Near-Infrared Spectroscopy with Machine Learning for Classifying and Quantifying Nutmeg Adulteration

dc.contributor.authorSitorus, Agustami
dc.contributor.authorPambudi, Suluh
dc.contributor.authorBoodnon, Wutthiphong
dc.contributor.authorLapcharoensuk, Ravipat
dc.date.accessioned2026-08-06T10:45:15Z
dc.date.available2026-08-06T10:45:15Z
dc.date.issued2024-01-01
dc.description.abstractNear-infrared spectroscopy (NIRS) provides broadbands, overtones, and combinations of organic-bond vibrations and has been used to characterize agricultural and food products. The adulteration of grated nutmeg with cinnamon is extremely profitable and difficult to detect; to prevent retail fraud, it is vital to differentiate between these materials. This study proposes a model for classifying the adulteration of nutmeg with cinnamon and predicting the level of adulteration. NIR spectra were characterized with six machine learning (ML) algorithms, namely, the principal component-multilayer perceptron (PC-MLP), principal component-linear discriminant analysis (PC-LDA), partial least squares regression (PLSR), support vector machine (SVM), random forest (RF), and decision tree (DT) methods. PC-MLP provided 100% accuracy in calibration and prediction in distinguishing nutmeg from cinnamon. In addition, this approach showed excellent performance in predicting the adulteration ratio of nutmeg and cinnamon with a high coefficient of determination of prediction (R <sup>2</sup><inf>pred</inf>) value of 0.9969, low root mean square error of prediction (RMSEP) value of 0.5728%, and high ratio of prediction to deviation (RPD) value of 17.9605. Therefore, this study indicates the potential of integrating NIR spectroscopy with PC-MLP to classify and quantify the adulteration of nutmeg.
dc.identifier.citationAnalytical Letters, 57(2), 285-306, 2024
dc.identifier.doi10.1080/00032719.2023.2206665
dc.identifier.issn00032719
dc.identifier.other2-s2.0-85154611695
dc.identifier.urihttps://dspace.kmitl.ac.th/handle/123456789/15415
dc.sourceAnalytical Letters
dc.subjectAdulteration detection
dc.subjectchemometrics
dc.subjectherbs
dc.subjectnear-infrared spectroscopy (NIRS)
dc.subjectnutmeg
dc.subjectprincipal component–multilayer perceptron (PC-MLP)
dc.subjectspices
dc.titleNear-Infrared Spectroscopy with Machine Learning for Classifying and Quantifying Nutmeg Adulteration
dc.typeArticle

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