Saechua, Wanphut

Preferred name

Saechua, Wanphut

Alternative Name

Saechua, W.

Main Affiliation

School of Engineering

wanphut.sa@kmitl.ac.th

Now showing 1 - 10 of 10

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Precision test for the spectral characteristic of FT-NIR for the measurement of water content of wheat straw
(2019-09-09)
Fonseca, F. G.
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Funke, A.
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Saechua, W.
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Sirisomboon, P.
Near Infrared (NIR) Spectroscopy is widely employed as a rapid technique for the evaluation of properties of biomass materials. Precision and accuracy of the instruments is an important aspect in order to minimize error in the determination of results. The objective of this publication is to determine scanning repeatability and reproducibility of the NIR spectrometer for wheat straw (Triticum aestivum L.), using either a fixed scan or a rotating scan. The former presented marginally better repeatability but worse reproducibility. Samples in equilibrium with the local atmosphere versus samples of controlled and different moisture contents were also compared, and the latter performed better on the precision test but both fixed and rotating scans. As the ultimate objective of this test is the use of this method to determine variations between different moisture content, and as the rotating scan presents better reproducibility, this method was selected as the reference method for further NIR analyses focused on the variation of moisture content.
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Total soluble solids, dry matter content prediction and maturity stage classification of durian fruit using long-wavelength NIR reflectance
(2023-12-01)
Saenphon, Chirawan
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Ditcharoen, Sirirak
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Malai, Chayuttapong
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Saengprachatanarug, Khwantri
;
Wongpichet, Seree
The DM and TSS of durian pulp moving on a conveyor belt were measured for their rapid and non-destructive qualities based on quantitative and qualitative measurements. The calibration set and prediction set equaled 209 and 69 pulps, respectively. The quantitative test compared the performance of PLS regression for DM and TSS prediction developed from full wavelength (860–1754 nm) and a few significant variables using SPA, GA, and VIP methods. The qualitative test identified the possibility of maturity stage classification by comparing three supervised machine learning classifiers, namely SVM, random forest (RF), and LDA. Effective models for DM and TSS prediction were developed from second derivatives spectra combined with the GA method, exhibiting r2, SEP, and RPD of 0.85, 4.50%, and 2.64, respectively for DM, and 0.66, 5.15%, and 1.60, respectively, for TSS. The model classifying samples into two distinct groups, namely “reject” and “pass,” utilizing the LDA algorithm, exhibited an impressive accuracy rate of 94.20%, making it a suitable choice for quality assurance purposes. This result indicates that the few effective variables were more efficient than full wavelength and improved model accuracy with greater model stability. Enhancing the classification model could involve data sample balancing in each group, leading to further improvements.
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Near infrared scanning precision analysis for intact durian fruits (cv. Chanee, Kanyao and Monthong)
(2019-09-09)
Chanachot, K.
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Saechua, W.
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Sirisomboon, P.
In order to develop a model of near infrared (NIR) spectroscopy, it is important to first perform the precision analysis of scanning of the NIR spectrometer. Therefore, it was the main aim of this paper by evaluating the scanning repeatability and reproducibility on intact durian fruit of 3 varieties including Chanee, Kanyao and Monthong using 3 spectrometers including FT-NIR spectrometer (MPA.), Long wavelength diode array spectrometer (MICRO NIR PRO) and Short wavelength diode array spectrometer (FQA NIR GUN). Results show that the lowest repeatability was of MPA for the scanning of Chanee and Kanyao. The lowest reproducibility was of the scanning by MICRO NIR PRO for all varieties. Therefore, from precision analysis of intact durian scanning, the MPA and MICRO NIR PRO could be recommended for the scanning to get the spectra for development the NIR predictive model for identify the geographic origin and variety of the durian.
