Publication: Oxidation of saturated hydrocarbons to alkyl hydroperoxides by a 'H 2O2/titanosilicalite-1/NaOH/MeCN' system
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Abstract
Hydrogen peroxide oxidizes alkanes at room temperature to produce the corresponding alkyl hydroperoxides in the presence of titanosilicalite-1, NaOH and acetonitrile. The reaction proceeds with low regio- and bond-selectivity and its mechanism apparently involves the formation of hydroxyl radicals. © 2008 Springer Science+Business Media, LLC.
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Keywords
Alkanes, Alkyl hydroperoxides, Hydrogen peroxide, Nano structures, Oxidation, Titanium catalysts
Citation
Catalysis Letters, 123(1-2), 135-141, 2008