Chuayboon, Srirat
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Chuayboon, Srirat
Alternative Name
Chuayboon, S.
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Email
srirat.ch@kmitl.ac.th
18 results
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Item type:Publication, Solar-driven chemical looping methane reforming using zno oxygen carrier for syngas and zn production in a cavity-type solar reactor(2020-11-01); Abanades, StéphaneConverting sunlight into chemical fuels and metal commodities, via solar thermochemical conversion processes, is an attractive prospect for the long-term storage of renewable energy. In this study, the combined methane reforming and ZnO reduction in a single reaction for co-production of hydrogen-rich syngas and metallic Zn was demonstrated in a flexible solar thermochemical reactor prototype, driven by highly concentrated sunlight. Using solar energy as the process heat source in chemical-looping methane reforming with the ZnO/Zn oxygen carrier is a means to reduce the dependence on conventional energy resources and to reduce emissions of CO<inf>2</inf> and other pollutants, while upgrading the calorific value of the feedstock for the production of energy-intensive and high-value chemical fuels and materials. On-sun experiments were carried out with different operating parameters including operating temperatures (800–1000<sup>◦</sup>C), inlet methane flow-rates (0.1–0.4 NL/min), and inlet ZnO feeding-rates (0.5–1.0 g/min) both in batch and continuous modes under reduced (0.15 and 0.45 bar) and atmospheric pressures (0.90 bar), thereby demonstrating solar reactor flexibility and reliability. As a result, increasing the temperature promoted net ZnO conversion at the expense of favored methane cracking reaction, which can be lowered by decreasing pressure to vacuum conditions. Diminishing total pressure improved the net ZnO conversion but favored CO<inf>2</inf> yield due to insufficient gas residence time. Rising ZnO feeding rate under a constant over-stoichiometric CH<inf>4</inf>/ZnO molar ratio of 1.5 enhanced ZnO and methane consumption rates, which promoted Zn and syngas yields. However, an excessively high ZnO feeding rate may be detrimental, as ZnO could accumulate when the ZnO feeding rate is higher than the ZnO consumption rate. In comparison, continuous operation demonstrated greater performance regarding higher ZnO conversion (X<inf>ZnO</inf>) and lower methane cracking than batch operation. High-purity metallic Zn with a well-crystallized structure and of micrometric size was produced from both batch and continuous tests under vacuum and atmospheric pressures, demonstrating suitable reactor performance for the solar thermochemical methane-driven ZnO reduction process. The produced Zn metal can be further re-oxidized with H<inf>2</inf>O or CO<inf>2</inf> in an exothermic reaction to produce pure H<inf>2</inf> or CO by chemical-looping. - Some of the metrics are blocked by yourconsent settings
Item type:Publication, Comprehensive performance assessment of a continuous solar-driven biomass gasifier(2018-12-15); - Some of the metrics are blocked by yourconsent settings
Item type:Publication, Experimental analysis of continuous steam gasification of wood biomass for syngas production in a high-temperature particle-fed solar reactor(2018-03-01); - Some of the metrics are blocked by yourconsent settings
Item type:Publication, Clean magnesium production using concentrated solar heat in a high-temperature cavity-type thermochemical reactor(2019-09-20); Abanades, StéphaneThe synthesis of magnesium from the corresponding oxide via a solar carbo-thermal and methano-thermal reduction process using high-temperature concentrated solar heat was investigated. The reduction of magnesium oxide (MgO) was experimentally demonstrated in a directly-irradiated prototype solar reactor at reduced pressure and temperature up to ∼1650 °C. The solar reactor was successfully operated with a variety of reducing agents (carbon and CH<inf>4</inf>) in batch and continuous modes under atmospheric and low pressure conditions (0.1–0.9 bar), thus representing the first process demonstration of MgO carbothermal reduction with continuous reactant injection in vacuum condition. A parametric study regarding operating pressure, carbon feedstock type, and C/MgO molar ratio was conducted to emphasize their effect on products yield (Mg and CO) and solar reactor performance. MgO conversion, reduction rate, and CO yield increased with decreasing pressure, in agreement with thermodynamic analysis. Utilizing activated charcoal as reducing agent showed the highest MgO conversion and CO yield. High MgO conversion over 99% was demonstrated with maximal CO yield up to 24.59 mmol/g<inf>MgO</inf>, closely approaching theoretical maximum value (24.81 mmol/g<inf>MgO</inf>). Employing methane as a reducing agent was also shown to be an alternative option to produce Mg, although methane cracking occurred simultaneously at the elevated reaction temperature. Mg recovery in the outlet products was identified as one of the most critical process challenges because of the pyrophoric property of the produced nanopowder and its strong oxidation reactivity with air. - Some of the metrics are blocked by yourconsent settings
