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    Enhancing the properties of a hypereutectic Al-Fe alloy through recycled aluminum scrap and ultrasonic melt processing
    (2025-10-01)
    Tangsuksan, Tawatchai
    ;
    Pandee, Phromphong
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    Diewwanit, Onnjira
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    Limmaneevichitr, Chaowalit
    ;
    Tyurnina, Anastasia V.
    This paper focuses on the effects of using recycled aluminum beverage cans and ultrasonic melt processing (USP) on the microstructure and properties of a hypereutectic Al-Fe alloy that has potential in structural and electric applications. The proportion of recycled aluminum scrap used as the starting material varied, and its influence on grain refinement, intermetallic phase formation, precipitation hardening, and mechanical performance was examined. Ultrasonic melt processing (USP) was applied to refine the microstructure and improve phase distribution. The experimental results showed that both the addition of recycled aluminum scrap and USP significantly increased the hardness and tensile strength of the alloys, with further improvements observed after optimal aging treatments, although ductility slightly decreased. Additionally, the presence of alloying elements from the recycled scrap, such as Mg, Mn, Si, and Cu, led to a reduction in electrical conductivity while improving the precipitation hardening response. This study highlights the potential of using recycled materials and advanced processing techniques to develop sustainable, high-performance aluminum alloys for various industrial applications.
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    Ambient- and elevated temperature properties of Sc- and Zr-modified Al–6Ni alloys strengthened by Al3Ni microfibers and Al3(Sc,Zr) nanoprecipitates
    (2022-04-28)
    Suwanpreecha, C.
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    Rakhmonov, J. U.
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    Pandee, P.
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    Dunand, D. C.
    The eutectic Al–6Ni (wt.%) alloy exhibits excellent strength at ambient and elevated temperature, provided by a high volume fraction of Al<inf>3</inf>Ni microfibers formed during solidification. Here, Al–6Ni is micro-alloyed with Sc and Zr (with 0.1Sc+0.2Zr, 0.2Sc+0.4Zr and 0.3Sc+0.2Zr, wt.%), creating two additional populations of primary and secondary Al<inf>3</inf>(Sc,Zr) precipitates. The fully eutectic microstructure (α-Al + Al<inf>3</inf>Ni) observed in Al–6Ni alloy changes, with Sc and Zr addition to hypoeutectic microstructure with primary α-Al grains nucleated on solidification by primary Al<inf>3</inf>(Sc,Zr) precipitates. Upon subsequent aging, fully-coherent Al<inf>3</inf>(Sc,Zr) nanoprecipitates form in the α-Al matrix between Al<inf>3</inf>Ni microfibers, providing substantial precipitation strengthening, which is maintained for up to 1 month at 350 °C. Alloy strength - both at ambient temperature and during creep at 300 °C - can be quantitatively described through a superposition of precipitation strengthening by Al<inf>3</inf>(Sc,Zr) nanoprecipitates and load-transfer strengthening by Al<inf>3</inf>Ni microfibers.
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    Laser surface polishing of material extrusion additively manufactured 316L stainless steel
    (2026-02-01)
    Hemwat, Jirayu
    ;
    Saetang, Viboon
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    Qi, Huan
    ;
    Seenawat, Mongkol
    ;
    Material extrusion additive manufacturing (MEX) provides a cost-effective pathway for fabricating metallic components; however, its industrial use remains limited by surface defects and high roughness. This study evaluates nanosecond laser polishing (LP) as a post-processing method to improve the surface characteristics of 316L stainless steel produced by Bound Metal Deposition (BMD). The objective is to understand how laser beam diameter, scan speed, and processing atmosphere (air vs. argon) influence surface integrity. Polishing experiments were performed using 50 W and 100 W laser power with beam diameters of 200 and 400 μm at scanning speeds of 100–400 mm/s. Areal roughness (S<inf>a</inf>), surface waviness (W<inf>a</inf>), surface chemistry, subsurface microstructure, and electrochemical response were systematically characterized. Laser polishing reduced S<inf>a</inf> from 2.003 μm to 0.371 μm (81 % reduction) and W<inf>a</inf> by up to 43 %. Polishing in argon produced cleaner melt tracks with minimal oxidation, a refined remelted layer, and enhanced passive film formation, leading to improved corrosion resistance (E<inf>corr</inf> improved from −0.466 V to −0.062 V). These findings demonstrate that LP effectively mitigates the surface limitations of BMD-fabricated stainless steel and provide process guidelines for achieving high-quality functional surfaces in MEX metal components.
