Thermal decomposition kinetics of FePO4·3H2O precursor to synthetize spherical nanoparticles FePO4

Boonchom, Banjong; Danvirutai, Chanaiporn

doi:10.1021/ie071107z

Thermal decomposition kinetics of FePO4·3H2O precursor to synthetize spherical nanoparticles FePO4

Author(s)

Boonchom, Banjong

Danvirutai, Chanaiporn

Date Issued

December 19, 2007

Type

Conference Paper

DOI

10.1021/ie071107z

Abstract

The thermal decomposition of iron phosphate trihydrate FePO 4·3H2O was investigated in air using TG-DTG/DTA. The FePO4·3H2O decomposes in two steps, and the final decomposition product (FePO4) was studied by X-ray powder diffraction (XRD), scanning electron microscopy (SEM), and Fourier transform infrared (FT-IR) spectroscopy. The activation energies of the second dehydration reaction of FePO4·3H2O were calculated through the isoconversional methods of Ozawa and Kissinger-Akahira-Sunose (KAS), and the possible conversion functions have been estimated through the Coats-Redfern method. The specificity of thermal decomposition was characterized by identification of the bonds to be selectively activated due to energy absorption at the vibrational level, which was assigned by comparing the calculated wavenumbers with the observed wavenumbers in FTIR spectra. The kinetic model that better describes the second reaction of dehydration for FePO 4·3H2O is the Fn model as a simple n-order reaction, and the corresponding function is xc4(α) = (1-α)^2.50 and g(α) = -[1-(1-α)^-1.50/(1. 50)]. © 2007 American Chemical Society.

Citation

Industrial and Engineering Chemistry Research, 46(26), 9071-9076, 2007