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    A double-shell capsule catalyst with core-shell-like structure for one-step exactly controlled synthesis of dimethyl ether from CO2 containing syngas
    (2011-08-10)
    Yang, Guohui
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    Vitidsant, Tharapong
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    Yoneyama, Yoshiharu
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    Tan, Yisheng
    A zeolite capsule catalyst Cr/ZnO-S-Z was prepared successfully by a novel dual-layer method, in which one layer of neutral Silicalite-1 zeolite shell was first synthesized on the bimetallic Cr/ZnO core catalyst, acting as the intermediate layer for the following H-type H-ZSM-5 zeolite shell direct synthesis on its surface. By using this dual-layer method, it can be easily realized that the formation of H-ZSM-5 zeolite membrane on the millimeter-sized bimetallic substrates. Direct synthesis of dimethyl ether (DME) from syngas at higher reaction temperature was the application of this zeolite capsule catalyst to test its catalytic performance. In reaction, this zeolite capsule catalyst could realize the exactly controlled synthesis of DME, suppressing the formation of other alkane/alkene by-products simultaneously, demonstrating its exclusive ability for the selective synthesis of target product compared with the conventional hybrid catalyst. © 2011 Elsevier B.V. All rights reserved.
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    Optical properties of Cu0.95Pt0.05Fe0.97Sn0.03O2 for p-type transparent conducting oxide materials
    (2013-08-30) ;
    Kahatta, Sagulthai
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    ; ;
    The Cu<inf>0.95</inf>Pt<inf>0.05</inf>Fe<inf>0.97</inf>Sn<inf>0.03</inf>O<inf>2</inf> sample has been synthesized by a solid-state reaction to investigate optical properties of materials of transparent conducting oxide. Crystal structure was characterized by XRD. The Seebeck coefficient and electrical conductivity were measured in the high temperature (300 to 860 K), while the XPS and UV-VIS-NIR spectra were analyzed at room temperature. The XRD peaks confirm the samples forming the delafossite structure phase. The Seebeck coefficient reveals the samples displays the p-type conducting. The XPS spectra show the Sn2+ state stabling in this compound. The optical direct gap is 3.45 eV as a visible-transparent material. These results support that the Cu<inf>0.95</inf>Pt<inf>0.05</inf>Fe<inf>0.97</inf>Sn<inf>0.03</inf>O<inf>2</inf> oxide compounds, of which the Cu<sup>1+</sup> and Fe<sup>3+</sup> sites are substituted by the Pt<sup>1+</sup> and Sn<sup>2+</sup> ions respectively, are p-type transparent conducting oxide materials. © (2013) Trans Tech Publications, Switzerland.
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    Electrical and optical properties of p-type CuFe1-xSn xO2 (x = 0.03, 0.05) delafossite-oxide
    (2013-01-14) ; ; ;
    Kongtaweelert, Samart
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    Thanachayanont, Chanchana
    The CuFe<inf>1-x</inf>Sn<inf>x</inf>O<inf>2</inf> (x = 0.03, 0.05) delafossite samples have been synthesized by a solid-state reaction to investigate electrical and optical properties of the transparent conducting oxide materials. Crystal structure was characterized by XRD. The electrical conductivity and Seebeck coefficient were measured in the high temperature range of 300 to 960 K, while the Hall coefficient, XPS, and UV-VIS-NIR spectra were analyzed at room temperature. The XRD peaks of the samples indicate the delafossite structure phase, and the XPS spectra reveal the stable Sn <sup>2+</sup>-doping state. The Seebeck and Hall coefficient display a positive sign indicating the p-type conducting oxide. The optical allowed direct gap is 3.45 eV as a visible-transparent material. The activation energies for polaron hopping between Sn<sup>2+</sup> sites and Fe<sup>3+</sup> sites of 36 and 32 meV are obtained from the samples having x = 0.03 and 0.05, respectively. The CuFe<inf>1-x</inf>Sn<inf>x</inf>O<inf>2</inf> delafossite oxide compounds, of which the Fe<sup>3+</sup> sites in the CuFeO<inf>2</inf> are substituted by the Sn<sup>2+</sup> ions, are p-type transparent conducting oxide materials. The activation energy is found to decrease with an increased in Sn content. © 2013 American Institute of Physics.
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    A simple route to synthesize ferromagnetic binary calcium iron pyrophosphate CaFeP2O2 using aqueous-acetone media
    (2013-08-30)
    Chaiyasith, Pachernchaipat
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    ; ;
    Kongteweelert, Samart
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    Woramongkonchai, Somsak
    A binary calcium iron pyrophosphate CaFeP<inf>2</inf>O<inf>7</inf> was synthesized by solid state route using the mixing of calcium carbonate, iron metal and phosphoric acid in aqueous-acetone media at 600°C. The XRD datum indicates the formation of CaFeP<inf>2</inf>O<inf>7</inf> phase without the presence of any phase impurities. FTIR result indicates the presence of the P<inf>2</inf>O<inf>7</inf> <sup>4-</sup> anion in the structure. Sheet-like microparticle of CaFeP<inf>2</inf>O<inf>7</inf> was revealed by SEM. Room temperature magnetization result showed ferromagnetic behavior of the synthesized CaFeP<inf>2</inf>O<inf>7</inf>, with saturation-specific magnetization value of 11.067 emu g<sup>-1</sup> at 10kOe. The magnetic feature of the synthesized CaFeP<inf>2</inf>O<inf>7</inf> in this work compared with M<inf>2</inf>P<inf>2</inf>O<inf>7</inf> (M = Ca and Fe), its isotypic (CaMP2O7 (M= Mn and Co) and CFeP<inf>2</inf>O<inf>7</inf> (C= Co and Cu) reported in our previous works is important properties for specific applications. © (2013) Trans Tech Publications, Switzerland.
