Now showing 1 - 8 of 8
  • Some of the metrics are blocked by your 
    Item type:Publication,
    Ultrasonic-assisted Extraction of Dietary Fiber from Defective Lemon Basil (Ocimum basilicum var. citriodorum) Seed
    (2025-01-01)
    Nilmat, Kamonthip
    ;
    Noitang, Sajee
    ;
    Supang, Wirasinee
    ;
    ;
    Lemon basil (Ocimum basilicum var. citriodorum) is an herbaceous plant cultivated for seed consumption only in Sukhothai Province, Thailand. Unlike cultivating for fresh leave consumption, the production of lemon basil seed requires maturity and reproduction phases, the same as rice and wheat. After harvesting, the farmer separates unmatured red basil seeds (RBS) because of their diverse color. The RBS contains valuable compounds, such as dietary fiber, that could be extracted by an ultrasonic-assisted extraction (UAE). This work aims to extract DF with the highest brightness using L*a*b* color in liquid form as an indicator. The optimal condition was identified by the crossing point between the brightness (L*) and extraction yield. The proximate nutrient analysis showed that RBS has a higher fiber content than high-quality basil seed (HBS). For water swelling ability, HBS performed 4-fold higher than RBS. The complete extraction of dietary fiber was observed at 10 min for UAE at 200 W, a water-to-seed ratio of 30:1, and 100% amplitude, and it was preferably conducted at room temperature (30±2°C) without an external cooling system. The correlation between UAE extraction time and temperature at constant total power and amplitude was also explored. When the extraction temperature exceeded 80°C, the extracted mucilage was rotten within 24 h, even if stored at 4°C. Moreover, the extracted RBS contained Omega-3 oil that a screw-press machine or supercritical CO2 could extract in further study.
  • Some of the metrics are blocked by your 
    Item type:Publication,
    Optimization of yield and thymoquinone content of screw press-extracted black cumin seed oil using response surface methodology
    (2023-01-01) ;
    Sila-ngam, Piraya
    ;
    Chummengyen, Supitcha
    ;
    Sukruay, Atitaya
    ;
    Ngamprasertsith, Somkiat
    Because there have been no previous reports on the use of screw presses for black cumin (Nigella sativa L.) seed oil extraction, the present study examined the effects of feed rate, temperature, and moisture content on the yield and thymoquinone content of mechanically extracted cold-pressed black cumin seed oil. The extraction parameters were optimized using a Box–Behnken design. Optimal conditions were identified by superimposing the response surfaces of oil yield and thymoquinone content. The thymoquinone content was stable under extraction conditions of 60 °C. Moisture played an important role in both oil yield and thymoquinone content. A maximum oil yield of 31.67 wt% ± 0.85 wt% was obtained at a feed rate of 45 g/min, temperature of 70 °C, and moisture content of 6 wt%. However, a low thymoquinone content of 5.14 ± 0.74 mg/mL was observed under these conditions. Furthermore, high thymoquinone content (∼12.00 mg/mL) reduced the oil yield to 10–13 wt%. The optimal conditions were found to be a feed rate of 50–54 g/min, moisture content of 15–18 wt%, and temperature of 55–60 °C, which gave a yield of 22 wt% oil and 10 mg/mL thymoquinone content.
  • Some of the metrics are blocked by your 
    Item type:Publication,
    Biodiesel Production from Rambutan Seed Waste by Supercritical Ethanol: Economic Analysis
    (2025-01-01)
    Supang, Wirasinee
    ;
    Nilmat, Kamonthip
    ;
    ;
    Utthachat, Kassama
    ;
    Ngamprasertsith, Somkiat
    The production capacity of rambutan (Nephelium lappaceum Linn.) in Thailand is approximately 0.3–0.4 million tons per year, and an average of 1,900 tons of rambutan seed is left as seed waste. This work pre-extracted rambutan seed oil using a single screw press machine to serve as feedstock for biodiesel production. However, the rambutan seed had a high lipid content of ~40%; the screw press machine was capable of extracting only 6–10% of the rambutan seed oil; in other words, ~24% of the residual oil remains in the seed cake. An ethanolic extraction was performed to recover the remaining lipids in the pressed seed cake. This work also aimed to use ethanol as a reactant for biodiesel production in supercritical conditions without removing the extracting ethanol. Ethanolic extraction and supercritical ethanol transesterification were collectively called the EE-SET process. The fatty acid ethyl esters (FAEE) content in the resultant biodiesel ranged from 40–60% because rambutan seed oil contained ~50% oleic (C18:1) and ~40% arachidic (C20:0) acids, which have higher molecular weights than common plant oil. Next, the experimental conditions were simulated in Aspen Plus V.12 software to estimate the mass and energy balances in the biodiesel production process. The results from computer simulations were applied to an economic analysis to assess the feasibility of the EE-SET process. Because the unique fatty acid profile of rambutan seed oil generated a lower FAEE content and consumed a large amount of energy for distillation, the process's complexity reduced the EE-SET process's profitability.