Item type:Publication, Solar Carbo-Thermal and Methano-Thermal Reduction of MgO and ZnO for Metallic Powder and Syngas Production by Green Extractive Metallurgy(2022-01-01); Abanades, StéphaneThe solar carbo-thermal and methano-thermal reduction of both MgO and ZnO were performed in a flexible solar reactor operated at low pressure through both batch and continuous operations. The pyro-metallurgical process is an attractive sustainable pathway to convert and store concentrated solar energy into high-value metal commodities and fuels. Substituting fossil fuel combustion with solar energy when providing high-temperature process heat is a relevant option for green extractive metallurgy. In this study, a thermodynamic equilibrium analysis was first performed to compare the thermochemical reduction of MgO and ZnO with solid carbon or gaseous methane, and to determine the product distribution as a function of the operating conditions. The carbo-thermal and methano-thermal reduction of the MgO and ZnO volatile oxides was then experimentally assessed and compared using a directly irradiated cavity-type solar reactor under different operating conditions, varying the type of carbon-based reducing agent (either solid carbon or methane), temperature (in the range 765–1167<sup>◦</sup>C for ZnO and 991–1550<sup>◦</sup>C for MgO), total pressure (including both reduced 0.10–0.15 bar and atmospheric ~0.90 bar pressures), and processing mode (batch and continuous operations). The carbo-thermal and methano-thermal reduction reactions yielded gaseous metal species (Mg and Zn) which were recovered at the reactor outlet as fine and reactive metal powders. Reducing the total pressure favored the conversion of both MgO and ZnO and increased the yields of Mg and Zn. However, a decrease in the total pressure also promoted CO<inf>2</inf> production because of a shortened gas residence time, especially in the case of ZnO reduction, whereas CO<inf>2</inf> formation was negligible in the case of MgO reduction, whatever the conditions. Continuous reactant co-feeding (corresponding to the mixture of metal oxide and carbon or methane) was also performed during the solar reactor operation, revealing an increase in both gas production yields and reaction extent while increasing the reactant feeding rate. The type of carbon reducer influenced the reaction extent, since a higher conversion of both MgO and ZnO was reached when using carbon with a highly available specific surface area for the reactions. The continuous solar process yielded high-purity magnesium and zinc content in the solar-produced metallic powders, thus confirming the reliability, flexibility, and robustness of the solar reactor and demonstrating a promising solar metallurgical process for the clean conversion of both metal oxides and concentrated solar light to value-added chemicals. - Some of the metrics are blocked by yourconsent settings
Item type:Publication, Complete solar thermal direct reduction of iron ore by hydrogen in a particle-fed reactor under concentrated sunlight(2026-06-01) - Some of the metrics are blocked by yourconsent settings
Item type:Publication, Continuous solar-driven gasification of oil palm agricultural bio waste for high-quality syngas production(2022-12-01); Abanades, StéphaneEmpty fruit bunch (EFB) from oil palm is a solid agricultural bio-waste obtained from the edible oil process. Continuous solar-driven gasification of EFB offers a bright carbon–neutral avenue to convert both EFB bio-waste and renewable solar energy into sustainable and clean syngas. High-temperature concentrated solar heat is used to provide the reaction enthalpy, and therefore biomass waste feedstock is entirely dedicated to produce hydrogen and carbon monoxide (syngas). Solar energy is stored as a high-quality syngas and can be easily transported as a convertible and dispatchable chemical form. In this study, the performance of continuous steam gasification of EFB, fully powered by concentrated solar heat, was experimentally investigated in a solar gasification reactor. Experiments were carried out with continuous EFB biomass injection to evaluate the influence of temperature (1100–1300 °C) and biomass feeding rate (0.5–1.8 g/min). As a result, syngas yields and reactor performance were substantially enhanced by rising the EFB feeding rate and gasification temperature. An optimal EFB biomass feeding rate enabling maximum gasification performance was found to be 1.4 g/min at 1300 °C and 1.0 g/min at 1200 °C. Carbon conversion approaching 97%, energy upgrade factor of 1.38, and solar-to-fuel energy conversion efficiency up to 20% were demonstrated. Finally, the maximum syngas yield was found to be 81.1 mmol/g<inf>dry biomass</inf> at 1300 °C (with H<inf>2</inf> and CO as the main constituents), closely approaching the maximum theoretical expected value reached at thermodynamic equilibrium (85.2 mmol/g<inf>dry biomass</inf>). Combining concentrated solar energy and biomass waste gasification was shown to be a promising and sustainable pathway toward waste valorization into carbon–neutral solar fuels. - Some of the metrics are blocked by yourconsent settings
