Graphene nanosheet-grafted double-walled carbon nanotube hybrid nanostructures by two-step chemical vapor deposition and their application for ethanol detection

dc.contributor.authorMuangrat, Worawut
dc.contributor.authorWongwiriyapan, Winadda
dc.contributor.authorMorimoto, Shingo
dc.contributor.authorHashimoto, Yoshio
dc.date.accessioned2026-08-06T10:26:33Z
dc.date.available2026-08-06T10:26:33Z
dc.date.issued2019-12-01
dc.description.abstractHere, we present a facile technique for synthesis of graphene nanosheet (GNS)-grafted double-walled carbon nanotube (DWCNT) hybrid carbon nanostructures (here after referred to as G-DWCNTs) by directly growing GNSs along the sidewalls of DWCNTs using a two-step chemical vapor deposition (CVD). DWCNTs were synthesized by floating catalyst CVD at 1300 °C using ferrocene and thiophene dissolved in ethanol. Then, GNSs were grafted onto the synthesized DWCNT bundles by thermal CVD at 1300 °C using ethanol. The sharp-edged petal-like structure of GNSs were grown along the sidewalls of DWCNT bundles while maintaining the one-dimensional structure of DWCNT. Next, DWCNTs and G-DWCNTs were dispersed in ethanol, then deposited on the paper using vacuum filtration method and used for ethanol detection. G-DWCNTs sensor exhibited a 3-fold improvement in the response to ethanol vapor compared to the DWCNTs sensor. The sensing mechanism of DWCNTs and G-DWCNTs can be described in terms of charge transfer between the gas molecules and sensing material. These results demonstrate that the facile technique by two-step CVD method provides a promising approach for simple and low-cost technique to synthesize the hybrid nanostructure of GNSs and DWCNTs. The new hybrid carbon nanostructures are attractive for gas sensing application.
dc.identifier.citationScientific Reports, 9(1), 2019
dc.identifier.doi10.1038/s41598-019-44315-y
dc.identifier.issn20452322
dc.identifier.other2-s2.0-85066232548
dc.identifier.urihttps://dspace.kmitl.ac.th/handle/123456789/10412
dc.sourceScientific Reports
dc.titleGraphene nanosheet-grafted double-walled carbon nanotube hybrid nanostructures by two-step chemical vapor deposition and their application for ethanol detection
dc.typeArticle

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