepared with pure TTM and ten different steroid concentrations (0.25-5 mg steroid/g TTM). Fourier transform near-infrared (FT-NIR) spectrometer was used to scan TTM samples. The partial least squares (PLS) regression was used for the NIR spectroscopic model development to predict the level of steroid adulteration in TTM. For classification analysis, the principal component analysis (PCA) was used to discriminate 11 groups of raw TTM spectra (220 spectra). The developed PLS model accompanied by 3 latent variables (LVs) could predict the steroid content in TTM accurately with the coefficient of determination of prediction (r2) of 98.20%, root mean square error of prediction (RMSEP) of 0.22 mg steroid/g TTM, and residual prediction deviation (RPD) of 7.46. Furthermore, the PCA approach was possible to discriminate among the groups of TTM. The study showed NIR spectroscopy's capability to be used as a powerful technique to evaluate the steroid adulterated in TTM. This report is useful for food and drug association, patients, pharmaceuticals, and medical sectors.
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Evaluation of physiological properties and texture traits of durian pulp using near-infrared spectra of the pulp and intact fruit
(2021-04-01)
Onsawai, Phalanon
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Phetpan, Kittisak
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Khurnpoon, Lampan
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Sirisomboon, Panmanas
This study aimed to investigate the feasibility of non-destructively predicting physiological properties (color, dry matter, and soluble solids) and texture properties (initial firmness, average firmness, rupture force, rupture distance, toughness, average penetrating force, and penetrating energy) of ‘Monthong’ durian using Fourier transform near-infrared spectroscopy of the pulp of the largest locule, the intact fruit at the largest locule, and the stylar end of the intact fruit. Based on partial least squares regression modeling, the internal quality evaluation of durian obtained by scanning the pulp could provide rough screening capability, with coefficient of determination of validation (r2), root mean square error of prediction (RMSEP), and the ratio of standard error of validation to standard deviation (RPD) values for the dry matter content, average penetrating force, and rupture force of 0.89, 3.60%, and 3.27; 0.73, 5.53 N, and 1.95; and 0.74, 6.15 N, and 1.96, respectively. Only the dry matter content of the pulp could be reasonably predicted based on scanning the intact durian fruit at the largest locule, with r2, RMSEP, and RPD values of 0.79, 5.23%, and 2.18, respectively. This finding could be applied at the first stage of trade between durian agriculturalists and exporters to prevent the exportation of immature durian and would be helpful for the industries producing frozen durian pulp and intact durian fruit for export.
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Development of the partial least-squares model to determine the soluble solids content of sugarcane billets on an elevator conveyor
(2021-01-01)
Udompetaikul, Vasu
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Phetpan, Kittisak
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Sirisomboon, Panmanas
This study aimed to determine the optimum multivariate model for monitoring the soluble solids content (SSC) of sugarcane billets being transferred on a conveyor. The study covered two main issues: the exploration of an appropriate spectral range (450–900 nm versus 700–900 nm) and the assessment of the influence of different levels of cane billets on an elevator via modelling to predict the SSC values. Partial least squares regression (PLSR) was used for model development. Modelling using the range of 450–900 nm employed 4 latent variables (LVs) and showed the coefficient of determination (R2) and root mean squares error of prediction (RMSEP) of 0.83 and 0.29 °Brix, respectively. This caused the model established using the range of 700–900 nm, employed 3 LVs and provided the R2 and RMSEP values of 0.81 and 0.31 °Brix, respectively, seems more appropriate. In case of assessing the different cane levels on the conveyor, the outcomes presented model performance of the full and half cane levels in predicting half and full cane datasets with R2 and RMSEP of 0.52 and 0.55 °Brix and 0.53 and 0.48 °Brix, respectively. This showed that the different levels affected the SSC predictive accuracy of the model. The combined model was developed to cover variations of this difference and was used to predict two external sets. The predictions of ninety and thirty samples that were collected from the same and different growing seasons as the samples for the modelling presented the R2, RMSEP and RPD of 0.70, 0.42 °Brix and 1.83 and 0.56, 0.42 °Brix and 2.00, respectively.
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An online visible and near-infrared spectroscopic technique for the real-time evaluation of the soluble solids content of sugarcane billets on an elevator conveyor
(2018-11-01)
Phetpan, Kittisak
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Udompetaikul, Vasu
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Sirisomboon, Panmanas
The aim of this research study is to propose a prototype online detection system based on the visible and near-infrared spectroscopic (vis/SW-NIR) technique for the real-time evaluation of the soluble solids content (SSC) of sugarcane billets on an elevator conveyor. The system consisted of two main parts, a cane billet elevator and a spectral acquisition device. An elevator speed of 2 m/s was used for the transfer of sugarcane billets. Spectra acquisition was performed using four 50 W tungsten halogen lamps as a light source in conjunction with vis/SW-NIR spectrometer in reflectance mode. Partial least squares regression (PLSR) was subsequently used to correlate the spectra with the experimentally determined SSC values. The model performance was then assessed using an independent prediction set. The model was found to display a coefficient of determination of prediction (R2) of 0.785, a root mean square error of prediction (RMSEP) of 0.30 and a residual predictive deviation (RPD) of 2.16. The result on the prediction set confirm that the proposed system is suitable for the online SSC measurement of the sugarcane billets on an elevator conveyor.
