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    Evidence for chromium, cobalt and molybdenum volatilisations during high temperature oxidation of Co-27Cr-6Mo Alloy
    (2022-07-01) ;
    Galerie, Alain
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    Thublaor, Thammaporn
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    Ponpo, Phisan
    A Co-27Cr-6Mo alloy was oxidised in pure O<inf>2</inf> between 800 and 1000 °C for durations up to 96 h. The flow rate was varied between 2 and 5 cm.s<sup>–1</sup>. In these conditions, volatilisations of chromium, cobalt and molybdenum were observed. The chromium volatilisation values were in good agreement with calculations assuming (CrO<inf>3</inf>)g volatilisation limited by diffusion in the gas boundary layer. On the contrary, the measured flux of evaporated Co was higher than the calculated Co volatilisation flux from the metallic Co. The theoretical relation between the solid Co particle size and its vapour pressure was suggested to help explaining such difference.
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    Effect of water vapour on the high temperature oxidation of stainless steels
    (2020-01-01)
    Chandra-Ambhorn, Somrerk
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    Thublaor, Thammaporn
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    This chapter primarily reviews the nature of water vapour when it presents in bulk gas. The change in a ratio between water vapour and corresponding dissociated hydrogen, which determine the thermodynamic stability of the oxide formation, is analysed when the oxidation kinetics are linear and parabolic. When water vapour reaches the solid/gas interface, chromium species volatilisation and oxidation controlled by surface reaction can occur. The adsorbed water vapour can be further incorporated into the oxide possibly in the form of hydrogen defects. The role of these defects on altering the defect structure of the oxide is discussed. Finally, characteristics of the oxide scale on stainless steels formed in the atmosphere containing water vapour are reviewed.