Wongpromrat, Patthranit

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School of Engineering

patthranit.wo@kmitl.ac.th

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Possibility of metallic cobalt formation in the oxide scale during high-temperature oxidation of Co-27Cr-6Mo alloy in air
(2023-01-01)
Wongpromrat, Patthranit
;
Tunthawiroon, Phacharaphon
;
Bumrungthaichaichan, Eakarach
;
Ponpo, Phisan
;
Nilsonthi, Thanasak
Co-based alloys are known to be high oxidation-resistant material and used in several high temperature applications. During high temperature oxidation, duplex oxides containing Co and Cr were formed. It was thermodynamically elucidated that when the growing scale was thick enough, the partial pressure of O<inf>2</inf> in the scale dropped. Then, the reduction of CoO occurred for promoting O<inf>2</inf> which was responsible for Cr<inf>2</inf>O<inf>3</inf> production. This work experimentally proved this point by in situ char-acterising Co-27Cr-6Mo at high temperatures in air by X-ray diffractometer in a grazing incident mode and metallic Co was confirmed to be formed by the reduction of CoO consistent with the image taken and analysed by field emission scanning electron microscope, energy-dispersive X-ray, and electron backscatter diffraction. Furthermore, the change in lattice parameter and the phase transition were observed when the temperature was altered.
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Evidence for chromium, cobalt and molybdenum volatilisations during high temperature oxidation of Co-27Cr-6Mo Alloy
(2022-07-01)
Wongpromrat, Patthranit
;
Galerie, Alain
;
Thublaor, Thammaporn
;
Chandra-ambhorn, Walairat
;
Ponpo, Phisan
A Co-27Cr-6Mo alloy was oxidised in pure O<inf>2</inf> between 800 and 1000 °C for durations up to 96 h. The flow rate was varied between 2 and 5 cm.s–1. In these conditions, volatilisations of chromium, cobalt and molybdenum were observed. The chromium volatilisation values were in good agreement with calculations assuming (CrO<inf>3</inf>)g volatilisation limited by diffusion in the gas boundary layer. On the contrary, the measured flux of evaporated Co was higher than the calculated Co volatilisation flux from the metallic Co. The theoretical relation between the solid Co particle size and its vapour pressure was suggested to help explaining such difference.
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Corrosion Resistance Enhancement of Reinforced Concrete in Marine Environment by Partial Replacement of Black Rice Husk Ash
(2023-01-01)
Chandra-Ambhorn, Walairat
;
Bumrungthaichaichan, Eakarach
;
Rotchan, Chayanit
;
Haema, Narunat
;
Wongpromrat, Patthranit
In this work, the black rice husk ash (BRHA), a pozzolanic material, was used as a partial replacement in concrete with the weight percentages of 0%, 10%, 20%, 30%, 40% and 50% for enhancing the corrosion resistivity in the marine environment. The compressive strength, corrosion by accelerated corrosion test by impressed voltage (ACTIV), and chloride (Cl− ) penetration of concrete specimens were investigated after 28 days of curing. For corrosion and chloride penetration analyses, the 20% of BRHA replacement specimen was the most effective concrete specimen because the deformation was not observed within 19 days of the test. The cement specimens with lower BRHA percentages were cracked due to the development of stress by the rust formation. For higher BRHA percentages, the protective Fe2O3 was dissolved due to the acidic environment caused by higher chloride accumulation in the cement specimens. The steel rebar was then aggressively attacked by the chloride and it was finally broken. Therefore, the optimization of the BRHA percentage is needed to minimize corrosion. However, the longer curing time of 20% BRHA replacement specimen is required for increasing the compressive strength because its compressive strength is slightly lower than the standard.
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Effect of water vapour on the high temperature oxidation of stainless steels
(2020-01-01)
Chandra-Ambhorn, Somrerk
;
Wongpromrat, Patthranit
;
Thublaor, Thammaporn
;
Chandra-Ambhorn, Walairat
This chapter primarily reviews the nature of water vapour when it presents in bulk gas. The change in a ratio between water vapour and corresponding dissociated hydrogen, which determine the thermodynamic stability of the oxide formation, is analysed when the oxidation kinetics are linear and parabolic. When water vapour reaches the solid/gas interface, chromium species volatilisation and oxidation controlled by surface reaction can occur. The adsorbed water vapour can be further incorporated into the oxide possibly in the form of hydrogen defects. The role of these defects on altering the defect structure of the oxide is discussed. Finally, characteristics of the oxide scale on stainless steels formed in the atmosphere containing water vapour are reviewed.
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Simple Empirical Relation for an Evacuated-Tube Solar Collector Performance Prediction from Solar Intensity
(2023-09-01)
Pongboriboon, Nattapat
;
Wu, Wei
;
Chandra-ambhorn, Walairat
;
Wongpromrat, Patthranit
;
Bumrungthaichaichan, Eakarach
In this paper, the effect of solar intensity on the heat pipe tip temperature in a heat pipe type—evacuated-tube solar collector (HP-ETSC) was investigated. A simple relation was proposed, relating the solar intensity to the heat pipe tip temperature generated from the experimental data. This simple empirical relation was applied in a set of heat transfer equations derived to predict the heating medium temperature at the manifold outlet of the evacuated-tube solar collector. The calculated results corresponding to two types of heating medium, i.e., palm oil and water, were compared with experimental results from the literature. The results show that the average error was 6.41% for the case of palm oil and 4.66% for the case of water. Based on the case of water as a heating medium fluid, it was found that the flow rate of the heating medium fluid affected the accuracy of prediction, as the percentage error increased with the heating medium flow rate. The maximum percentage error increased from only 1.83% for a water inlet flowing at a Reynolds number of about 2.4 × 103 to 15.23% for a water flow rate at a Reynolds number of about 2.6 × 104. The correction factor was added into the correlation to predict the heat transfer coefficients of heating medium fluids. With this correction factor, the maximum error could be reduced from 11.78% to 7.29% for the palm oil case and from 15.23% to 5.57% for the water case. The average errors corresponding to palm oil and water cases could be reduced to 0.74% and 1.26%, respectively.
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Development of sofc interconnect stainless steels
(2020-01-01)
Chevalier, Sébastien
;
Combemale, Lionel
;
Popa, Ioana
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Chandra-Ambhorn, Somrerk
;
Chandra-Ambhorn, Walairat
The chapter introduces components and working principle of solid oxide fuel cells (SOFCs). It is followed by the explanation on the choices of materials focussing on ferritic stainless steels. The review is further made on the required properties of these steels, i.e. low oxidation rate, low chromium species volatilisation rate, high electrical conductivity and good scale adhesion. For the oxidation aspect, the behaviour of stainless steel interconnect in cathode, anode (hydrogen and biogas), and dual atmospheres are described. Surface modification by pre-oxidation and coatings to improve the oxide electrical conductivity and to reduce chromium species volatilisation is finally reviewed.

Wongpromrat, Patthranit

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