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Multifunctional properties of Mn and Fe co-doped lead-free BCT perovskite ceramics synthesized via solid-state combustion
Author(s)
Kornphom, Chittakorn
Sonchaopri, Nutkamon
Yimsabai, Sununta
Jantaratana, Pongsakorn
Pinitsoontorn, Supree
Bongkarn, Theerachai
Date Issued
October 1, 2025
Type
Article
Abstract
There is a growing demand to improve the performance of multiferroic lead-free ceramics. Good ferroelectric and magnetic properties are key parameters for achieving high magnetoelectric coupling (ME). In this work, Mn and Fe were co-doped into lead-free Ba0.96Ca0.04Ti(1-x)(Mn0.5Fe0.5)xO3 (BCT-xMF) ceramics with 0 ≤ x ≤ 0.030 mol%, synthesized by the solid-state combustion technique. X-ray diffraction (XRD) analysis and Rietveld refinement confirmed the formation of a pure phase with coexisting tetragonal and cubic phases in all compositions. As the Mn/Fe content increased, the percentage of the tetragonal phase decreased while the cubic phase increased, consistent with Raman spectroscopy results. Increasing Mn/Fe content also led to more oxygen vacancies and defects, and a decrease in average grain size. Analysis of the temperature-dependent dielectric constant revealed a reduction in the Curie temperature from 116 to 67 °C, corresponding to the tetragonal-to-cubic phase transformation. The ceramic with x = 0.015 showed the highest dielectric constant at the Curie temperature (εc), maximum saturated polarization (Ps), remnant polarization (Pr), saturation magnetization (Ms), and remnant magnetization (Mr), with values of 4583, 14.09 μC/cm2, 9.31 μC/cm2, 0.0127 emu/g, and 0.006 emu/g, respectively. These results indicate that Fe/Mn co-doping into BCT ceramics enhanced both ferroelectric and ferromagnetic properties, resulting in a high magnetoelectric coefficient (αME∼1.27 mV/cm Oe) at room temperature, making these ceramics candidates for multiferroic applications.
Citation
Radiation Physics and Chemistry, 235, 2025