Item type:Publication, Combined ZnO reduction and methane reforming for co-production of pure Zn and syngas in a prototype solar thermochemical reactor(2021-01-01); Abanades, StéphaneSolar thermochemical conversion processes offer a promising avenue for storing intermittent solar energy into high value chemical products. A directly-irradiated packed-bed reactor was developed to experimentally investigate the solar thermochemical methane reforming combined with ZnO reduction for co-production of Zn and syngas in a single process. On-sun experiments were conducted to demonstrate reliable process operation and to identify optimal operating conditions, considering the impact of reduced and atmospheric pressures, temperatures, and inlet methane flow-rates. A pressure decrease enhanced net ZnO conversion at the expense of lowered syngas selectivity attributed to the CO<inf>2</inf> increase because of insufficient gas residence time. Increasing temperature promoted syngas production rate, yield, ZnO and methane conversion at the expense of favored methane cracking which can be alleviated by lowering pressure. The maximum H<inf>2</inf> and CO yields of 28.4 and 4.6 mmol/g<inf>ZnO</inf>, and the maximum net ZnO conversion and methane conversion (67.3% and 57.6%) were achieved from non-isothermal tests. The calorific value of chemical products was upgraded by solar energy (U up to 1.31), and η<inf>solar-to-chemical</inf> = 3.9% was achieved. Pure and highly reactive metallic Zn was produced with well crystallized structure in micrometric size, demonstrating the feasibility of combined solar methane reforming and ZnO reduction for synthetic fuel production and sustainable Zn metallurgy. - Some of the metrics are blocked by yourconsent settings
Item type:Publication, Carbon-neutral synfuel production via continuous solar H2O and CO2 gasification of oil palm empty fruit bunch(2023-10-15); Abanades, StéphaneSolar gasification offers a promising carbon-neutral pathway to thermochemically convert waste biomass and solar energy into synfuel. In this study, a thermodynamic analysis of solar gasification of oil palm empty fruit bunch (EFB) with H<inf>2</inf>O and CO<inf>2</inf> gasifying agents was first performed to predict equilibrium product distribution. Subsequently, on-sun continuous solar gasification of EFB was experimentally carried out in a solar particle-fed gasifier to evaluate the influence of gasifying agent types (H<inf>2</inf>O and CO<inf>2</inf>), gasifying agent/EFB molar ratios (1.8–3.4), temperatures (1050–1350 °C), and to assess overall process feasibility and reliability. As a result, solar EFB gasification performed efficiently with both H<inf>2</inf>O and CO<inf>2</inf> gasifying agents under continuous on-sun operation. Syngas product composition and gasification reaction rate strongly depended on gasifying agent type. Increasing temperature enhanced syngas yield and quality, and changed the CO/H<inf>2</inf> mole ratio, especially in EFB + CO<inf>2</inf> gasification. A gasifying agent/EFB molar ratio of 2.6 (slight excess of gasifying agents) and a temperature of 1300 °C were shown to be optimal for continuous solar EFB gasification. The maximum total syngas yield above 76 mmol/g<inf>dry_EFB</inf>, syngas lower heating value above 22 kJ/g<inf>dry_EFB</inf>, and energy upgrade factor above 1.37 were achieved from both EFB + H<inf>2</inf>O and EFB + CO<inf>2</inf> gasification, which closely approached their theoretical equilibrium values. The maximum carbon conversion exceeding 93% and solar-to-fuel energy conversion efficiency up to 19.3% were achieved, demonstrating efficient EFB-to-synfuel conversion performance. Continuous solar EFB gasification with both H<inf>2</inf>O and CO<inf>2</inf> was thus established to be a reliable process for EFB waste biomass valorization into high-quality and carbon-neutral synfuel. - Some of the metrics are blocked by yourconsent settings
Item type:Publication, Thermochemical performance assessment of solar continuous methane-driven ZnO reduction for co-production of pure zinc and hydrogen-rich syngas(2022-02-01); Abanades, StéphaneConverting renewable solar energy to dispatchable chemical products via solar-driven thermochemical processes is one of the best solutions for long-term solar energy storage and renewable fuel production. This study addresses the performance assessment of continuous methane-driven ZnO reduction, fully powered by renewable solar heat, for co-production of hydrogen-rich syngas and metallic Zn in a solar prototype consuming-bed chemical reactor. On-sun experiments were conducted under continuous ZnO and CH<inf>4</inf> co-feeding to assess the effect of key parameters (inlet CH<inf>4</inf>/ZnO molar ratio: 1–1.5, temperature: 900–1000 °C, and ZnO feeding rate: 0.5–1.5 g/min) in order to maximize syngas and Zn yields, and reactor performance metrics. As a result, a rise in either the CH<inf>4</inf>/ZnO molar ratio or temperature enhanced the reaction extent but favored solid carbon formation, which downgraded syngas products quality, and consumed more solar energy input. Increasing ZnO feeding rate under a constant ZnO/CH<inf>4</inf> molar ratio significantly promoted ZnO + CH<inf>4</inf> reaction performance thanks to both hastened ZnO consumption rate (boosting products yield) and reduced solar energy consumption (improving solar conversion efficiency). However, excessively high ZnO feeding rate caused temporal ZnO accumulation in the reactor. Optimal operating conditions for on-sun continuous methane-driven ZnO reduction were identified (at ZnO feeding rate = 1.2 g/min, CH<inf>4</inf>/ZnO molar ratio = 1.5, and temperature = 950 °C), yielding total syngas yield of 12.3 mmol/g<inf>ZnO</inf>, solid carbon formation down to 0.58 mmol/g<inf>ZnO</inf>, ZnO conversion of 63.0%, methane conversion of 10.6%, energy upgrade factor of 1.08, and solar-to-fuel energy conversion efficiency of 5.3%. High-purity Zn particles with hexagonal morphologies were generated in continuous mode, demonstrating the proposed approach feasibility and reliability for simultaneous methane conversion to syngas and metallic Zn production in a single process.