Lerkkasemsan, Nuttapol
Loading...
Preferred name
Lerkkasemsan, Nuttapol
Main Affiliation
Email
nuttapol.le@kmitl.ac.th
15 results
Now showing 1 - 10 of 15
- Some of the metrics are blocked by yourconsent settings
Item type:Publication, Study of ethanol fermentation reaction using Saccharomyces diastaticus in a two-tank fermentation system with cell recycling(2018-10-01); Lee, Wen ChienExperimental data of ethanol fermentation in a two-tank system with cell recycling using sucrose as a substrate were investigated to establish a kinetic model that described the reaction. Flocculent yeast Saccharomyces diastaticus LORRE-316 was used as the fermenting yeast, and the fermentation medium comprised 80 g/L sucrose, 10 g/L yeast extract, 10 g/L peptone, 2 g/L potassium phosphate monobasic (KH<inf>2</inf>PO<inf>4</inf>), and 0.5 g/L magnesium sulfate heptahydrate (MgSO<inf>4</inf>·7H<inf>2</inf>O). Three models, the Monod model, the modified Monod model, and the extended-modified Monod model, were used to describe fermentation, and the extended-modified Monod model described the reaction more accurately than the other two models. The model took substrate limitations plus substrate and ethanol inhibitive effects into consideration, and was modified to include assumptions that included terms for substrates (sucrose, glucose and fructose) and product (ethanol). In addition, the ethanol concentration had a significant effect on cell growth. The results of Lineweaver–Burk plots showed that the maximum specific growth rate (μ<inf>MAX</inf>) and the Monod constant (K<inf>S</inf>) were 0.72/h and 26.77 g/L, respectively. The models were suitable for describing the experimental data. - Some of the metrics are blocked by yourconsent settings
Item type:Publication, Mn-Fe Prussian blue analogue as low-cost robust cathode for non-aqueous Zn-ion batteries(2023-03-01) ;Yimtrakarn, Trakarn ;Liao, Yi Chih ;MV, Ahmed Sanin ;Chen, Jeng LungChuang, Yu ChunZn-ion batteries (ZIBs) are one of the most promising alternatives for large-scale energy storage systems due to two-electron transfer capability, safety, low toxicity, and low cost. However, most of the cathode materials reported for non-aqueous ZIBs still show unsatisfactory electrochemical performance. To overcome this, factors such as type of crystal structure, transition metal-ion coordination, and nature of the d orbitals being filled must be taken into consideration in the design of suitable host materials. Herein, we report the use of a Prussian blue analogue, sodium manganese hexacyanoferrate (NaMnFe-PB), as cathode in ZIBs. Its ease of synthesis, rigid open framework, and compositional and electrochemical tunability make this low-cost Mn-Fe-based compound highly attractive. The strong interactions among the two redox centers Mn<sup>III</sup>/Mn<sup>II</sup>, Fe<sup>III</sup>/Fe<sup>II</sup>, and C[tbnd]N<sup>-</sup> ligand allow two close voltage plateaus at ∼1.50 V vs Zn/Zn<sup>2+</sup>, delivering a capacity of 89.5 mAh g<sup>-1</sup>. Ex-situ X-ray absorption and diffraction techniques confirm the high redox reversibility and structural stability of NaMnFe-PB upon divalent guest insertion. The Fe(CN)<inf>6</inf> vacancies and coordinated water in the host lattice are believed to facilitate cation diffusion. The insight gained in this work may pave the way for the design of low-cost cathode materials for next-generation large-scale energy storage systems. - Some of the metrics are blocked by yourconsent settings
Item type:Publication, Outer-tubes Falling Film Evaporator with Well-Mixed Surface Renewal(2017-01-01); ;Lerssubsuree, Kuntaphon ;Chotiviriyavanich, Boonchai ;Benjangkaprasert, RuenruedeeKitchaiya, PrakobA falling film evaporator with a liquid flowing laminarly outside vertical cylindrical tubes was studied by a mathematical modeling in order to describe the performance of the system and the results are later used for a design of a falling film evaporator. In this study a mathematical model was developed from mass and energy as well as momentum transfer processes in an evaporation of a sugar solution. The equations were solved by using a numerical technique known as implicit method. This model yields the prediction of velocity, temperature and concentration profiles of solution as well as rate of mass evaporation and energy required in this process. Evaporation limitation was disclosed to be based on water mass transfer across the liquid thin film. Renewable surface was proposed to enhance the evaporation by adding a collector for liquid mixing before further evaporation. Adding only one collector at the half height of the evaporation tube could increase water evaporation rate by 1.3 and 2.1 % in case of the liquid perfect mixing, respectively. - Some of the metrics are blocked by yourconsent settings