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Integrating Vis-SWNIR spectrometer in a conveyor system for in-line measurement of dry matter content and soluble solids content of durian pulp
(2021-11-01)
Saechua, Wanphut
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Sharma, Sneha
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Nakawajana, Natrapee
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Leepaitoon, Kritsanaphon
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Chunsri, Rashphon
The prediction of dry matter content (DMC) and soluble solids content (SSC) in durian pulp were performed using a small laboratory scale in-line visible and short wave near infrared (Vis-SWNIR) spectroscopic system. The fiber optic diode array spectrometer with a charged coupled device (CCD) detector in a wavelength range of 450−1000 nm was used for spectral data acquisition. The spectra of the sample were acquired on the moving conveyor belt in two different orientations, including scanning in the upright position of pulps collected in 2018 and the stable position by scanning on the side of the pulps collected in 2019. Partial least squares regression (PLSR) was used to establish the relationship between the spectra and observed DMC and SSC values using the different wavelength ranges, including 450−1000, 700−1000, and 800−1000 nm for the comparison. The results showed that the durian pulp should be scanned in the upright position at the center of the pulp. Moving average smoothing preprocessing combined with the standard normal variate (SNV) for DMC and multiple scatter correction (MSC) for SSC gave the best result. The suitable wavelength range for model development to predict the DMC and SSC was 700−1000 nm and 800−1000 nm, respectively. After comparing the results, the optimum model showed the coefficient of determination of calibration (R<inf>C</inf>2), and prediction (R<inf>P</inf>2), root mean square error of prediction (RMSEP), bias, and the ratio of performance to interquartile distance (RPIQ) of 0.88, 0.83, 4.32 %, 1.25 %, and 3.52 for DMC and 0.70, 0.70, 4.0 %, 0.4 %, and 2.2 for SSC prediction.
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Rapid non-destructive evaluation of moisture content and higher heating value of Leucaena leucocephala pellets using near infrared spectroscopy
(2016-07-15)
Posom, Jetsada
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Shrestha, Amrit
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Saechua, Wanphut
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Sirisomboon, Panmanas
The MC (moisture content) and HHV (higher heating value) of Leucaena leucocephala pellets using NIR (near infrared) spectroscopy was investigated in this study. The MC of the pellets was adjusted by subjecting the samples to different relative humidity environments. The samples were scanned in diffuse reflection mode at wavenumbers of 12,500-4000 cm-1. Partial least squares regression models correlating the MC and HHV with the NIR spectra were developed and validated by full cross validation. The model for MC and HHV provided coefficients of determination (R2) of 0.995 and 0.964, a root mean square error of cross validation (RMSECV) of 0.187%wb and 79.2 J g-1, bias of -0.0008%wb and 1.29 J g-1 and a RPD (ratio of prediction to deviation) of 13.9 and 5.30, respectively. The models had excellent accuracy. This rapid quality evaluation method may be used for trading of biomass pellets. An equation related MC and HHV was also developed.
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A Geographical Origin Classification of Durian (cv. Monthong) Using Near-Infrared Diffuse Reflectance Spectroscopy
(2023-10-01)
Chanachot, Kingdow
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Saechua, Wanphut
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Posom, Jetsada
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Sirisomboon, Panmanas