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    Characterization of the Anodic Film and Corrosion Resistance of an A535 Aluminum Alloy after Intermetallics Removal by Different Etching Time
    (2022-07-01) ;
    Eskin, Dmitry
    ;
    Limmaneevichitr, Chaowalit
    ;
    Kengkla, Nattarat
    ;
    Diewwanit, Onnjira
    The objective of this study was to improve the corrosion resistance of an A535 alloy by removing intermetallics on the alloy surface by alkaline etching to improve the morphologies and properties of the anodic film that was sealed with different sealants. It was found that alkaline etching for 4 min was suitable for dissolving intermetallic particles and simultaneously providing sufficient roughness for the adhesion of an oxide film to the Al matrix. The effect of alkaline etching revealed that a decrease in the intermetallic fraction from 21% to 16% after etching for 2 and 4 min, respectively, corresponded to the increase in the surface roughness, thickness, and consistency of the anodic film. It was also demonstrated that the surface morphology of the anodic films after stearic acid sealing was more uniform and compact than that after nickel fluoride sealing. The electrochemical polarization curves and salt spray test proved that the alloy etched for 4 min and sealed with stearic acid had better corrosion resistance as compared with the aluminum alloy sealed with nickel fluoride.
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    The improvement of deformability in AA7075 alloy through cryogenic treatment and its correlation with microstructural evolution and FE modelling
    (2024-12-01) ;
    Eskin, Dmitry G.
    ;
    Patakham, Ussadawut
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    Chancharoen, Wares
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    Seehanam, Saran
    Cryogenic treatment has high potential for improving the deformation behavior through the recrystallization at a low temperature. In this work, true stress–strain curves were obtained via compression tests to understand the deformation behavior of an AA7075 under cryogenic conditions. Results showed a significant improvement in the flow stress of AA7075, increasing from 260 to 560 MPa at the yield point. The strain hardening exponent (n) also increased from 0.25 to 0.35 after deformation at cryogenic temperatures. The presence of Al<inf>2</inf>CuMg phase influenced the deformation texture of the tested aluminum alloy, resulting in more elongated grains and fine sub-grains after deformation at cryogenic temperatures, due to the hindered recrystallization. Microstructure evolution after deformation at room and cryogenic temperatures was investigated using EBSD technique to characterize texture and recrystallized grains. The results indicated that the spacing of the high-angle grain boundaries (HAGBs) in the sample deformed at room temperature was slightly larger than in the cryogenically treated sample. The alloy deformed at the cryogenic temperature exhibited a higher strain hardening exponent (n = 0.35) compared to room temperature deformation (n = 0.25). Furthermore, finite element analysis supported the experimental findings, showing that the Plastic Equivalent Strain (PEEQ) of the model tested at cryogenic temperature was higher than at room temperature, attributed to grain refinement during low-temperature deformation. The calculated effective stress responses at cryogenic temperatures for the investigated flow stress aligned well with the experimental results. These new aspects and mechanisms of deformation of aluminum alloys at cryogenic temperatures can improve the formability of high-strength alloys in the future production of more complex and integrated lightweight components.
