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Improvement of biohydrogen production from biomass using supercritical water gasification and CaO adsorption

Author(s)
Panichkittikul, Nitsara
Mariyappan, Vinitha
Wu, Wei
Patcharavorachot, Yaneeporn
Date Issued
April 1, 2024
Type
Article
DOI
10.1016/j.fuel.2023.130724
Abstract
Producing biohydrogen is a promising alternative to fossil fuels, sourced from renewable energy like wind, solar, and biomass, known for its eco-friendliness and minimal greenhouse gas emissions. This study focuses on the process design and simulation of producing biohydrogen from biomass (bagasse) gasification. New integration of the water gas shift reactor and CaO adsorption process is connected to biomass gasification with the steam/supercritical water agents for improving the hydrogen production process. Simulations show that steam gasification integrated with CaO adsorption (SG-CaO) is optimized at specific conditions, resulting in high-purity hydrogen at 99.95 %. Similarly, the supercritical water gasification integrated with CaO adsorption (SCWG-CaO) requires specific conditions, achieving exceptionally pure hydrogen at 99.99 %. In terms of energy analysis, SCWG-CaO outperforms SG-CaO, with higher hydrogen yield (14.16 % vs. 14.12 %) and greater energy efficiency (42.32 % vs. 40.26 %). It shows that the SCWG-CaO is a suitable and efficient approach for biohydrogen production, considering factors such as hydrogen purity, yield, and energy efficiency.
Citation
Fuel, 361, 2024
Subjects

Bagasse

Biohydrogen

Biomass gasification

CO2 capture

Supercritical water

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