The objective of this research was to classify the geographical origin of durians (cv. Monthong) based on geographical identification (GI) and regions (R) using near infrared (NIR). The samples were scanned with an FT-NIR spectrometer (12,500 to 4000 cm−1). The NIR absorbance differences among samples that were collected from different parts of the fruit, including intact peel with thorns (I-form), cut-thorn peel (C-form), stem (S-form), and the applied synthetic minority over-sampling technique (SMOTE), were also investigated. Models were developed across several classification algorithms by the classification learner app in MATLAB. The models were optimized using a featured wavenumber selected by a genetic algorithm (GA). An effective model based on GI was developed using SMOTE-I-spectra with a neural network; accuracy was provided as 95.60% and 95.00% in cross-validation and training sets. The test model was provided with a testing set value of %accuracy, and 94.70% by the testing set was obtained. Likewise, the model based on the regions was developed from SMOTE-ICS-form spectra, with the ensemble classifier showing the best result. The best result, 88.00FF% accuracy by cross validation, 86.50% by training set, and 64.90% by testing set, indicates the classification model of East (E-region), Northeast (NE-region), and South (S-region) regions could be applied for rough screening. In summary, NIR spectroscopy could be used as a rapid and nondestructive method for the accurate GI classification of durians.
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Evaluation of pyrolysis characteristics of milled bamboo using near-infrared spectroscopy
(2017-01-01)
Posom, Jetsada
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Saechua, Wanphut
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Sirisomboon, Panmanas
This paper reports the development of a rapid and low-cost method based on near-infrared spectroscopy as an alternative for thermogravimetric determination of the pyrolysis characteristics, including T<inf>onset</inf>, T<inf>sh</inf>, T<inf>peak</inf>, T<inf>offset</inf>and DTG<inf>peak</inf>, of milled bamboo. T<inf>onset</inf>is the extrapolated onset temperature that is calculated from the partial peak resulting from the decomposition of the hemicellulose component, T<inf>sh</inf>is the temperature corresponding to the overall maximum of the hemicellulose decomposition rate, DTG<inf>peak</inf>is the overall maximum of the cellulose decomposition rate, T<inf>peak</inf>is the temperature corresponding to the overall maximum of the cellulose decomposition rate and T<inf>offset</inf>is the extrapolated offset temperature of the DTG<inf>peak</inf>curves determined using thermogravimetric analysis (TGA). The models may be used to control the pyrolysis processes of bamboo to achieve the most economical and environmental conditions. 80 samples of bamboo with various circumferences of culms in the ranges of approximately 16–18, 18–20, 20–22, 22–24, 24–26, 26–28, 28–30, 30–32, 32–34, 34–36, 36–38 and 38–40 cm were randomly collected for optimization of the models. The models were optimized by partial least squares regression (PLSR) with 80% of samples for the calibration set and 20% for the validation set. For T<inf>onset</inf>, T<inf>sh</inf>, T<inf>peak</inf>, T<inf>offset</inf>and DTG<inf>peak</inf>the models showed coefficients of determination (R2) of 0.566, 0.845, 0.917, 0.973, and 0.671; root mean square errors of prediction (RMSEP) of 9.7 °C, 4.36 °C, 3.77 °C, 2.66 °C, and 0.428 wt loss %/min; ratios of prediction to deviation (RPD) of 1.52, 2.58, 3.48, 3.55, and 1.75; and biases of −0.344 °C, −0.765 °C, 0.349 °C, −5.41 °C, and 0.045 wt loss %/min, respectively. In addition, the results showed that pyrolysis characteristics did not depend on the circumference. The vibrational bands of water and CH<inf>3</inf>, O[sbnd]H stretch, first overtones of Ar–OH, CH<inf>2</inf>and HC[dbnd]CH in the cellulose and lignin structures, O[sbnd]H hydrogen bonds of polyvinyl alcohol and C[sbnd]H stretch corresponding to the first overtone of CH<inf>2</inf>had the highest influence on the values of T<inf>onset</inf>, T<inf>sh</inf>, T<inf>peak</inf>, and T<inf>offset</inf>, respectively. The vibrational band of the C[sbnd]O[sbnd]C asymmetrical stretches of cellulose and hemicellulose, and the combination of O[sbnd]H stretch and HOH bend of polysaccharides influenced the DTG<inf>peak</inf>value. These results are beneficial for studying the thermal behaviour of milled bamboo as a potential resource for producing biofuels, especially in the pyrolysis process.
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Precision test for spectral characteristic of NIR spectroscopy and bomb calorimeter for measuring higher heating value of Leucaena Leucocephala
(2018-08-14)
Posom, Jetsada
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Sirisomboon, Panmanas
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Saechua, Wanphut