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    Primary Si refinement and eutectic Si modification in Al-20Si via P-Ce addition
    (2022-03-01)
    Chokemorh, Peerawit
    ;
    Pandee, Phromphong
    ;
    ;
    Patakham, Ussadawut
    ;
    Limmaneevichitr, Chaowalit
    Enhancing the mechanical properties of hypereutectic Al-Si alloys by refining the primary and eutectic Si morphology is very challenging. In this study, the refinement mechanism of primary and eutectic Si morphologies via the simultaneous addition of P-Ce into the Al-20Si alloy was studied. Microstructural analysis revealed that the primary and eutectic Si morphologies were significantly refined, which increased the tensile strength. Furthermore, the addition of Ce, up to 0.6 wt%, can result in the formation of Ce-rich intermetallic phases, which may lead to a significantly increased tensile strength while retaining the ductility of the alloy. The ultimate tensile strength of the Al-20Si alloy increased from 96 to 175 MPa, and the elongation increased from 1.0% to 1.7% with the addition of P-Ce. Moreover, the wear resistance of the alloy improved. The added P and Ce did not react with each other to form an intermetallic compound; therefore, this method can simultaneously refine primary and eutectic Si.
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    Enhancing ambient and elevated temperature performance of hypoeutectic Al–Ce cast alloys by Al3(Sc,Zr) precipitate
    (2024-01-01)
    Mohammed, Abid A.
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    Wang, Shihao
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    Eskin, Dmitry G.
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    Patakham, Ussadawut
    This study explored the consequences of incorporating Sc and Zr into hypoeutectic Al–9Ce cast alloys, specifically investigating their influence on microstructure and mechanical properties. The findings demonstrated the significant reduction in the grain size of the Al–9Ce alloy while successfully maintaining the distinctive shape of the eutectic Al<inf>11</inf>Ce<inf>3</inf> phase through the incorporation of Sc and Zr additions. During aging treatments, Al<inf>3</inf>(Sc,Zr) coherent precipitates formed both at the interface between the α-Al and Al<inf>11</inf>Ce<inf>3</inf> phases and within the α-Al matrix. Remarkably, this led to optimal hardness achieved within a short duration of 3 h at 350 °C. Peak-aged quaternary Al–9Ce–xSc–yZr alloys showed significantly better tensile strength than the binary Al–Ce alloy at both ambient and elevated temperatures. Overall, the study underscored promising prospects of Al–Ce–Sc–Zr alloys for use in high-temperature applications, as they exhibited enhanced mechanical properties.
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    Optimizing Fabrication of Plasma-Driven CuO Shell Over Porous Al2O3 Substrate to Meet Coating Issues
    (2026-07-01)
    Kaentown, Sasithon
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    Wang, Wei Cheng
    ;
    Lin, Yi Cheng
    ;
    ;
    Diewwanit, Onnjira
    A plasma-driven in situ conversion strategy was developed in which Cu<inf>2</inf>O nanoparticles introduced into an alkaline phosphate–hydroxide electrolyte undergo oxidative transformation to CuO within plasma micro-discharge channels during plasma electrolytic oxidation (PEO) of AA6061 aluminum alloy. The positive duty cycle was systematically varied from 10% to 40% under constant mean current density to regulate dielectric breakdown behavior, discharge energy input, and interfacial oxidation conditions. Voltage transient analysis, X-ray diffraction, field emission scanning electron microscopy, and scratch adhesion testing were employed to correlate discharge characteristics with phase evolution and coating integrity. A progressive increase in the duty cycle was found to reduce the dielectric breakdown transition voltage, promote more spatially distributed microdischarges, and facilitate charge-transfer-driven oxidation of Cu<inf>2</inf>O to CuO within the active oxide growth zone. This plasma-assisted redox mechanism enables CuO to form co-spatially with Al<inf>2</inf>O<inf>3</inf> melting and rapid re-solidification, producing a CuO shell structure distributed over the porous alumina matrix rather than as a passively entrapped particulate phase. The resulting microstructural densification suppresses discharge-crater porosity, reduces surface roughness, and improves coating–substrate adhesion by nearly twofold relative to particle-free PEO coatings. These findings establish that duty-cycle-controlled discharge behavior provides a mechanistically grounded and dispersant-free route for fabricating CuO-modified oxide coatings with enhanced structural integration and interfacial adhesion on aluminum alloys.
