Experimental insights into catalytic oxidation of 1,6-hexanediol to ε-caprolactone over (<i>p</i>-cymene)RuCl<sub>2</sub>(L) complexes in non-polar media
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Reaction Chemistry & Engineering
Abstract
The activity-pocket site dimension ( θ c ) dependence of ( p -cymene)RuCl 2 (L) supports associative interchange mechanism for 1,6-hexandiol oxidation to ε-caprolactone. Methyl isobutyl carbinol, a H-accepting product, reacts with Ru, causing deactivation.