Item type:Publication, Kinetic modeling of CO2 gasification reactivity of Palm Kernel Shell (PSK)(2017-01-01)This research demonstrates the investigation of gasification reactivity behavior of palm kernel shell bio char using thermogravimetric analysis (TGA) at 850, 900 or 950°C under CO<inf>2</inf>. There are three fluid-solid kinetic models used to describe the reaction behavior of palm kernel shell bio char. The three models are volumetric model (VM), grain model (GM), and random pore model (RPM). From model results, the GM model and RPM model describe the reaction quite well. However, the GM model is considered as the best model in all three models to describe the reactivity of palm kernel shell bio char gasification reaction. From the GM model, the reaction starts from the surface and it moves to the core. As time go on, the gasify agent will defuse through the core and it keep the reaction go into the core. The activation energy of gasification reactivity of palm kernel shell bio char are 150kJ/mol for GM model. From the results, the coefficient of determination of GM model are 0.989, 0.989, and 0.961 at 850, 900, 950°C respectively. - Some of the metrics are blocked by yourconsent settings
Item type:Publication, Kinetic Study of Steam Gasificaiton of Palm Kernel Shell Char(2020-05-27)In this work, we investigate the reaction mechanism of steam gasification reaction of palm kernel shell char. The experiment results which are used in this work are carried on at temperature of 1123, 1173, and 1223K. The isothermal steam gasification of palm kernel shell char is described by mathematic models including volumetric model (VM), grain model (GM), random pore model (RPM), and modified random pore model (mRPM). From results, we found that the RPM model can predict gasification of palm kernel shell char better than other models. The RPM model considers the overlapping of pore surfaces, which results in the reduction of surface area available for the reaction. The activation energy of gasification reactivity of palm kernel shell char is 152.63 kJ/mol for RPM model. The coefficient of determination of RPM model are 0.9920, 0.9995, and 0.9907 at 1123, 1173, and 1223 K respectively. - Some of the metrics are blocked by yourconsent settings
Item type:Publication, Efficient and selective electrosynthesis of 4-aminophenol at circumneutral pH from the electrocatalytic reduction of nitrophenol over the nickel-iron phosphide modified electrode(2023-12-01) ;Ong, Papontee Sae ;Huang, Shih Ching ;Lin, Chia YuThe efficient and sustainable synthesis of 4-aminophenol (4-AP) from the electrocatalytic reduction of 4-nitrophenol (e-NPR) with water as the proton source relies on the development of robust electrocatalysts that readily expedite the kinetics of e-NPR and generate 4-AP with high selectivity at environmentally-benign conditions. In this study, we report on the efficient and sustainable electrosynthesis of 4-AP at circumneutral pH using the micro-structured nickel-iron phosphide modified electrode (CP|microNiFeP). The effects of the iron content of the prepared CP|microNiFeP electrodes as well as electrolysis conditions, including the electrolyte pH, applied potential, and electrolysis duration, on the electrosynthesis of 4-AP were thoroughly examined through a series of controlled-potential electrolyses (CPEs). Under optimal conditions, the CP|microNiFeP electrode exhibited a turnover frequency of 7.25 ± 0.05 h<sup>−1</sup> for the generation of 4-AP at 0.0 V vs. RHE and achieved a high 4-NP conversion of 92.29 ± 1.47% with high selectivity for 4-AP generation (S<inf>A</inf><inf>P</inf>:85.77 ± 2.21%) after 8-h CPE at −0.15 V vs. RHE in the H-cell. In addition, the scale-up electrosynthesis of 4-AP with a flow-type electrolyzer was also demonstrated. The 3-h electrolysis using the flow-type electrolyzer resulted in a high 4-NP conversion (93.84 ± 0.84%) with a high S<inf>AP</inf> (86.32 ± 1.05%). The possible reaction pathways of e-NPR have been proposed, and 4,4′-dihydroxyazobenzene and dimers were identified as the main side products. - Some of the metrics are blocked by yourconsent settings
Item type:Publication, A study of eutectic temperature of sugar mixture for thermal energy storage(2021-08-02) ;Wisutthimateekorn, SuchanunWe studied Phase Change Materials (PCMs), which can be used as thermal energy storage for temperatures lower than 120<sup>◦</sup>C: They can store both sensible heat from a changing temperature and latent heat from changing the state of a substance. The advantage of storing energy in a PCM is that it can be reused continuously, without the degradation of efficiency. Here, the PCM mixture consists of fructose and xylitol and thus, this PCM can be used to store energy below 120<sup>◦</sup>C. The calculated Excess Gibbs Energy and activity coefficient of xylitol and fructose decreased as the fraction of xylitol increased. We tested a system, which included an evacuated tubular collector and—fructose mixtures. The system with the PCM maintained a water temperature ~14<sup>◦</sup>C higher than water without the PCM. This PCM system could store 248 kJ/kg. The xylitol—fructose mixture had a market price ~$US 4.62 $/kg (2018 price), so compared to other PCMs, xylitol-fructose was cheap and store energy efficiently. - Some of the metrics are blocked by yourconsent settings
