Reversal of methanation-oriented to RWGS-oriented Ni/SiO<sub>2</sub> catalysts by the exsolution of Ni<sup>2+</sup> confined in silicalite-1
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Green Chemistry
Abstract
Ni/SiO 2 -based catalysts derived from the reduction of silicalite-1-encapsulated, ligand-protected Ni 2+ was found to be effective in the selective hydrogenation of CO 2 to CO via the reverse water-gas shift (RWGS).