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    Facile, alternative synthesis of spherical-like ca(H2PO4)2•H2O nanoparticle by aqueous-methanol media
    (2013-08-30)
    Kongteweelert, Samart
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    ; ;
    Chaiyasith, Pachernchaipat
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    Woramongkonchai, Somsak
    Spherical-like calcium dihydrogenphosphate monohydrate (Ca(H<inf>2</inf>PO<inf>4</inf>)<inf>2</inf>•H<inf>2</inf>O) nanostructure was successfully prepared by the mixing of calcium carbonate and phosphoric in aqueous-methanol media at ambient temperature for 30 min. Three thermal decomposition step and higher stability at over 800°C of the prepared sample are different from the earlier works. Spherical-like Ca(H<inf>2</inf>PO<inf>4</inf>)<inf>2</inf>•H<inf>2</inf>O nanostructure with diameter < 100 nm confirmed by SEM may be important for potential applications. This method of synthesis by aqueous-methanol media is a fast and simple method and it is expected to be applicable for the synthesis of other nanocrystalline calcium phosphates. © (2013) Trans Tech Publications, Switzerland.
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    A new synthesis of BaHPO4 precipitated by BaCO3-H4PO4-NaOH system at room temperature
    (2013-08-30) ; ; ;
    Chaiyasith, Pachernchaipat
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    Woramongkonchai, Somsak
    Barium hydrogenphosphate, BaHPO<inf>4</inf> was synthesized for the first time through simple and rapid method using BaCO<inf>3</inf>-H<inf>3</inf>PO<inf>4</inf>-NaOH, pH =9.0 at room temperature for 30 min. The studied BaHPO<inf>4</inf> decomposed in a single well-defined stage via deprotonated hydrogenphosphate reactions, revealed by TG/DTG and DSC techniques. The calculated wavenumbers based on DSC peak were comparable with FTIR results, which support the breaking bonds of P-OH (HPO<inf>4</inf><sup>2-</sup>) in the deprotonated hydrogenphosphate reactions. The thermodynamic functions (ΔH*, ΔG*, and ΔS*) for the deprotonated hydrogenphosphate reactions calculated from DSC data indicate that the deprotonated HPO<inf>4</inf><sup>2-</sup> reaction occur a lower-energy pathway and spontaneous process. The FTIR, XRD and SEM data of the studied BaHPO<inf>4</inf> and its decomposed product Ba<inf>4</inf>P<inf>2</inf>O<inf>7</inf> are also reported. © (2013) Trans Tech Publications, Switzerland.
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    Non-isothermal decomposition kinetics of synthetic serrabrancaite (MnPO4 · H2O) precursor in N2 atmosphere
    (2010-01-01) ;
    Danvirutai, Chanaiporn
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    The thermal decomposition of synthetic serrabrancaite (MnPO<inf>4</inf> · H<inf>2</inf>O) was studied in N<inf>2</inf> atmosphere using TG-DTG-DTA. Thermal analysis results indicate that the decomposition occurs in two stages, which are assigned to the dehydration and the reduction processes and the final product is Mn<inf>2</inf>P<inf>2</inf>O<inf>7</inf>. X-ray powder diffraction, FT-IR and FT-Raman techniques were used for identification of the solid decomposition product. The decomposition kinetics analysis of MnPO <inf>4</inf> · H<inf>2</inf>O was performed under non-isothermal condition through isoconversional methods of Flynn-Wall-Ozawa (FWO) and Kissinger-Akahira-Sunose (KAS). The dependences of activation energies on the extent of conversions are observed in the dehydration and the reduction reactions, which could be concluded the "multi-step" processes. © Akadémiai Kiadó, Budapest, Hungary 2009.
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    Kinetics and thermodynamics of the formation of MnFeP4O 12
    The kinetics and thermodynamics of dehydration and intermolecular polycondensation reactions of Mn<inf>1/2</inf>Fe<inf>1/2</inf>(H <inf>2</inf>PO<inf>4</inf>)<inf>2</inf> ·H<inf>2</inf>O and Mn <inf>1/2</inf>Fe<inf>1/2</inf>(H<inf>2</inf>PO<inf>4</inf>)<inf>2</inf> were studied under nonisothermal heating by thermogravimetry (TG). On the basis of three calculation procedures and 24 kinetic mechanism functions, kinetic triplets (E, A, kinetic model) using the Arrhenius equation were calculated for both processes. The comparison of the results obtained with these calculation procedures show a strong dependence on the selection of the mechanism function for the process. The thermodynamic functions (ΔH*, C<inf>p</inf>, ΔG*, and ΔS*) of both reactions are calculated from differential scanning calorimetry (DSC) experiments. Kinetic and thermodynamic results indicate that the polycondensation step has a lower rate and is a stronger reaction than the dehydration step and corresponds to the breaking of the strong hydrogenbonded P-OH group, in connection with the polycondensation reaction, which confirms that the decomposition product (manganese iron cyclotetraphosphate, MnFeP<inf>4</inf>O<inf>12</inf>) was obtained. © 2010 American Chemical Society.