Hybrid gas sensor based on platinum nanoparticles/poly(methyl methacrylate)-coated single-walled carbon nanotubes for dichloromethane detection with a high response magnitude

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dc.contributor.authorMuangrat, Worawut
dc.contributor.authorYordsri, Visittapong
dc.contributor.authorMaolanon, Rungroj
dc.contributor.authorPratontep, Sirapat
dc.contributor.authorPorntheeraphat, Supanit
dc.contributor.authorWongwiriyapan, Winadda
dc.date.accessioned2026-08-06T10:13:49Z
dc.date.available2026-08-06T10:13:49Z
dc.date.issued2016-05-01
dc.description.abstractA dichloromethane (DCM) sensor with a high response magnitude was successfully fabricated using the integration of single-walled carbon nanotubes (SWNTs), poly(methyl methacrylate) (PMMA) and platinum nanoparticles (Pt NPs). A pristine SWNT network was first formed by drop-casting onto printed circuit board (PCB) substrates. Next, PMMA was coated onto the pre-dropped SWNT network by spin coating using a PMMA-toluene solution, followed by the deposition of Pt NPs by electron-beam evaporation (hereafter referred to as Pt/PMMA/SWNT). The Pt/PMMA/SWNT enabled an approximately 69-fold improvement in DCM detection compared to pristine SWNT. The high response magnitude of the Pt/PMMA/SWNT was successfully achieved because of the incorporation of PMMA and Pt functions. Swelling of the PMMA matrix as a result of DCM adsorption leads to PMMA volume expansion, thereby increasing the SWNT-SWNT distance, which results in an increase in the resistance. Pt NPs promote the dissociation of DCM to CO, and consequently the CO oxidation on the Pt NPs catalyst and electron donation from Pt NPs to SWNTs, resulting in an increase in the resistance. Moreover, a linear relationship was obtained between the sensor response of the Pt/PMMA/SWNT and the concentration of DCM. These results suggest that the integration of SWNTs with PMMA and Pt NPs is a promising approach for improving DCM detection at room temperature.
dc.identifier.citationDiamond and Related Materials, 65, 183-190, 2016
dc.identifier.doi10.1016/j.diamond.2016.03.016
dc.identifier.issn09259635
dc.identifier.other2-s2.0-84962426707
dc.identifier.urihttps://dspace.kmitl.ac.th/handle/123456789/6874
dc.sourceDiamond and Related Materials
dc.subjectDichloromethane
dc.subjectGas sensor
dc.subjectPlatinum nanoparticles
dc.subjectPoly(methyl methacrylate)
dc.subjectSingle-walled carbon nanotube
dc.titleHybrid gas sensor based on platinum nanoparticles/poly(methyl methacrylate)-coated single-walled carbon nanotubes for dichloromethane detection with a high response magnitude
dc.typeArticle

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