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    Precipitation hardening and structure evolution in hypereutectic Al-6 % Fe-Zr alloys subjected to ultrasonic melt processing
    (2024-01-05) ;
    Wang, F.
    ;
    Pandee, P.
    ;
    Limmaneevichitr, C.
    ;
    Eskin, D. G.
    The objective of this research was to study the influence of Zr concentration and ultrasonic melt processing (USP) on the microstructure and precipitation hardening of a hypereutectic Al-6% Fe alloy. Such alloys have a good potential in high-temperature, wear-resistant, and conducting applications but suffer from coarse structure and low strength/ductility, which prevents their processing. The microstructure of the studied alloys consisted of primary Al<inf>13</inf>Fe<inf>4</inf> intermetallics and (Al)+Al<inf>13</inf>Fe<inf>4</inf> eutectic colonies, which were successfully refined by adding Zr and performing USP. The mechanisms of USP and Zr were confirmed for the Al-6 % Fe alloys with a range of Zr additions. The structure refinement led to improved hardness and tensile properties of the alloys. All studied alloys demonstrated strong precipitation hardening effect with hardness increasing 4–5 times, reaching 170 HV for the alloy with 0.4 % Zr after annealing at 400 ℃ for 20 hrs. The electrical conductivity increased from 25 % IACS in the as-cast alloy to 40% IACS in the annealed Al-6% Fe-0.4 % Zr alloy. The prime novelty of this work is a considerable increase of hardness upon annealing, i.e. more than 100 HV, in the Al-6 % Fe alloy with only minute traces of Zr (<0.01 %). The precipitation phenomena were investigated by transmission electron microscopy. The precipitation of the semi-coherent Al<inf>13</inf>Fe<inf>4</inf> phase with Zr segregated to its surface was observed for the first time. All studied alloys (with minute and larger Zr additions) showed the precipitation of this phase, while the alloys with the larger amount of Zr also demonstrated the precipitation of the metastable L1<inf>2</inf> Al<inf>3</inf>Zr phase. Therefore, the properties improvement was attributed to the structure refinement and the formation of Zr-modified Al<inf>13</inf>Fe<inf>4</inf> and Al<inf>3</inf>Zr precipitates in the microstructure.
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    Microstructure, Hardening, and Mechanical Properties of Hypoeutectic Al–Ce–Ni Alloys with Zr and Zr + Sc Additions and the Effect of Ultrasonic Melt Processing
    (2023-11-01) ;
    Wang, Feng
    ;
    Limmaneevichitr, Chaowalit
    ;
    Eskin, Dmitry G.
    Ternary Al–Ce–Ni alloys have a potential in the manufacture of automotive and airspace components, as well as in replacing traditional aluminum alloys in high-temperature applications, which is determined by the formation of fine and thermally stable Al<inf>11</inf>Ce<inf>3</inf> and Al<inf>3</inf>Ni eutectic. Herein, the microstructure and mechanical properties of a hypoeutectic Al<inf>4</inf>Ce<inf>2</inf>Ni alloy using Zr and Zr + Sc additions combined with ultrasonic melt processing and dispersion hardening are improved. As a result, the grain structure of the as-cast alloys is significantly refined and the annealing at 350 °C leads to a considerable hardening effect, especially in the alloys with Zr + Sc additions (doubling the hardness). Al<inf>3</inf>Zr and Al<inf>3</inf>(Zr,Sc) coherent particles are identified as hardening nanoprecipitates. The compressive mechanical testing at room and elevated temperatures shows that the additions of Zr and Zr + Sc improve the strength with the additional increase caused by ultrasonic melt processing.