Modified energy storage properties of lead-free Sr0.3Bi0.35Na0.335Li0.015TiO3 ceramics with La3+ substitution via the solid-state combustion technique

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dc.contributor.authorSinkruason, Thanapon
dc.contributor.authorLuangpangai, Anupong
dc.contributor.authorJulphunthong, Phongthorn
dc.contributor.authorRittidech, Aurawan
dc.contributor.authorSuthapintu, Aekasit
dc.contributor.authorVittayakorn, Naratip
dc.contributor.authorBongkarn, Theerachai
dc.date.accessioned2026-08-06T10:47:54Z
dc.date.available2026-08-06T10:47:54Z
dc.date.issued2024-12-01
dc.description.abstractIn this study, the influence of La<sup>3+</sup> substitution on the phase structure, microstructure, electrical and energy storage properties of (Sr<inf>0.3</inf>Bi<inf>0.35</inf>Na<inf>0.335</inf>Li<inf>0.015</inf>)<inf>1-x</inf>La<inf>x</inf>TiO<inf>3</inf> (SBNLT-xLa) ceramics with x = 0–0.05, using the solid-state combustion technique, was investigated. X-ray diffraction (XRD) patterns indicated a pure perovskite structure formed, along with coexisting rhombohedral and tetragonal phases in all ceramics. The Rietveld refinement analysis showed the tetragonal phase increased while the rhombohedral phase decreased with increased La<sup>3+</sup> content. The morphology of the SBNLT-xLa ceramics displayed polygonal grain shapes and anisotropic grain growth. Average grain sizes increased from 2.01 to 2.43 μm as x increased from 0 to 0.01 and afterwards decreased as x increased further. Both the measured density and maximum dielectric constant (ɛ<inf>m</inf>) decreased from 5.48 to 5.29 g/cm<sup>3</sup> and from 4667 to 2313, respectively, when x increased from 0 to 0.05. A decrease in the dielectric properties caused by the phase ratio shifting away from a morphotropic phase boundary (MPB) condition, poor microstructure and low density was produced with La<sup>3+</sup> replacement. The maximum polarization (P<inf>max</inf>), remnant polarization (P<inf>r</inf>) and coercive field (E<inf>c</inf>) decreased with increased La<sup>3+</sup> content. A decline in P<inf>r</inf> and E<inf>c</inf> improved the energy storage efficiency (ƞ) and energy storage loss (W<inf>loss</inf>), resulting in enhanced energy storage properties. At x = 0.02, the ceramic showed good energy storage properties (W<inf>total</inf> of 0.781 J/cm<sup>3</sup>, W<inf>rec</inf> of 0.624 J/cm<sup>3</sup>, W<inf>loss</inf> of 0.157 J/cm<sup>3</sup> and ƞ of 79.8%), measured at 60 kV/cm.
dc.identifier.citationCeramics International, 50(23), 52011-52019, 2024
dc.identifier.doi10.1016/j.ceramint.2024.03.083
dc.identifier.issn02728842
dc.identifier.other2-s2.0-85188002121
dc.identifier.urihttps://dspace.kmitl.ac.th/handle/123456789/16103
dc.sourceCeramics International
dc.subjectBNLT-xLa
dc.subjectEnergy storage
dc.subjectFerroelectric
dc.subjectMicrostructure
dc.subjectPhase structure
dc.titleModified energy storage properties of lead-free Sr0.3Bi0.35Na0.335Li0.015TiO3 ceramics with La3+ substitution via the solid-state combustion technique
dc.typeArticle

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