Item type:Publication, Solvent Selection for Mitragynine Extraction by Hansen Solubility Parameter(2023-01-01) ;Ditthapornset, Sirawich; Mitragyna speciosa (Korth.) Havil., commonly known as “Kratom” has a wide range of therapeutic benefits. In this research study the solvents that can be used to extract Mitragynine from kratom leaves. To predict solubility parameters, Hansen solubility parameters were employed. Then analyzing the solubility parameters using the ProCAPE application However, Mitragynine cannot directly determine the solubility. Instead, a method for evaluating the solubility from derivatives of Mitragynine was used in this study. A ternary graph shows the solubility of the derivatives and solvents. The solvents selected were considered for safety from the GSK’s Solvent Selection Guide. From the results, it was found that several types of solvents which that were dissolved derivatives of Mitragynine better than conventional solvents. Additionally, while using ProCAPE, the solubility parameters were predicted from extraction-related research was applied, and the results were shown as ternary graphs. The graphs were confirmed to be in accordance with the experimental data from the research that was collected. - Some of the metrics are blocked by yourconsent settings
Item type:Publication, Predicting Conversion from Pyrolysis of Pongmia(2015-01-01)This research demonstrates the technique of predicting pyrolysis of lignocellulosic biomass. Modeling of pyrolysis of biomass is complex and challenging because of short reaction times, temperatures as high as a thousand degrees Celsius, and biomass of varying or unknown chemical compositions. As such a deterministic model is not capable of representing the pyrolysis reaction system. To be able to predict a pyrolysis reaction of an unknown lignocellulosic biomass without an experimental data support or data fitting is an even more challenging work. In this research, we are trying to predict pyrolysis of Pongmia in Nitrogen to demonstrate that our technique is useful for predicting pyrolysis reaction of other biomass source. There are three main chemical compositions in lignocellulosic biomass which are cellulose, hemicellulose and lignin. We are considering that the total pyrolysis reaction is affected by the reaction of three main compositions. However, these three main chemical compositions of biomass is vary not only by type of biomass but also by other things such as where it is grown or even which part of biomass since the chemical compositions in the leaf can be different from the trunk. Our propose method is an extending study of our previous paper "pyrolysis of biomass-fuzzy modeling". Our model successfully gives a good predicting result. The result shows that our model can predict 91.82% of pyrolysis of Pongmia in Nitrogen correctly without any data from the experiment. Therefore, we could use this method to predict other lignocellulosic biomass before we perform an experiment. - Some of the metrics are blocked by yourconsent settings
Item type:Publication, Study of Lignin Extracted from Rubberwood Using Microwave Assisted Technology for Fuel Additive(2022-02-01) ;Yimtrakarn, Trakarn ;Kaveevivitchai, Watchareeya ;Lee, Wen ChienLignin is the most abundant natural aromatic polymer, especially in plant biomass. Lignin-derived phenolic compounds can be processed into high-value liquid fuel. This study aimed to determine the yield of lignin by the microwave-assisted solvent extraction method and to characterize some essential properties of the extracted lignin. Rubberwood sawdust (Hevea brasiliensis) was extracted for lignin with an organic-based solvent, either ethanol or isopropanol, in a microwave oven operating at 2450 MHz. Two levels of power of microwave, 100 W and 200 W, were tested as well as five extraction times (5, 10, 15, 20, 25, and 30 min). The extracted lignin was characterized by Klason lignin, Fourier transform infrared spectroscopy (FT-IR), 2D HSQC NMR, Ultraviolet-visible spectrophotometry (UV-vis), and Bomb calorimeter. The results showed that the yield of extracted lignin increased with the extraction time and power of the microwave. In addition, the extraction yield with ethanol was higher than the yield with isopropanol. The highest yield was 6.26 wt.%, with ethanol, 30 min extraction time, and 200 W microwave power.