The higher heating value (HHV) plays a significant role in determining of the energy potential of biomass. The method to receive this value using a bomb calorimeter takes a long time approximately of 15 minutes. The implementation of near infrared spectroscopy (NIR) technique by generating a prediction model can be replaced the former method in order to reduce time into 2 minutes. Therefore, the precision of both techniques have to be concerned in order to get the reliable values. The repeatability and reproducibility processes were carried out to evaluate the precision of both methods. It was found that the percentage difference of standard deviation (SD) from the mean of repeatability for the NIR was less than 5 % and for reproducibility was slightly over 5 % (but not over than 10%). The SD of repeatability and reproducibility of the bomb calorimeter were 54.6 J/g (0.3 % difference of average HHV value) and 81.3 J/g (0.5 % difference of average HHV value) respectively. The average HHV from the bomb calorimeter was 18,166.77±236.29 J/g. Both techniques showed very low percentage difference of the SD from the mean that revealed very high reliability and precision of measurements.
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GEOGRAPHICAL IDENTIFICATION OF DURIAN (CV. MONTHONG) FROM PRACHUAP KIRI KHAN AND CHANTHABURI PROVINCE BY USING NEAR INFRARED SPECTROSCOPY
(2021-01-01)
Chanachot, Kingdow
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Saechua, Wanphut
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Sirisomboon, Panmanas
Geographic origin of durian (Durio zibethinus Murray) can influence consumers purchasing decisions. A guaranteed geographical origin is extremely useful to maintain the credibility and popularity of this fruit. The objective of this work is to confirm geographical identification (GI) of durian Monthong from Prachuap Kiri Khan Province from south of Thailand which achieved the GI lable from the department of intellectual property by near infrared spectroscopy (NIRs). Total of 60 durian Monthong samples were acquired in the wavenumber range of 12,500-4,000 cm-1by FT-NIR spectrometer. The sample presentation for scanning were 3 forms including intact peel (with thorns), cut-thorns peel and stem of the fruit. Soft independent modeling of class analogy (SIMCA), partial least squares discriminant analysis (PLS-DA) and support vector machine classification (SVMC) were used to establish identification model using the full spectra. Overall classification accuracy of SVMC was the highest in training and validation set of stems which was 100% and 100%, respectively. This study indicated that NIRs might be a method to guaranteed geographic origin of durian Monthong from Prachuap Kiri Khan. However, more robust model should be developed by using more samples.
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Comparing Machine Learning and PLSDA Algorithms for Durian Pulp Classification Using Inline NIR Spectra
(2023-06-01)
Pokhrel, Dharma Raj
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Sirisomboon, Panmanas
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Khurnpoon, Lampan
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Posom, Jetsada
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Saechua, Wanphut
The aim of this study was to evaluate and compare the performance of multivariate classification algorithms, specifically Partial Least Squares Discriminant Analysis (PLS-DA) and machine learning algorithms, in the classification of Monthong durian pulp based on its dry matter content (DMC) and soluble solid content (SSC), using the inline acquisition of near-infrared (NIR) spectra. A total of 415 durian pulp samples were collected and analyzed. Raw spectra were preprocessed using five different combinations of spectral preprocessing techniques: Moving Average with Standard Normal Variate (MA+SNV), Savitzky–Golay Smoothing with Standard Normal Variate (SG+SNV), Mean Normalization (SG+MN), Baseline Correction (SG+BC), and Multiplicative Scatter Correction (SG+MSC). The results revealed that the SG+SNV preprocessing technique produced the best performance with both the PLS-DA and machine learning algorithms. The optimized wide neural network algorithm of machine learning achieved the highest overall classification accuracy of 85.3%, outperforming the PLS-DA model, with overall classification accuracy of 81.4%. Additionally, evaluation metrics such as recall, precision, specificity, F1-score, AUC ROC, and kappa were calculated and compared between the two models. The findings of this study demonstrate the potential of machine learning algorithms to provide similar or better performance compared to PLS-DA in classifying Monthong durian pulp based on DMC and SSC using NIR spectroscopy, and they can be applied in the quality control and management of durian pulp production and storage.

Saechua, Wanphut

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