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Evaluation of pyrolysis characteristics of milled bamboo using near-infrared spectroscopy
(2017-01-01)
Posom, Jetsada
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Saechua, Wanphut
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Sirisomboon, Panmanas
This paper reports the development of a rapid and low-cost method based on near-infrared spectroscopy as an alternative for thermogravimetric determination of the pyrolysis characteristics, including T<inf>onset</inf>, T<inf>sh</inf>, T<inf>peak</inf>, T<inf>offset</inf>and DTG<inf>peak</inf>, of milled bamboo. T<inf>onset</inf>is the extrapolated onset temperature that is calculated from the partial peak resulting from the decomposition of the hemicellulose component, T<inf>sh</inf>is the temperature corresponding to the overall maximum of the hemicellulose decomposition rate, DTG<inf>peak</inf>is the overall maximum of the cellulose decomposition rate, T<inf>peak</inf>is the temperature corresponding to the overall maximum of the cellulose decomposition rate and T<inf>offset</inf>is the extrapolated offset temperature of the DTG<inf>peak</inf>curves determined using thermogravimetric analysis (TGA). The models may be used to control the pyrolysis processes of bamboo to achieve the most economical and environmental conditions. 80 samples of bamboo with various circumferences of culms in the ranges of approximately 16–18, 18–20, 20–22, 22–24, 24–26, 26–28, 28–30, 30–32, 32–34, 34–36, 36–38 and 38–40 cm were randomly collected for optimization of the models. The models were optimized by partial least squares regression (PLSR) with 80% of samples for the calibration set and 20% for the validation set. For T<inf>onset</inf>, T<inf>sh</inf>, T<inf>peak</inf>, T<inf>offset</inf>and DTG<inf>peak</inf>the models showed coefficients of determination (R2) of 0.566, 0.845, 0.917, 0.973, and 0.671; root mean square errors of prediction (RMSEP) of 9.7 °C, 4.36 °C, 3.77 °C, 2.66 °C, and 0.428 wt loss %/min; ratios of prediction to deviation (RPD) of 1.52, 2.58, 3.48, 3.55, and 1.75; and biases of −0.344 °C, −0.765 °C, 0.349 °C, −5.41 °C, and 0.045 wt loss %/min, respectively. In addition, the results showed that pyrolysis characteristics did not depend on the circumference. The vibrational bands of water and CH<inf>3</inf>, O[sbnd]H stretch, first overtones of Ar–OH, CH<inf>2</inf>and HC[dbnd]CH in the cellulose and lignin structures, O[sbnd]H hydrogen bonds of polyvinyl alcohol and C[sbnd]H stretch corresponding to the first overtone of CH<inf>2</inf>had the highest influence on the values of T<inf>onset</inf>, T<inf>sh</inf>, T<inf>peak</inf>, and T<inf>offset</inf>, respectively. The vibrational band of the C[sbnd]O[sbnd]C asymmetrical stretches of cellulose and hemicellulose, and the combination of O[sbnd]H stretch and HOH bend of polysaccharides influenced the DTG<inf>peak</inf>value. These results are beneficial for studying the thermal behaviour of milled bamboo as a potential resource for producing biofuels, especially in the pyrolysis process.
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Sensory quality evaluation of rice using visible and shortwave near-infrared spectroscopy
(2015-05-04)
Lapchareonsuk, Ravipat
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Sirisomboon, Panmanas
This research aimed to develop both visible and shortwave near-infrared spectroscopy to evaluate the sensory qualities of cooked rice. In this study, four different types of milled rice were used: parboiled, white, new Jasmine, and aged Jasmine. The sensory qualities of cooked rice (adhesiveness, hardness, stickiness, dryness, whiteness, and aroma) were evaluated by a trained sensory panel. The results demonstrated that these sensory attributes correlated with visible and shortwave near-infrared spectral data. Both visible and shortwave near-infrared spectroscopy models used for predicting the sensory qualities of cooked rice were established using partial least squares regression. All prediction results for sensory qualities showed a range of R2<inf>val</inf> between 0.837 and 0.918, with the highest found for aroma (0.918). The proposed models can be utilized in quality control by the rice industry.
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Evaluation of the moisture content of Jatropha curcas kernels and the heating value of the oil-extracted residue using near-infrared spectroscopy
(2015-02-01)
Posom, Jetsada
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Sirisomboon, Panmanas
The use of near-infrared spectroscopy for evaluation of moisture content of Jatropha curcas kernels and heating value of its residue after oil extraction were studied. In total, 100 samples of whole kernels from green, yellow and black fruits and oven-dried kernels scanned in diffuse reflection mode using a Fourier transform NIR spectrometer at wave numbers of 1,250,000-400,000m-1 were used to develop moisture-predicting models. The corresponding residues after the oil extraction of the samples scanned in transflection mode using the same spectrometer and wave number range were used to develop the heating-value-predicting models. The models correlating the spectral data and the corresponding values measured using the reference method were developed by partial least squares regression and were validated using a test set. For the moisture content and heating value, coefficients of determination (R2) were 0.969 and 0.860, root mean square errors of prediction (RMSEP) were 4.0%wb and 360Jg-1, biases were -0.7%wb and -17Jg-1 and ratios of prediction to deviation (RPD) were 5.7 and 2.6, respectively. In addition, vibration bands of fibre and cellulose had important effects on the prediction of the heating value.

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