Phawachalotorn, Chanadda

Preferred name

Alternative Name

Phawachalotorn, C.

Main Affiliation

KMITL Prince of Chumphon Campus

chanadda.ph@kmitl.ac.th

Now showing 1 - 4 of 4

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Mechanistic insights into efficient methylene blue adsorption by single-rod mangosteen peel waste composite starch cryogel: Batch and column studies
(2026-02-01)
Phatthanawiwat, Kharittha
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Phawachalotorn, Chanadda
;
Wongniramaikul, Worawit
;
Choodum, Aree
A green composite tablet, based on the immobilization of mangosteen peel (MP) waste particles in starch cryogel (Cry-DMP), was successfully prepared and characterized. Cry-DMP exhibited a high adsorption capacity for methylene blue (MB), with a maximum capacity (qₘₐₓ) of 26.53 mg g⁻¹ , and the equilibrium data were best described by the Langmuir model ( R² = 0.9902). High removal efficiencies of 97.21 % in synthetic water and 70.8 % in real Batik industrial wastewater were achieved without chemical activation of the mangosteen peel particles, demonstrating the practical applicability of the adsorbent. The suggested adsorption mechanism mainly relies on electrostatic interaction with additional contributions from hydrogen bonding and π–π interactions. The pseudo-second-order model best described the adsorption kinetics ( R² = 1), and the adsorption of MB onto Cry-DMP was determined to be spontaneous and endothermic. Furthermore, the Yoon–Nelson model accurately described the experimental results from continuous flow experiments ( R 2 = 0.8598–0.9981). Sodium silicate reduces removal efficiency by 8.82 %, while sodium phosphate increases it by 2.94 %. Cry-DMP effectively removes MB and other cationic dyes but is ineffective against anionic dyes, highlighting its selective adsorption capabilities. These findings emphasize the effectiveness of Cry-DMP as a green adsorbent for MB and highlight the feasibility of waste utilization with a greener approach.
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Magnetic calcium silicate hydrate–oyster shell waste nanocomposite for phosphate removal and recovery: RSM-based optimization, mechanism, and real water application
(2025-09-01)
Boonkanon, Chanita
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Wongniramaikul, Worawit
;
Phawachalotorn, Chanadda
;
Limwongsakorn, Somsak
;
Choodum, Aree
Magnetic nanocomposites offer an effective strategy for phosphate removal from wastewater, preventing eutrophication and enabling phosphate recovery for reuse as fertilizer—supporting a zero-waste approach. In this study, a novel hybrid nanocomposite composed of magnetized calcined oyster shell waste and calcium silicate hydrate (M-COS-CSH) was synthesized through a simple process completed within 5.2 h. Response Surface Methodology was employed for optimization: a Central Composite Design determined the optimal FeCl₃ and COS ratios, while a Box–Behnken Design optimized adsorption conditions including adsorbent dose (20–100 mg), initial phosphate concentration (10–90 mg L−1), contact time (15–75 min), and pH (3−11). Under optimal conditions (60 mg adsorbent, 10 mg L−1 phosphate, 45 min, pH 6.28), M-COS-CSH achieved a predicted maximum removal efficiency of 97.30 %. An experimental removal efficiency of 98.06 % ± 0.19 % was obtained under the same conditions without pH adjustment (pH 6.84), offering a cost advantage. The adsorption process closely followed the Langmuir isotherm model (R2 = 0.9963), with a maximum adsorption capacity of 161.29 mg g−1, and was best described by the pseudo-second-order kinetic model (R2 = 1.0000). Characterization suggested a mechanism involving surface microprecipitation and inner-sphere complexation. Thermodynamic analysis confirmed the process to be endothermic and spontaneous (ΔG°: −9.97 to −10.84 kJ mol−1; ΔH°: 3.00 kJ mol−1; ΔS°: 43.52 J mol−1 K−1). M-COS-CSH achieved phosphate removal ranging from 70.81 % ± 2.47 % to 94.24 % ± 0.39 % in real water samples. Even in the presence of competing anions at fivefold phosphate concentration, removal efficiency remained high (93.58 % ± 0.32 %), confirming the material's strong selectivity and suitability in complex matrices.
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Calcium silicate hydrate–embedded porous concrete for efficient phosphate removal and recovery in concentrated eluates
(2026-01-01)
Wongniramaikul, Worawit
;
Choodum, Aree
;
Pasitsuparoad, Pakorn
;
Cotchim, Suparat
;
Phawachalotorn, Chanadda
Phosphate remediation and recovery from wastewater remain challenging due to limitations in adsorbent stability and real–world applicability. This study presents a sustainable porous concrete–calcium silicate hydrate (PC–CSH) column engineered for continuous–flow phosphate removal and resource recovery. Synthesized CSH nanoparticles were incorporated into a porous cement matrix, and comprehensive characterization confirmed the formation of calcium phosphate phases, including hydroxyapatite (HAP), CaHPO₄, and Ca(H₂PO₄)₂. The results indicate that surface-induced microprecipitation, driven by Ca²⁺ and OH⁻ released from both added and in situ–formed CSH, is the dominant removal mechanism. Externally added nanoparticles contributed 40.05% of total uptake, while the remainder originated from CSH generated during cement hydration. Breakthrough analysis showed that increasing column height enhanced longevity, whereas higher influent phosphate concentration and flow rate accelerated saturation. Under optimal conditions (7.5 cm column, 50 mg L⁻¹ phosphate, 10 mL min⁻¹ flow), the system achieved >99% removal with a total adsorption capacity of 3599.7 mg. The nonlinear Yoon–Nelson model best described the breakthrough behavior. Application to real municipal wastewater (initial phosphate 4.57 mg L⁻¹) achieved 99.3% removal with minimal influence from coexisting anions (SO₄²⁻, NO₃⁻, CO₃²⁻). Phosphate was efficiently recovered using 0.5 M HCl (100.4% desorption), and performance was restored by reloading fresh PC–CSH slurry. The column retained 73.9% phosphate removal efficiency after four adsorption–desorption cycles with real wastewater, demonstrating excellent reusability and practical potential. Overall, the PC–CSH column offers a robust, semi–regenerable platform for sustainable phosphate mitigation and recovery in wastewater treatment.
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Continuous-flow phosphate removal using Cry-Ca-COS Monolith: Insights from dynamic adsorption modeling
(2025-05-01)
Phawachalotorn, Chanadda
;
Wongniramaikul, Worawit
;
Kaewnoo, Satabodee
;
Choodum, Aree
This study rigorously evaluates the adsorption performance of the Cry-Ca-COS monolith for phosphate removal in a column operation mode. Characterization of the material both before and after exhaustion in a continuous flow system (column form) showed no difference compared to results from a batch system (tablet form). The XPS results indicated that the adsorption mechanism of phosphate on the Cry-Ca-COS column involved surface microprecipitation and ligand exchange (inner-sphere complexation). A systematic examination of key parameters revealed that higher column height, lower flow rate, and higher initial phosphate concentration favor increased phosphate adsorption in continuous mode. The application of the developed system to a real wastewater sample resulted in a satisfactory removal efficiency of 99.16 %, along with a concurrent reduction in total suspended solids (TSS) by 63.07 %. The adsorption data were analyzed using five dynamic adsorption models—Adam-Bohart, Wolborska, Thomas, Yoon-Nelson, and Yan—employing both linear and non-linear approaches. The non-linear models demonstrated a better fit with the experimental data, as indicated by higher correlation coefficients (R² = 0.9994 in the Yoon-Nelson model). An analysis of comprehensive errors was also conducted to assess the adequacy and precision of the model equations.

Phawachalotorn, Chanadda

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