Advanced AlN/SiO2/AlN multilayer coatings for protecting gold-like decorative surfaces: Improved hardness and color stability
| dc.contributor.author | Raengroeng, Sitanan | |
| dc.contributor.author | Theekhasuk, Nattharika | |
| dc.contributor.author | Sakulkalavek, Aparporn | |
| dc.contributor.author | Sakdanuphab, Rachsak | |
| dc.contributor.author | Somdock, Nuttakrit | |
| dc.date.accessioned | 2026-08-06T10:53:05Z | |
| dc.date.available | 2026-08-06T10:53:05Z | |
| dc.date.issued | 2025-12-01 | |
| dc.description.abstract | This study explores the development of multilayer AlN/SiO<inf>2</inf>/AlN thin film coatings to enhance tarnish resistance, surface hardness, and color stability of gold-coated silver substrates for decorative use. Gold films were deposited via electroplating, followed by multilayer coatings using reactive magnetron sputtering. The SiO<inf>2</inf> thickness was systematically varied while maintaining fixed AlN layers. Optical evaluations using CIE Lab parameters confirmed that the specimen with a 110-min SiO<inf>2</inf> layer exhibited acceptable color difference (ΔE < 5). X-ray photoelectron spectroscopy (XPS) revealed stable Al–N and Si–O bonds with minimal oxidation. Nanoindentation tests showed a significant hardness increase, reaching 7.02 ± 0.62 GPa. After 240 days of ambient exposure, multilayer-coated samples showed no visible discoloration or sulfur-induced degradation, unlike uncoated and electrochemically coated samples. These results confirm that AlN/SiO<inf>2</inf>/AlN multilayers effectively improve the durability and aesthetic stability of gold-like surfaces, offering a promising solution for long-term decorative applications. | |
| dc.identifier.citation | Current Applied Physics, 80, 1-8, 2025 | |
| dc.identifier.doi | 10.1016/j.cap.2025.08.009 | |
| dc.identifier.issn | 15671739 | |
| dc.identifier.other | 2-s2.0-105013676216 | |
| dc.identifier.uri | https://dspace.kmitl.ac.th/handle/123456789/17470 | |
| dc.source | Current Applied Physics | |
| dc.subject | Color changes and scratches | |
| dc.subject | Gold-like jewelry | |
| dc.subject | Multi-layer | |
| dc.title | Advanced AlN/SiO2/AlN multilayer coatings for protecting gold-like decorative surfaces: Improved hardness and color stability | |
| dc.type | Article |