  • Some of the metrics are blocked by your 
    Item type:Publication,
    Biodiesel Production from Spent Coffee Grounds by Using Ethanolic Extraction and Supercritical Transesterification
    (2024-12-01)
    Supang, Wirasinee
    ;
    Ngamprasertsith, Somkiat
    ;
    ;
    Sawangkeaw, Ruengwit
    This work presents a way to use ethanol and spent coffee grounds (SCG) as feedstocks for biodiesel production to solve ethanol overproduction in Thailand and biodiesel feedstock shortage problems together. Waste coffee oil (SCGO) was ethanolic extracted from SCG; then, ethanol-SCGO mixture was transesterified in supercritical condition without ethanol removal. The ethanolic extraction curves of SCG at a temperature range of 50–70 °C were constructed. Transesterification experiments were studied in a batch reactor and a continuous reactor at various temperatures (275–350 °C) and reaction time (5–40 min) under 15.0 MPa. The molar ratio of ethanol-oil mixture was set at 30:1. The highest ester content of 88.37 ± 3.00 wt% was found in biodiesel obtained at a temperature of 275 °C and a reaction time of 40 min in a batch reactor. Furthermore, excess temperature (< 300 °C) and reaction time (< 20 min) induced thermal degradation and promoted the loss of ethyl linoleate. For continuous reactor, the maximum ester content of 83.38 ± 5.86 wt% was observed at 325 °C and 29.4 min of residence time. Unlike in batch reactors, thermal degradation of ethyl linoleate was not observed in a continuous reactor. The results showed that ethanolic extraction and supercritical transesterification are alternative ways to produce biodiesel from SCG without removing extractant and using catalyst. From a prospective point of view, techno-economic analysis (TEA) and life-cycle assessment (LCA) of invented process should be conducted to ensure profitability and environmental benefits, respectively. Graphical Abstract: (Figure presented.)
  • Some of the metrics are blocked by your 
    Item type:Publication,
    Biodiesel production from spent coffee grounds via ethanolic extraction and supercritical ethanol transesterification: technoeconomic analysis and life cycle assessment
    (2026-01-01)
    Supang, Wirasinee
    ;
    Ngamprasertsith, Somkiat
    ;
    Nimmanterdwong, Prathana
    ;
    ;
    Hunsub, Panusorn
    Previous studies have developed biodiesel production methods from spent coffee grounds (SCGs) via ethanolic extraction and supercritical ethanol transesterification (EE-SET) to minimize the energy consumption associated with solvent evaporation. In this study, we perform a technoeconomic analysis (TEA) and a life cycle assessment (LCA) to evaluate the profitability and sustainability of EE-SET. The material and energy balances in the TEA and LCA were derived from Aspen Plus<sup>®</sup> V12 based on experimental data from previous research. The results from the base case indicated that EE-SET was unprofitable and posed a considerable environmental burden by disposing of defatted SCG (DSCG) as solid waste due to two main issues. First, the amount of DSCG was 4.8 times greater than the total biodiesel and glycerol produced. Second, landfilling DSCG incurred waste treatment costs and induced greenhouse gas (GHG) emissions simultaneously. Selling DSCG as a feedstock for solid fuel pellets offers an effective strategy for achieving profitability and sustainability. As such, EE-SET addresses the economic drawback of generating profit from selling DSCG while reducing waste treatment costs. Using DSCG as a solid fuel for environmental benefits increases ash disposal credit and substantially reduces GHG emissions. The incorporation of pelletizing units or biomass power plants into EE-SET represents a promising avenue for future research.
