Thongkam, Montree
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Item type:Publication, Adsorption kinetic of direct dyes from aqueous solution on zeolite lta(2021-01-01); ;Trisupakitti, Somsuk ;Palama, Thongsuk ;Senajuk, WatcharaNausri, ChompooThe analysis of adsorption relies on the equilibrium state of the mass. It is the relationship between the concentration of the adsorbate in the liquid phase and the concentration of the adsorbate in the solid phase. The relationship is written as an isotherm of the adsorption graph. Zeolite LTA was used as adsorbent to remove dye from solution in a batch adsorption system. The adsorption isotherm showed that the Langmuir model was better than the Freundlich model. Adsorption of adsorbate consists of a diffusion process through the fluid layer around the adsorbent material and the diffusion in the cavity. This research found that a pseudo-second order model was a better fit to measured adsorption data. - Some of the metrics are blocked by yourconsent settings
Item type:Publication, Effects of Zinc and Aluminum on the CuO Crystalline Size for Direct Dimethyl Ether Synthesis from Syngas(2021-09-01); ;Piyabunditgul, Nanchapak ;Trisupakitti, SomsukThe effects of zinc and aluminum on the CuO crystalline size for direct dimethyl ether (DME) synthesis from syngas were investigated. Metal oxide catalysts were synthesized with various molar ratios of CuO by the precipitation method, and by the co-precipitation method with CuO/ZnO (CZ), CuO/ZnO/Al<inf>2</inf>O<inf>3</inf> (CZA), and CZA at ratios of 1:1, 2:2:1, and 6:3:1, respectively. The acid catalysts (γ-Al<inf>2</inf>O<inf>3</inf>, HZSM-5) were added to the metal oxide catalysts by physical mixing. The catalysts were characterized morphologically and their acidities were determined. Loading of zinc and aluminum at different ratios showed that CZA (2:2:1) gave the smallest CuO crystalline size, appropriate for the methanol synthesis reaction. γ-Al<inf>2</inf>O<inf>3</inf> has a weak to moderate acidity range, suitable for DME synthesis. Moreover, the bifunctional catalyst, CZA (2:2:1)/γ-Al<inf>2</inf>O<inf>3</inf>, had the highest surface area as well as the highest %CO conversion and %DME selectivity.
