Chuayboon, Srirat
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Preferred name
Chuayboon, Srirat
Alternative Name
Chuayboon, S.
Main Affiliation
Email
srirat.ch@kmitl.ac.th
4 results
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Item type:Publication, Continuous solar-driven gasification of oil palm agricultural bio waste for high-quality syngas production(2022-12-01); Abanades, StéphaneEmpty fruit bunch (EFB) from oil palm is a solid agricultural bio-waste obtained from the edible oil process. Continuous solar-driven gasification of EFB offers a bright carbon–neutral avenue to convert both EFB bio-waste and renewable solar energy into sustainable and clean syngas. High-temperature concentrated solar heat is used to provide the reaction enthalpy, and therefore biomass waste feedstock is entirely dedicated to produce hydrogen and carbon monoxide (syngas). Solar energy is stored as a high-quality syngas and can be easily transported as a convertible and dispatchable chemical form. In this study, the performance of continuous steam gasification of EFB, fully powered by concentrated solar heat, was experimentally investigated in a solar gasification reactor. Experiments were carried out with continuous EFB biomass injection to evaluate the influence of temperature (1100–1300 °C) and biomass feeding rate (0.5–1.8 g/min). As a result, syngas yields and reactor performance were substantially enhanced by rising the EFB feeding rate and gasification temperature. An optimal EFB biomass feeding rate enabling maximum gasification performance was found to be 1.4 g/min at 1300 °C and 1.0 g/min at 1200 °C. Carbon conversion approaching 97%, energy upgrade factor of 1.38, and solar-to-fuel energy conversion efficiency up to 20% were demonstrated. Finally, the maximum syngas yield was found to be 81.1 mmol/g<inf>dry biomass</inf> at 1300 °C (with H<inf>2</inf> and CO as the main constituents), closely approaching the maximum theoretical expected value reached at thermodynamic equilibrium (85.2 mmol/g<inf>dry biomass</inf>). Combining concentrated solar energy and biomass waste gasification was shown to be a promising and sustainable pathway toward waste valorization into carbon–neutral solar fuels. - Some of the metrics are blocked by yourconsent settings
Item type:Publication, Solar metallurgical process for high-purity Zn and syngas production using carbon or biomass feedstock in a flexible thermochemical reactor(2023-05-05); Abanades, StéphaneCo-production of high-purity Zn and syngas via carbothermal reduction of ZnO was performed in a directly-irradiated concentrated solar reactor, thereby converting and storing intermittent sunlight into high-value chemical fuels and commodities. On-sun experiments were carried out by varying operating parameters including solid carbonaceous feedstocks (either solid carbon or beech wood biomass) in batch and continuous modes at 950–1350 °C, demonstrating solar reactor flexibility and robustness. Decreasing pressure (150–400 hPa) promoted both ZnO reduction rate and net ZnO conversion above 78%, thus enhancing Zn production yield. Nevertheless, CO selectivity decreased because of rising CO<inf>2</inf> due to the residence time decrease. A remarkable increase in gas production rates/yields, CO selectivity, and reaction extent was highlighted when increasing temperature during continuous pellets reactant injection. Furthermore, utilizing wood biomass as a sustainable green reducer was proved to be an attractive choice to produce both metallic Zn and high-quality syngas in a single process consisting of biomass gasification with solid ZnO. Zn content exceeding 90 wt% was demonstrated for both batch and continuous tests, unveiling high reactor performance for the metallurgical process. The energy content of the feedstock was upgraded by the solar power input (maximum energy upgrade factor up to 1.2), and the maximum solar-to-fuel energy conversion efficiency up to ∼ 6% was achieved with continuous reactant injection. The high-purity Zn can be further used to produce fuel via CO<inf>2</inf>-splitting in a complete and fast reaction. - Some of the metrics are blocked by yourconsent settings
Item type:Publication, Thermodynamic and experimental investigation of solar-driven biomass pyro-gasification using h2o, co2, or zno oxidants for clean syngas and metallurgical zn production(2021-04-01); Abanades, StéphaneThe solar gasification of biomass represents a promising avenue in which both renewable solar and biomass energy can be utilized in a single process to produce synthesis gas. The type of oxidant plays a key role in solar-driven biomass gasification performance. In this study, solar gasification of beech wood biomass with different oxidants was thermodynamically and experimentally investigated in a 1.5 kW<inf>th</inf> continuously-fed consuming bed solar reactor at 1200<sup>◦</sup>C under atmospheric pressure. Gaseous (H<inf>2</inf>O and CO<inf>2</inf> ) as well as solid (ZnO) oxidants in pellet and particle shapes were utilized for gasifying beech wood, and the results were compared with pyrolysis (no oxidant). As a result, thermodynamic predictions provided insights into chemical gasification reactions against oxidants, which can support experimental results. Compared to pyrolysis, using oxidants significantly promoted syngas yield and energy upgrade factor. The highest total syngas yield (63.8 mmol/g<inf>biomass</inf> ) was obtained from biomass gasification with H<inf>2</inf>O, followed by CO<inf>2</inf>, ZnO/ biomass mixture (pellets and particles), and pyrolysis. An energy upgrade factor (U) exceeding one was achieved whatever the oxidants, with the maximum U value of 1.09 from biomass gasification with ZnO, thus highlighting successful solar energy storage into chemical products. ZnO/biomass pellets exhibited greater gas yield, particularly CO, thanks to enhanced solid–solid reaction. Solid product characterization revealed that ZnO can be reduced to high-purity Zn through solar gasification, indicating that solar-driven biomass gasification with ZnO is a promising innovative process for CO<inf>2</inf>-free sustainable co-production of metallic Zn and high-quality syngas. - Some of the metrics are blocked by yourconsent settings
Item type:Publication, Carbon capture through solar-driven CO2 gasification of oil palm empty fruit bunch to produce syngas and biochar(2025-05-15) ;Al-Muraisy, Saqr A.A.; ;Soares, Lais Americo ;Buijnsters, J. G.Ismail, Shahrul binOil palm empty fruit bunch (OPEFB) is an abundant organic waste in Malaysia that is often disposed of through field burning. A previous study has shown that solar-driven steam gasification of OPEFB can produce hydrogen-rich syngas with an energy upgrade factor of 1.2 and a carbon conversion efficiency of 95.1 %. Beyond its potential as a biofuel, OPEFB can also act as a carbon sink, capturing photosynthetically stored carbon. This study explores the potential of amplifying OPEFB's negative carbon emissions through solar-driven gasification, using CO<inf>2</inf> as the gasifying agent. In this work, a Central Composite Design (CCD) approach was employed to assess the influence of temperature (1100–1300 °C) and CO<inf>2</inf>/OPEFB molar ratio (1.6–3.0) on H<inf>2</inf>/CO molar ratio and energy upgrade factor, with a constant OPEFB flow rate of 1.8 g/min. The results demonstrated that at an energy upgrade factor of 1.4, 94.9 % of the total carbon was converted into syngas with a H<inf>2</inf>/CO molar ratio of 0.3. The maximum observed net carbon capture yield of 0.4 g C/g OPEFB was achieved at 1300 °C and a CO<inf>2</inf>/OPEFB molar ratio of 3.0. The remaining carbon (94.4–95.7 wt %) was converted into biochar with low heavy metal content, which has potential as a soil enhancer.