  • Some of the metrics are blocked by your 
    Item type:Publication,
    Effects of temperature and pressure on volatile compounds of black cumin seeds (Nigella sativa L.) oil extracted by supercritical carbon dioxide
    (2025-01-01) ;
    Sakulkittiyut, Buntita
    ;
    Ngamprasertsith, Somkiat
    ;
    Supang, Wirasinee
    ;
    Sawangkeaw, Ruengwit
    This study investigated the effects of temperature and pressure on the yield and volatile compound contents of black cumin seed oil (BCO) extracted from black cumin seeds using supercritical carbon dioxide (SCCO<inf>2</inf>). The solubility of BCO in SCCO<inf>2</inf> increased 2.5-fold as the pressure increased by 10 MPa. Major volatile compounds in BCO were identified using a static headspace gas chromatography–mass spectrometry (SH–GC–MS). Evidence indicated the main volatile components in SCCO<inf>2</inf>-extracted BCO to be hexanal, p-cymene, and thymoquinone. BCO extracted from China-cultivated black cumin seed contained similar amounts of p-cymene and thymoquinone. This black cumin seed is classified as the cymene/thymoquinone chemotype and is also found in Indian, Iranian, and Algerian black cumin seeds. Thymoquinone contents in BCO were more sensitive to the extraction temperature than hexanal and p-cymene contents. The maximum oil yield of 36.28 ± 1.38 wt%, with approximately 2.0 mg of thymoquinone per milliliter of oil, was obtained at extraction temperatures of 50°C and pressures of 30 MPa. A SH–GC–MS could detect small molecules in black cumin seed oil such as hexanal. The results of this work reveal that temperature has more impact on the selectivity of volatile compounds than pressure in supercritical carbon dioxide extraction.
  • Some of the metrics are blocked by your 
    Item type:Publication,
    Ethyl acetate as extracting solvent and reactant for producing biodiesel from spent coffee grounds: A catalyst- and glycerol-free process
    (2022-07-01)
    Supang, Wirasinee
    ;
    Ngamprasertsith, Somkiat
    ;
    ;
    Sawangkeaw, Ruengwit
    Oil was extracted from spent coffee grounds (SCGs) using ethyl acetate at atmospheric pressure; then, the ethyl acetate–SCG oil mixture was reacted under supercritical conditions, which involve a catalyst-free process. Moreover, ethyl acetate reacted with glycerol to form triacetin, which dissolves in biodiesel and acts as a fuel additive. Using this approach, the solvent removal step and glycerol byproducts are eliminated. The highest fatty acid ethyl ester contents of 91.80 wt% ± 1.62 wt% and 86.44 wt% ± 2.12 wt%. were obtained under optimal conditions in batch and continuous reactors, respectively. Based on gas chromatography–mass spectrometric analysis, no trace of glycerol was detected and triacetin was yielded at 4.22 wt%. This novel process simultaneously minimizes the number of chemicals used and the amount of waste generated because it employs only dried SCGs and ethyl acetate as the feedstock.
  • Some of the metrics are blocked by your 
    Item type:Publication,
    Technoeconomic analysis of biofuel production from spent coffee grounds using supercritical ethyl acetate
    (2026-03-01)
    Supang, Wirasinee
    ;
    Ngamprasertsith, Somkiat
    ;
    ;
    Sawangkeaw, Ruengwit
    This study is a techno-economic analysis of biodiesel production from spent coffee grounds (SCGs) using ethyl acetate as an extracting solvent and a reactant through interesterification under supercritical conditions—a process called SCEA. Aspen Plus V12 was employed to simulate the SCEA process compared to the conventional biodiesel production process. Both processes operated at an original feed rate of 24,225 tonnes per year, but the production capacities of the conventional and SCEA processes were 1000 tonnes per year and 1800 tonnes per year, respectively. Because of the simplicity of SCEA, the fixed capital investment costs were lower than those of the conventional process. However, at the original feed rate, neither process was profitable within a project lifetime of 20 years. The production capacity of SCEA was increased to 4 times, 8 times, and 16 times its original size to identify the most effective scale for the production facility. The SCEA process commenced successfully with a production capacity of 7500 tonnes per year, but the payback period of 19.5 years was deemed unsatisfactory. The production capacities of 15,000 tonnes per year and 30,000 tonnes per year provided the payback periods of 7.67 years and 6.08 years, respectively. Nonetheless, the 15,000-ton plant requires 193,798 tonnes SCGs per year as feedstock, which is 12 times the annual coffee production in Thailand. Hence, this project is well-suited for large coffee producers when utilizing SCGs as a singular feedstock. Combining other feedstocks, such as microalgae, non-edible seeds, and waste fruit seeds, with SCGs presents an optional pathway for future research on biodiesel production.